Data/hora: 13/06/2024 05:26:55

Provedor de dados: 	90	
País: 	Brazil	
Título: 	Functionalized Charcoal as a Buffering Matrix of Copper and Zinc Availability	
Autores: 	Guimarães,Gelton Geraldo Fernandes; Giroto,Amanda Soares; Teixeira,Breno Cardoso; Vergütz,Leonardus; Cantarutti,Reinaldo Bertola.	
Data: 	2018-01-01	
Ano: 	2018	
Palavras-chave: 	Adsorption; Desorption; Metals; Remediation; Biochar.	
Resumo: 	ABSTRACT: High copper (Cu) and zinc (Zn) contents in soil can cause phytotoxicity to plants and contaminate surface and groundwater, with negative effects on agriculture and the environment. Functionalized charcoal (OCh) has high cation exchange capacity (CEC) and the ability to adsorb Cu and Zn and control their availability in the soil and water. An adsorption study at two pH levels was carried out to evaluate increasing Cu and Zn sorption capacity provided by the functionalization process of a charcoal. In addition, a kinetics study of competitive and non-competitive adsorption-desorption of Cu and Zn in OCh was also evaluated. The results showed that functionalized charcoal (Ch) increased CEC 8.7 times due to an increase in carboxyl and phenolic groups, without changing its specific surface area. The Cu and Zn kinetics study showed higher interaction of Cu with the OCh, with total adsorption capacity of 53.1 mg g−1. From this amount, only 74.9 % was desorbed. However, competitive adsorption with Zn reduced the total amount of Cu adsorbed and decreased the Cu affinity for organic matter. This study shows the potential use of functionalized charcoal for control of Cu and Zn availability in the soil solution.	
Tipo: 	Info:eu-repo/semantics/article	
Idioma: 	Inglês	
Identificador: 	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832018000100530	
Editor: 	Sociedade Brasileira de Ciência do Solo	
Relação: 	10.1590/18069657rbcs20170366	
Formato: 	text/html	
Fonte: 	Revista Brasileira de Ciência do Solo  v.42 2018	
Fonte: 	info:eu-repo/semantics/openAccess