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Patterns of trace metal bioaccumulation and trophic transfer in a phytoplankton-zooplankton-small pelagic fish marine food web ArchiMer
Chouvelon, Tiphaine; Strady, Emilie; Harmelin-vivien, Mireille; Radakovitch, Olivier; Brach-papa, Christophe; Crochet, Sylvette; Knoery, Joel; Rozuel, Emmanuelle; Thomas, Bastien; Tronczynski, Jacek; Chiffoleau, Jean-francois.
Trace metal contamination in the European sardine and anchovy food web was investigated in the Gulf of Lions, NW Mediterranean Sea, including seawater and size fractions of plankton. The results highlighted: i) higher and more variable concentrations in the smaller plankton size classes for all metals except cadmium; ii) higher concentrations in anchovy versus sardine for all elements except lead; iii) different patterns of metal bioaccumulation through the food web: cobalt, nickel, copper, silver, lead and zinc displayed continuously decreasing concentrations (with the exception of increased zinc in fish only), while mercury concentrations dropped considerably in larger plankton size classes and rose significantly in fish. Lastly, cadmium concentrations...
Tipo: Text Palavras-chave: Inorganic elements; Seawater; Size-classed plankton; Sardina pilchardus; Engraulis encrasicolus; Mediterranean Sea.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00511/62286/67906.pdf
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Occurrence of priority and emerging organic compounds in fishes from the Rhone River (France) ArchiMer
Miege, Cécile; Peretti, A.; Labadie, P.; Budzinski, Helene; Le Bizec, B.; Vorkamp, K.; Tronczynski, Jacek; Persat, H.; Coquery,; Babut, M..
The main objective of this study was to collect new data on the occurrence, levels of priority and emerging organic compounds in freshwater fish sampled in the Rhone River. The 34 studied contaminants included alkylphenols, bisphenol A, polybromodiphenylethers (PBDE), perfluorinated compounds, hexabromocyclododecanes (HBCD), hexachlorobenzene and hexachlorobutadiene (HCBD). About 50 fish samples (individual specimens or pooled fish) were collected from three sites located upstream and downstream of the Lyon metropolitan area in the Rhone River (France). Four species were caught at each site, namely: the barbel (Barbus barbus), the common bream (Abramis brama), the white bream (Blicca bjoerkna) and the chub (Squalius cephalus). Some contaminants were...
Tipo: Text Palavras-chave: Emerging compounds; Priority compounds; Fishes; River waters; Contamination level.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00109/22043/19802.pdf
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Report on the approaches implemented in the Mediterranean countries for GES descriptor 8. Proposition of a road map for a better harmonization ArchiMer
Mauffret, Aourell; Bajt, Oliver; Bellas, Juan; Chalkiadaki, Olga; Dassenakis, Manos; Giannoudi, Louisa; Giubilato, Elisa; Hatzianestis, Ioannis; Marcomini, Antonio; Paramana, Theodora; Tsangaris, Catherine; Tronczynski, Jacek; Zeri, Christina.
Based on the data gap analysis performed in the first step of MEDCIS, the Medcis team on contaminant proposed a road map associated with a time-schedule in order to improve harmonization in Mediterranean region for 2024 GES assessment. Partner countries shared information on monitored substances and biological effects, thresholds used, matrix/matrices used for the monitoring of each substance/family of substances, the limit of quantification (LQ) of each chemical measurement, and the proportion of censored data
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Ano: 2019 URL: https://archimer.ifremer.fr/doc/00620/73249/72463.pdf
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Programme de recherche sur les produits phytosanitaires en zones littorales et estuaires ArchiMer
Tronczynski, Jacek.
This report represents sorne thoughts and the bibliographical review focused on an appraisal of the geochemical fate in freshwater and marin environments of principal pesticides used on French littoral. The sources and routes of entry, concentrations, distribution between non-living compartments and main degradation processes of these xenobiotic substances in the aquatic environment are presented.
Tipo: Text Palavras-chave: Produits phytosanitaires; Pollution; Environnement aquatique; Littoral.; Pesticides; Pollut~on; Aquatic environment; Littoral.
Ano: 1990 URL: http://archimer.ifremer.fr/doc/00132/24302/22300.pdf
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Dating of sediments in the Biscay bay: Implication for pollution chronology ArchiMer
Schmidt, S.; Tronczynski, Jacek; Guiot, Nadege; Lefevre, I..
