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High precision U-series dating of scleractinian cold-water corals using an automated chromatographic U and Th extraction ArchiMer
Wefing, Anne-marie; Arps, Jennifer; Blaser, Patrick; Wienberg, Claudia; Hebbeln, Dierk; Frank, Norbert.
High-precision U-series dating of scleractinian cold-water corals is a key chronological tool for studies of past environmental and climate conditions. Here, we tested and optimized an automated chemical extraction system (ESI prepFAST-MC equipped with an Eichrom TRU-resin chromatographic column) for its ability to purify U and Th isotopes for mass spectrometric U-series dating at the sub-‰ precision level. Chemical yields are constantly high, on average around 90% for both U and Th. Analytical blanks are comparable to manual purification (< 0.15 pg U, 0.15 pg Th for a typical sample of 50 mg) and memory effects due to the recycling of the column are mostly insignificant as the carry-over fraction is about 10− 5 for Th and 10− 3 for U isotopes. However,...
Tipo: Text Palavras-chave: U-series dating; PrepFAST-MC; Cold-water corals; South Atlantic; Angola; Past climate.
Ano: 2017 URL: https://archimer.ifremer.fr/doc/00409/52058/52761.pdf
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