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	Provedor de dados eCrystals (21) Anais da ABC (AABC) (4) ArchiMer (1) Autor Hursthouse, Michael B. (21) Horton, Peter N. (19) Butler, Ian R. (17) Coles, Simon J. (4) Allen, D. W. (2) Khan, S. M. (2) BELLETI,ELISANGELA (1) BIAZZOTTO,JULIANA C. (1) BRITO,ADRIANNE M.M. (1) Butler, Ian. R. (1) CAMARGO,PEDRO H.C. (1) CIUFFI,KATIA J. (1) Defauchy, Virginie (1) Drozdzak, Renata (1) Freund,Hans-Joachim (1) GEONMONOND,RAFAEL S. (1) Guinault, Alain (1) Hii, Mimi (K.K.) (1) IAMAMOTO,YASSUKO (1) LANFREDI,ALEXANDRE J.C. (1) Mais... Palavra-chave Catalysis (26) Organometallic (14) Iron (13) Ferrocene compounds (5) Organic (5) Controlled synthesis (2) Crystal structures (2) Hypercoordination (2) Inorganic (2) Nanomaterials (2) Noble-metals (2) Palladium (2) Phosphonium salts (2) Stibonium salts (2) Benzodiazepinic ligands (1) Characterization (1) Cobalt (1) C~17~H~27~FeIN~2~ (1) C~18~H~15~FeNO (1) C~18~H~22~O~2~ (1) Mais... Tipo do documento Crystal Structure Data Holding (21) Info:eu-repo/semantics/article (4) Text (1) Ano 2019 (1) 2018 (1) 2017 (1) 2009 (1) 2005 (1) 2004 (7) 2003 (6) 2002 (6) 2001 (1) 2000 (1) Mais... País United Kingdom (21) Brazil (4) France (1) Idioma Inglês (5)		Ordenar por:  Relevância Autor Título Ano Registros recuperados: 26 Primeira ... 1 2 ... Última 04SRC334 eCrystals Butler, Ian R.; Horton, Peter N.; Hursthouse, Michael B.. Tipo: Crystal Structure Data Holding Palavras-chave: C~46~H~49~Cl~3~O~6~; Organic; Catalysis. Ano: 2004 URL: http://ecrystals.chem.soton.ac.uk/925/ Kinetic analysis of polydicyclopentadiene oxidation ArchiMer Defauchy, Virginie; Le Gac, Pierre-yves; Guinault, Alain; Verdu, Jacques; Recher, Gilles; Drozdzak, Renata; Richaud, Emmanuel. The in situ thermal oxidation of thin unstabilized polydicyclopentadiene was studied by TGA to monitor mass gain, and DSC to characterize hydroperoxides concentration. Results were discussed using kinetic analysis, which allowed the estimation of activation energies for key reactions of the oxidation process. Activation energy for termination was shown to be higher than in hydrocarbon liquids, which was discussed from the theory of diffusion controlled reactions, and a possible link with local motions associated with sub-glassy transition. Activation energy of thermal decomposition of hydroperoxides was found lower than for model hydroperoxides, suggesting an accelerating effect of organometallic catalysts. Despite those two results that indicate a poor... Tipo: Text Palavras-chave: Polydicyclopentadiene; Thermal oxidation; Segmental mobility; Catalysis; Diffusion limited oxidation. Ano: 2017 URL: http://archimer.ifremer.fr/doc/00388/49904/50476.pdf Proteins and Peptides at the Interfaces of Nanostructures Anais da ABC (AABC) BRITO,ADRIANNE M.M.; BELLETI,ELISANGELA; MENEZES,LUCIVALDO R.; LANFREDI,ALEXANDRE J.C.; NANTES-CARDOS,ISELI L.. Abstract: The present review focuses on the proteins and peptides at the interfaces of nanostructured metals and semiconductors as a result of their use in synthesis in-situ and functionalization of nanostructures. We start the review with an introduction about the peculiar properties of nanostructured materials and their applications. In the following, the chemical and structural properties of peptides and proteins that allow their use as reducing, stabilizing, and functionalization agents are discussed. Proteins and peptides have not only the chemical groups for the metal ion reducing but also provide templates for directing the crystalline growing of nanostructures to the desired shapes and sizes. Proteins and peptides are also used mainly for the... Tipo: Info:eu-repo/semantics/article Palavras-chave: Controlled