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	Provedor de dados Rev. Bras. Ciênc. Solo (2) Scientia Agricola (1) Autor Marchi,Giuliano (2) O’Connor,George (2) Vilar,Cesar Crispim (2) Costa,Antonio Carlos Saraiva da (1) Goldberg,Sabine (1) Oliveira,Letuzia Maria de (1) Reatto,Adriana (1) Rein,Thomaz Adolph (1) Santos,Patricia dos (1) Silva,Marx Leandro Naves (1) Mais... Palavra-chave FITEQL (3) Chemical equilibrium software (2) Intrinsic equilibrium constants (2) Visual MINTEQ (2) Chemical properties (1) Mineralogy (1) Oxisol (1) Oxisols (1) Mais... Tipo do documento Info:eu-repo/semantics/article (3) Ano 2020 (1) 2015 (2) País Brazil (3) Idioma Inglês (3)		Ordenar por:  Relevância Autor Título Ano Registros recuperados: 3 Primeira ... 1 ... Última Surface Complexation Modeling in Variable Charge Soils: Prediction of Cadmium Adsorption Rev. Bras. Ciênc. Solo Marchi,Giuliano; Vilar,Cesar Crispim; O’Connor,George; Oliveira,Letuzia Maria de; Reatto,Adriana; Rein,Thomaz Adolph. ABSTRACT Intrinsic equilibrium constants for 22 representative Brazilian Oxisols were estimated from a cadmium adsorption experiment. Equilibrium constants were fitted to two surface complexation models: diffuse layer and constant capacitance. Intrinsic equilibrium constants were optimized by FITEQL and by hand calculation using Visual MINTEQ in sweep mode, and Excel spreadsheets. Data from both models were incorporated into Visual MINTEQ. Constants estimated by FITEQL and incorporated in Visual MINTEQ software failed to predict observed data accurately. However, FITEQL raw output data rendered good results when predicted values were directly compared with observed values, instead of incorporating the estimated constants into Visual MINTEQ. Intrinsic... Tipo: Info:eu-repo/semantics/article Palavras-chave: Intrinsic equilibrium constants; Oxisol; FITEQL; Visual MINTEQ; Chemical equilibrium software. Ano: 2015 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832015000501395 Surface Complexation Modeling in Variable Charge Soils: Charge Characterization by Potentiometric Titration Rev. Bras. Ciênc. Solo Marchi,Giuliano; Vilar,Cesar Crispim; O’Connor,George; Silva,Marx Leandro Naves. ABSTRACT Intrinsic equilibrium constants of 17 representative Brazilian Oxisols were estimated from potentiometric titration measuring the adsorption of H+ and OH− on amphoteric surfaces in suspensions of varying ionic strength. Equilibrium constants were fitted to two surface complexation models: diffuse layer and constant capacitance. The former was fitted by calculating total site concentration from curve fitting estimates and pH-extrapolation of the intrinsic equilibrium constants to the PZNPC (hand calculation), considering one and two reactive sites, and by the FITEQL software. The latter was fitted only by FITEQL, with one reactive site. Soil chemical and physical properties were correlated to the intrinsic equilibrium constants. Both surface... Tipo: Info:eu-repo/semantics/article Palavras-chave: Intrinsic equilibrium constants; Oxisols; FITEQL; Visual MINTEQ; Chemical equilibrium software. Ano: 2015 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832015000501387 Modeling boron adsorption on five soils before and after removal of organic matter Scientia Agricola Santos,Patricia dos; Goldberg,Sabine; Costa,Antonio Carlos Saraiva da. ABSTRACT Boron- B concentrations that cause deficiency and those that cause toxicity appear to be very similar, compared to other nutrients, which can complicate successful management of this element in soils. In this study, B adsorption onto two Oxisols from Brazil (Rhodic Eutroperox and Anionic Acroperox), two Alfisols (Natric Palexeralf and Aridic Paleustalf) and an Entisol (Xeric Torrifluvent) from the United States of America were evaluated. The samples were treated with sodium hypochlorite in order to remove soil organic matter. Both treated and untreated samples were used to determine B adsorption isotherms using different B concentrations (0-4.630 mmol L–1) and NaNO3 (0.05 M) as background electrolyte solution at pH 7. Boron adsorption envelopes... Tipo: Info:eu-repo/semantics/article Palavras-chave: FITEQL; Chemical properties; Mineralogy. Ano: 2020 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162020000401401 Registros recuperados: 3 Primeira ... 1 ... Última

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