Important historical informations on the temporal changes of anthropogenic pollution in marine environment can be assessed using sediment analysis. Dating is a crucial prerequisite to reconstruct pollution events, to calculate fluxes, and thus to allow comparison between different sites. This work presents estimates of accumulation rates of sediments in the Bay of Biscay. Fives cores were collected during RIKEAU 2002 cruise on board o/v Thalia in order to study temporal changes in PAH and organohalogens compounds content of sediment. We compare chronostratigraphic estimates on cores derived from the natural radionuclide 210Pb in excess with estimates from the known times of introduction of the artificial radionuclide 137Cs to the environment. 210Pb, 226Ra...
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Ano: 2005 URL: http://archimer.ifremer.fr/doc/00335/44603/44329.pdf
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PCDD/F and PCB multi-media ambient concentrations, congener patterns and occurrence in a Mediterranean coastal lagoon (Etang de Thau, France) ArchiMer
Castro Jimenez, J; Deviller, Genevieve; Ghiani, A; Loos, R; Mariani, G; Skejo, H; Umlauf, G; Wollgast, J; Laugier, Thierry; Heas Moisan, K; Leaute, Frederique; Munschy, Catherine; Tixier, Celine; Tronczynski, Jacek.
Ambient concentrations, congener patterns and multi-media distribution of PCDD/Fs and PCBs were determined in air, water, sediment and mussels in a semi-enclosed marine ecosystem (Thau lagoon, France). Sigma 2,3,7,8-PCDD/F and Sigma 7ICES PCB air concentrations (0.2-1.4 and 31-57 pg m(-3), respectively) were typical of rural areas. Concentrations in the water column were very low for PCDD/Fs (163-476 fg L-1) and low for PCBs (138-708 pg L-1). PCDD/F and PCB concentrations found in surface sediment (0.15-1.6 and 2.5-33 ng g(-1) d.w., respectively) and mussel (13-21 pg g(-1) d.w. and 10-39 ng g(-1) d.w., respectively) were medium levels. PCDD/F congener patterns observed in air, water particulate phase and sediments were similar suggesting direct coupling...
Tipo: Text Palavras-chave: Water column; Mussel; Air Sediment; POPs.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-4807.pdf
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Link between exposure of fish (Solea solea) to PAHs and metabolites: Application to the "Erika" oil spill ArchiMer
Budzinski, Hélène; Mazeas, Olivier; Tronczynski, Jacek; Desaunay, Yves; Bocquene, Gilles; Claireaux, Guy.
An analytical method consisting in enzymatic deconjugation, solid phase extraction and purification, and gas chromatography/mass spectrometry analysis after derivatization was used in this study to quantify Polycyclic Aromatic Hydrocarbon (PAH) metabolites in the bile of fish. The method has been applied in a laboratory experiment studying the fate of pyrene in basin containing soles. This study has allowed the identification of 1-hydroxypyrene as the single metabolite in bile after enzymatic deconjugation. In a second time, 1-hydroxypyrene has been used as a biomarker of exposure in the case of the "Erika" oil spill. This biomonitoring was successful in demonstrating the exposure of juvenile soles to PAHs present in the "Erika" fuel oil.
Tipo: Text Palavras-chave: Gas chromatography mass spectrometry; Fish; PAH metabolites.
Ano: 2004 URL: http://archimer.ifremer.fr/doc/2004/publication-404.pdf
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Differential biomagnification of PCB, PBDE, Hg and Radiocesium in the food web of the European hake from the NW Mediterranean ArchiMer
Harmelin-vivien, Mireille; Bodiguel, Xavier; Charmasson, Sabine; Loizeau, Veronique; Mellon, Capucine; Tronczynski, Jacek; Cossa, Daniel.
Consumption of marine organisms represents one of the main exposure sources of contaminants for human populations. To obtain a global view of the contamination in commercial fish in the NW Mediterranean Sea, we analysed four types of priority contaminants (PCBs, PBDEs, Hg and Cs-137) in the European hake, Merluccius merluccius, from the Gulf of Lions in relation with organism's trophic level (delta N-15). All contaminants presented a significant increase in concentration in hake muscle with trophic level. However, obvious differences between contaminants were evidenced. Biomagnification factors (BMF and FWMF) along the hake food web were higher for Hg and CB-153 than for BDE-47 and Cs-137, and increase in contaminant concentration with trophic level...
