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Carbon isotope evidence for large methane emissions to the Proterozoic atmosphere ArchiMer
Cadeau, Pierre; Jézéquel, Didier; Leboulanger, Christophe; Fouilland, Eric; Le Floc’h, Emilie; Chaduteau, Carine; Milesi, Vincent; Guélard, Julia; Sarazin, Gérard; Katz, Amandine; D’amore, Sophie; Bernard, Cecile; Ader, Magali.
The Proterozoic Era records two periods of abundant positive carbon isotope excursions (CIEs), conventionally interpreted as resulting from increased organic carbon burial and leading to Earth’s surface oxygenation. As strong spatial variations in the amplitude and duration of these excursions are uncovered, this interpretation is challenged. Here, by studying the carbon cycle in the Dziani Dzaha Lake, we propose that they could be due to regionally variable methane emissions to the atmosphere. This lake presents carbon isotope signatures deviated by ~  + 12‰ compared to the modern ocean and shares a unique combination of analogies with putative Proterozoic lakes, interior seas or restricted epireic seas. A simple box model of its Carbon cycle demonstrates...
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Ano: 2020 URL: https://archimer.ifremer.fr/doc/00656/76784/77944.pdf
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Two-dimensional ammonium distribution in sediment pore waters using a new colorimetric diffusive equilibration in thin-film technique ArchiMer
Metzger, Edouard; Barbe, Anthony; Cesbron, Florian; Thibault De Chanvalon, Aubin; Jauffrais, Thierry; Jézéquel, Didier; Mouret, Aurélia.
This study presents a new gel based technique to describe the pore water ammonium distribution through the sediment-water interface in two dimensions at a millimeter scale. The technique is an adaptation of the classical colorimetric method based on the Berthelot's reaction. After the thin film of the gel probe was equilibrated by diffusion either in standard solutions or in pore waters, a colorimetric reagent gel was set on the gel probe, allowing development of the characteristic green color. A flatbed scanner and subsequent densitometry image analysis allowed to determine the concentration distribution of ammonium. The gel probe was tested in the laboratory for two media, deionized water and seawater, within the range 0–3000 μM in NH4+. Detection limit...
Tipo: Text Palavras-chave: Biogeochemistry; High-resolution; Porewater; DET; Densitometry.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00474/58557/61112.pdf
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