synthesis; Noble-metals; Nanomaterials; Catalysis; Proteins; Peptides. Ano: 2019 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652019000700402 Controlled synthesis of noble metal nanomaterials: motivation, principles, and opportunities in nanocatalysis Anais da ABC (AABC) GEONMONOND,RAFAEL S.; SILVA,ANDERSON G.M. DA; CAMARGO,PEDRO H.C.. ABSTRACT This review describes some principles of the controlled synthesis of metal nanoparticles, focusing on how the fundamental understanding of their synthesis in the solution-phase can be put to tailor size, shape, composition, and architecture. The maneuvering over these parameters not only enable the tuning of properties, but also the maximization and optimization of performances for various applications. Herein, we start with a brief description of metallic nanoparticles, highlighting the motivation for achieving physicochemical control in their synthesis. After that, we turn our attention to some important definitions and classifications as well as their unique properties such as surface and quantum effects. Moreover, we discuss the strategies for... Tipo: Info:eu-repo/semantics/article Palavras-chave: Controlled synthesis; Noble-metals; Nanomaterials; Catalysis. Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000200719 Towards an atomic level understanding of niobia based catalysts and catalysis by combining the science of catalysis with surface science Anais da ABC (AABC) Schmal,Martin; Freund,Hans-Joachim. The science of catalysis and surface science have developed, independently, key information for understanding catalytic processes. One might argue: is there anything fundamental to be discovered through the interplay between catalysis and surface science? Real catalysts of monometallic and bimetallic Co/Nb2O5 and Pd-Co/Nb2O5 catalysts showed interesting selectivity results on the Fischer-Tropsch synthesis (Noronha et al. 1996, Rosenir et al. 1993). The presence of a noble metal increased the C+5 selectivity and decreased the methane formation depending of the reduction temperature. Model catalyst of Co-Pd supported on niobia and alumina were prepared and characterized at the atomic level, thus forming the basis for a comparison with "real" support... Tipo: Info:eu-repo/semantics/article Palavras-chave: Catalysis; Model catalysts; Cobalt; Palladium; Characterization; Niobia. Ano: 2009 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652009000200016 Porphyrinosilica and metalloporphyrinosilica: hybrid organic-inorganic materials prepared by sol-gel processing Anais da ABC (AABC) IAMAMOTO,YASSUKO; SACCO,HÉRICA C.; BIAZZOTTO,JULIANA C.; CIUFFI,KATIA J.; SERRA,OSVALDO A.. New materials porphyrinosilica and metalloporphyrinosilica template have been obtained by a sol-gel processing where functionalyzed porphyrins and metalloporphyrins "building blocks" were assembled into a three-dimensional silicate network. The optimized conditions for preparation of these materials are revised. The monomer precursors porphyrinopropylsilyl and metalloporphyrinopropylsilyl preparation reactions and subsequent one pot sol-gel processing with tetraethoxysilane are discussed. In the case of metalloporphyrins the nitrogen base coordinates to the central metal and acts as a template in the molecular imprinting technique. UV-visible absorption spectroscopy, thermogravimetric analysis, electron paramagnetic resonance, nuclear magnetic spectra,... Tipo: Info:eu-repo/semantics/article Palavras-chave: Metalloporphyrin silica; Sol-gel; Catalysis; Hybrid material. Ano: 2000 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652000000100008 Registros recuperados: 26 Primeira ... 1 2 ... Última

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