Tipo: Text Palavras-chave: Persistent organic pollutants; Mercury; Cs-137; Merluccius merluccius; Mediterranean.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00085/19583/17484.pdf
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Bioturbation at the water-sediment interface of the Thau Lagoon: impact of shellfish farming ArchiMer
Schmidt, Sabine; Gonzalez, Jean-louis; Lecroart, Pascal; Tronczynski, Jacek; Billy, Isabelle; Jouanneau, Jean-marie.
Quantifier les processus de remaniement sédimentaire procure une vision nouvelle du fonctionnement des écosystèmes benthiques de l'étang de Thau, lieu d'une importante production ostréicole. Afin d'évaluer les taux de bioturbation des sédiments de surface, des profils de deux traceurs radioactifs, le béryllium 7Be (T1/2 = 53 jours) et le thorium 234Th (T1/2 = 24.1 jours) ont été mesurés à partir de carottes sédimentaires prélevées entre décembre 2001 et décembre 2006. La sélection de plusieurs sites a permis de couvrir la diversité de l'étang de Thau : C4, T10, et T11 dans le bassin central, C5, T7 et T8 au niveau des secteurs ostréicoles, T2 et T4 à l'ouest du bassin, et T12 à l'est près de la zone industrielle. Le 234Th en excès (234Thxs ; i.e. apporté...
Tipo: Text Palavras-chave: Mediterranean Lagoon; Radionuclides; Biodeposition; Sedimentation.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/publication-2584.pdf
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Levels and trends of organohalogen compounds in mussels from the Seine estuary in 1981 - 2003 ArchiMer
Johansson, Inger; Moisan, Karine; Guiot, Nadege; Truquet, Isabelle; Munschy, Catherine; Tronczynski, Jacek.
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Ano: 2004 URL: http://archimer.ifremer.fr/doc/00335/44604/44330.pdf
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Chronic Polyaromatic Hydrocarbon (PAH) Contamination Is a Marginal Driver for Community Diversity and Prokaryotic Predicted Functioning in Coastal Sediments ArchiMer
Jeanbille, Mathilde; Gury, Jérôme; Duran, Robert; Tronczynski, Jacek; Ghiglione, Jean-françois; Agogué, Hélène; Saïd, Olfa Ben; Taïb, Najwa; Debroas, Didier; Garnier, Cédric; Auguet, Jean-christophe.
Benthic microorganisms are key players in the recycling of organic matter and recalcitrant compounds such as polyaromatic hydrocarbons (PAHs) in coastal sediments. Despite their ecological importance, the response of microbial communities to chronic PAH pollution, one of the major threats to coastal ecosystems, has received very little attention. In one of the largest surveys performed so far on coastal sediments, the diversity and composition of microbial communities inhabiting both chronically contaminated and non-contaminated coastal sediments were investigated using high-throughput sequencing on the 18S and 16S rRNA genes. Prokaryotic alpha-diversity showed significant association with salinity, temperature, and organic carbon content. The effect of...
Tipo: Text Palavras-chave: Microbial communities; PAH; Chronic contamination; Coastal sediment; Functional diversity.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00347/45854/45522.pdf
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The fate of river organic carbon in coastal areas: A study in the Rhone River delta using multiple isotopic (delta C-13, Delta C-14) and organic tracers ArchiMer
Cathalot, Cecile; Rabouille, Christophe; Tisnerat-laborde, N.; Toussaint, Flora; Kerherve, P.; Buscail, R.; Loftis, K.; Sun, M. -y.; Tronczynski, Jacek; Azoury, S.; Lansard, Bruno; Treignier, Claire; Pastor, L.; Tesi, T..
A significant fraction of the global carbon flux to the ocean occurs in River-dominated Ocean Margins (RiOMar) although large uncertainties remain in the cycle of organic matter (OM) in these systems. In particular, the OM sources and residence time have not been well clarified. Surface (0-1 cm) and sub-surface (3-4 cm) sediments and water column particles (bottom and intermediate depth) from the Rhone River delta system were collected in June 2005 and in April 2007 for a multi-proxy study. Lignin phenols, black carbon (BC), proto-kerogen/BC mixture, polycyclic aromatic hydrocarbons (PAHs), carbon stable isotope (delta C-13(OC)), and radiocarbon measurements (delta C-14(OC)) were carried out to characterize the source of sedimentary organic material and to...
