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Provedor de dados:  REA
País:  Brazil
Título:  ADSORPTION OF ATRAZINE BY BIOCHARS PRODUCED FROM BYPRODUCTS OF THE WOOD INDUSTRY
Autores:  Fruehwirth,Marcelo
Sbizzaro,Mariana
Rosa,Danielle M.
Sampaio,Silvio C.
Reis,Ralpho R. dos
Data:  2020-12-01
Ano:  2020
Palavras-chave:  Water contamination
Isotherm
Functional groups
Kinetics models
Resumo:  ABSTRACT Atrazine is a herbicide widely used in agriculture; however, because of its toxicity, alternatives are needed to remove this compound from the environment. In this study, we investigated the adsorption process and the atrazine-adsorbing ability of three biochars produced at different pyrolysis temperatures from byproducts of the wood industry. The biochars were characterized by Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), and their physical characteristics were evaluated by Brunauer-Emmett-Teller (BET) analysis. The biochar pyrolyzed at 350 °C (BM350) adsorbed 26.04% of the herbicide, showing the best performance among the three biochars tested, even though it had the lowest specific surface area (1.467 m2 g–1). It also had a greater quantity of organic functional groups, which may have influenced the adsorption. The kinetics of the adsorption process were best explained by the pseudo-first-order model and by the Freundlich isotherm model. However, the biochar is not suitable for the removal of the herbicide atrazine, having a lower adsorption capacity than those of others described in the literature.
Tipo:  Info:eu-repo/semantics/article
Idioma:  Inglês
Identificador:  http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-69162020000600769
Editor:  Associação Brasileira de Engenharia Agrícola
Relação:  10.1590/1809-4430-eng.agric.v40n6p769-776/2020
Formato:  text/html
Fonte:  Engenharia Agrícola v.40 n.6 2020
Direitos:  info:eu-repo/semantics/openAccess
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