Data/hora: 13/06/2024 08:08:44

Provedor de dados: 	5	
País: 	France	
Título: 	Diazonium Salt-Based Surface-Enhanced Raman Spectroscopy Nanosensor: Detection and Quantitation of Aromatic Hydrocarbons in Water Samples	
Autores: 	Tijunelyte, Inga; Betelu, Stephanie; Moreau, Jonathan; Ignatiadis, Ioannis; Berho, Catherine; Lidgi-guigui, Nathalie; Guenin, Erwann; David, Catalina; Vergnole, Sebastien; Rinnert, Emmanuel; Lamy De La Chapelle, Marc.	
Data: 	2017-06	
Ano: 	2017	
Palavras-chave: 	Polynuclear aromatic hydrocarbon (PAH); Surface-enhanced Raman spectroscopy (SERS); Nanosensor; Diazonium salt; Surface functionalization; Detection.	
Resumo: 	Here, we present a surface-enhanced Raman spectroscopy (SERS) nanosensor for environmental pollutants detection. This study was conducted on three polycyclic aromatic hydrocarbons (PAHs): benzo[a]pyrene (BaP), fluoranthene (FL), and naphthalene (NAP). SERS substrates were chemically functionalized using 4-dodecyl benzenediazonium-tetrafluoroborate and SERS analyses were conducted to detect the pollutants alone and in mixtures. Compounds were first measured in water-methanol (9:1 volume ratio) samples. Investigation on solutions containing concentrations ranging from 10−6 g L−1 to 10−3 g L−1 provided data to plot calibration curves and to determine the performance of the sensor. The calculated limit of detection (LOD) was 0.026 mg L−1 (10−7 mol L−1) for BaP, 0.064 mg L−1 (3.2 × 10−7 mol L−1) for FL, and 3.94 mg L−1 (3.1 × 10−5 mol L−1) for NAP, respectively. The correlation between the calculated LOD values and the octanol-water partition coefficient (Kow) of the investigated PAHs suggests that the developed nanosensor is particularly suitable for detecting highly non-polar PAH compounds. Measurements conducted on a mixture of the three analytes (i) demonstrated the ability of the developed technology to detect and identify the three analytes in the mixture; (ii) provided the exact quantitation of pollutants in a mixture. Moreover, we optimized the surface regeneration step for the nanosensor.	
Tipo: 	Text	
Idioma: 	Inglês	
Identificador: 	http://archimer.ifremer.fr/doc/00386/49772/50316.pdf

http://archimer.ifremer.fr/doc/00386/49772/50317.pdf

DOI:10.3390/s17061198

http://archimer.ifremer.fr/doc/00386/49772/	
Editor: 	Mdpi Ag	
Formato: 	application/pdf	
Fonte: 	Sensors (1424-8220) (Mdpi Ag), 2017-06 , Vol. 17 , N. 6 , P. 1198 (1-17)	
Fonte: 	2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

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