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Ano: 2013 URL: http://archimer.ifremer.fr/doc/00157/26784/25673.pdf
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Contamination of the Bay of Biscay by polycyclic aromatic hydrocarbons (PAHs) following the T/V "Erika" oil spill ArchiMer
Tronczynski, Jacek; Munschy, Catherine; Moisan, Karine; Guiot, Nadege; Truquet, Isabelle; Olivier, Nathalie; Men, Sophie; Furaut, Audrey.
An investigation was carried out into the PAH chemical contamination resulting from the "Erika" tanker fuel spillage of December 1999 along the French coast of the Bay of Biscay. A qualitative and quantitative assessment was conducted of this contamination in water, suspended particulate matter, sediments, and in intertidal molluscs. The chemical composition of PAHs in pre-spill and post-spill samples was determined and used to distinguish the "Erika's" fuel as the source of PAHs in the coastal environment of the Bay of Biscay. Changes in concentrations of PAHs were also assessed. The GC-MS analysis made it possible to identify and quantify parent unsubstituted PAHs, alkyl-substituted PAHs (C-PAH) and sulfur heterocycle unsubstituted and alkyl substituted...
Tipo: Text Palavras-chave: The "Erika" oil spill; North East Atlantic; Marine molluscs; Sediments; Suspended particulate matter; Water; Chemical contamination.
Ano: 2004 URL: http://archimer.ifremer.fr/doc/2004/publication-401.pdf
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Plankton as biological pump for contaminants in marine ecosystems: a transmediterranean approach (Merite Hippocampe cruise, april-mai 2019) ArchiMer
Carlotti, François; Tronczynski, Jacek; Tedetti, Marc; Pagano, Marc; Garnier, Cédric.
Recent research on the bioaccumulation of organic and trace element contaminants along trophic food webs suggests that plankton plays a central role as a 'biological pump' for pollutants. The MERITE-HIPPOCAMPE project (oceanographic cruise in April- May 2019) aims at studying the interactions between plankton and contaminants (metallic, organic plastics) at atmosphere/water/biota interfaces via a North-South trans-Mediterranean approach in contrasted areas (primary production, fishing zones, ecoregions, polluted bays). The target contaminants are on the lists of priority pollutants and substances of Regional Conventions (OSPAR) and EU directives (WFD, MSF). The expected results are to provide a better understanding of the transfer processes of contaminants...
Tipo: Text Palavras-chave: Trace elements; Pcb; Pah; Plankton; Mediterranean Sea.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00599/71132/69447.pdf
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Comparison of five integrative samplers in laboratory for the monitoring of indicator and dioxin-like polychlorinated biphenyls in water ArchiMer
Jacquet, Romain; Miege, Cecile; Smedes, Foppe; Tixier, Celine; Tronczynski, Jacek; Togola, Anne; Berho, Catherine; Valor, Ignacio; Llorca, Julio; Barillon, Bruno; Marchand, Philippe; Coquery, Marina.
This study aimed at evaluating and comparing five integrative samplers for the monitoring of indicator and dioxin-like polychlorinated biphenyls (PCBs) in water: semi-permeable membrane device (SPMD), silicone rubber, low-density polyethylene (LDPE) strip, Chemcatcher and a continuous-flow integrative sampler (CFIS). These samplers were spiked with performance reference compounds (PRCs) and then simultaneously exposed under constant agitation and temperature in a 200 L stainless steel tank for periods ranging from one day to three months. A constant PCB concentration of about 1 ng·L−1 was achieved by immersing a large amount of silicone rubber sheets (“dosing sheets”) spiked with the target PCBs. The uptake of PCBs in the five samplers showed overall good...
Tipo: Text Palavras-chave: Integrative samplers; Polychlorinated biphenyls; Water monitoring; Time weighted average concentration; Modeling.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00162/27317/25962.pdf
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Levels and trends of brominated flame retardants in the European environment ArchiMer
Law, Robin J.; Allchin, Colin R; De Boer, Jacob; Covaci, Adrian; Herzke, Dorte; Lepom, Peter; Morris, Steven; Tronczynski, Jacek; De Wit, Cynthia A.
In this paper, we review those data which have recently become available for brominated flame retardants (particularly the brominated diphenyl ethers (BDEs) and hexabromocyclododecane (HBCD)) in samples from the European environment. Environmental compartments studied comprise the atmosphere, sediments and soils. sewage sludges. and a variety of biological samples and food chains. This is currently a very active research area, and we cite over 70 studies reported in the literature during 2003-04. Findings include that the input of BDEs (especially BDE209) to the Baltic Sea by atmospheric deposition now exceeds that of PCBs by a factor of almost 40 times. Sewage sludge samples from both industrial and background locations show concentrations of BDEs. HBCD...
Tipo: Text Palavras-chave: Biota; Sewage sludge; Soil; Sediment; Atmosphere; Europe; Tetrabromobisphenol A; Hexabromocyclododecane; Polybrominated diphenyl ethers; Brominated flame retardants.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/2006/publication-1685.pdf
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Marine Strategy Framework Directive. task group 8 : report contaminants and pollution effects ArchiMer
Law, R.; Hanke, Georg; Angelidis, Michael; Batty, J.; Bignert, A.; Dachs, J.; Davies, I.; Denga, Y.; Duffek, A.; Herut, B.; Hylland, K.; Lepom, Peter; Leonards, P.; Mehtonen, J.; Piha, Henna; Roose, J.; Tronczynski, Jacek; Velikova, V.; Vethaak, D..
The Marine Strategy Framework Directive (2008/56/EC) (MSFD) requires that the European Commission (by 15 July 2010) should lay down criteria and methodological standards to allow consistency in approach in evaluating the extent to which Good Environmental Status (GES) is being achieved. ICES and JRC were contracted to provide scientific support for the Commission in meeting this obligation. A total of 10 reports have been prepared relating to the descriptors of GES listed in Annex I of the Directive. Eight reports have been prepared by groups of independent experts coordinated by JRC and ICES in response to this contract. In addition, reports for two descriptors (Contaminants in fish and other seafood and Marine Litter) were written by expert groups...
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Ano: 2010 URL: http://archimer.ifremer.fr/doc/00077/18847/16420.pdf
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Interactions Between Dissolved Organic Matter and Organic Contaminants ArchiMer
Tronczynski, Jacek.
The interactions between dissolved organic matter and organic contaminants affect their solution speciation and their distribution between the aqueous and solid phases. This partitioning governs the transport and influences the transformations and toxicity of contaminants. Thus, detailed understanding of fate and effects of contaminant in aquatic ecosystems is dependent upon the knowledge of contaminant speciation in these environments.
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Ano: 1992 URL: http://archimer.ifremer.fr/doc/00177/28854/27334.pdf
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Implementation of a 3D Coupled Hydrodynamic and Contaminant Fate Model for PCDD/Fs in Thau Lagoon (France): The Importance of Atmospheric Sources of Contamination ArchiMer
Dueri, Sibylle; Marinov, Dimitar; Fiandrino, Annie; Tronczynski, Jacek; Zaldivar, Jose-manuel.
A 3D hydrodynamic and contaminant fate model was implemented for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in Thau lagoon. The hydrodynamic model was tested against temperature and salinity measurements, while the contaminant fate model was assessed against available data collected at different stations inside the lagoon. The model results allow an assessment of the spatial and temporal variability of the distribution of contaminants in the lagoon, the seasonality of loads and the role of atmospheric deposition for the input of PCDD/Fs. The outcome suggests that air is an important source of PCDD/Fs for this ecosystem, therefore the monitoring of air pollution is very appropriate for assessing the inputs of these contaminants. These...
Tipo: Text Palavras-chave: PCDD/F; Thau lagoon; POPs; Fate model; Hydrodynamic model.
Ano: 2010 URL: https://archimer.ifremer.fr/doc/00003/11441/7995.pdf
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Polycyclic aromatic hydrocarbons in surface sediments of the mid-Adriatic and along the Croatian coast: Levels, distributions and sources ArchiMer
Mandic, Jelena; Tronczynski, Jacek; Kuspilic, Grozdan.
This study provides contamination levels, distributions and source apportionment of PAHs in surface sediments in the mid-Adriatic and along the Croatian coast. Median summed concentrations of parent and alkyl-PAHs are circa 10 times lower in the off-shore transect stations of the mid-Adriatic (22.3 and 18.2 μg.kg−1 d.w.) than the ranges determined at the coastal stations, including those of Kaštela bay (227–331 and 11.7–197 μg.kg−1 d.w., respectively). The highest levels, circa 20 times higher, were found in Šibenik bay (median 6603 and 3051 μg.kg−1). The overall range of PAH concentrations spans more than 2000 times between the lowest and the highest contamination level. The geographical distributions reflect the presence of strong gradients at local and...
Tipo: Text Palavras-chave: Marine sediments; Polycyclic aromatic hydrocarbons (PAHs); Source profiles; Source apportionment; Source-receptor models.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00448/55965/57473.pdf
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