Data/hora: 06/06/2024 15:37:14

Provedor de dados: | 90
País: | Brazil
Título: | Kinetics of phosphorus sorption in soils in the state of Paraíba¹
Autores: | Santos,Hemmannuella Costa; Oliveira,Fábio Henrique Tavares de; Salcedo,Ignácio Hernan; Souza,Adailson Pereira de; Mota Silva,Valério Damásio da.
Data: | 2011-08-01
Ano: | 2011
Palavras-chave: | Adsorption; Kinetic equations; Phosphate; Tropical soils; Semi-arid soils.
Resumo: | The soil P sorption capacity has been studied for many years, but little attention has been paid to the rate of this process, which is relevant in the planning of phosphate fertilization. The purpose of this experiment was to assess kinetics of P sorption in 12 representative soil profiles of the State of Paraíba (Brazil), select the best data fitting among four equations and relate these coefficients to the soil properties. Samples of 12 soils with wide diversity of physical, chemical and mineralogical properties were agitated in a horizontal shaker, with 10 mmo L-1 CaCl2 solution containing 6 and 60 mg L-1 P, for periods of 5, 15, 30, 45, 60, 90, 120, 420, 720, 1,020, and 1,440 min. After each shaking period, the P concentration in the equilibrium solution was measured and three equations were fitted based on the Freundlich equation and one based on the Elovich equation, to determine which soil had the highest sorption rate (kinetics) and which soil properties correlated to this rate. The kinetics of P sorption in soils with high maximum P adsorption capacity (MPAC) was fast for 30 min at the lower initial P concentration (6 mg L-1). No difference was observed between soils at the higher initial P concentration (60 mg L-1). The P adsorption kinetics were positively correlated with clay content, MPAC and the amount of Al extracted with dithionite-citrate-bicarbonate. The data fitted well to Freundlich-based equations equation, whose coefficients can be used to predict P adsorption rates in soils.
Tipo: | Info:eu-repo/semantics/article
Idioma: | Inglês
Identificador: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832011000400024
Editor: | Sociedade Brasileira de Ciência do Solo
Relação: | 10.1590/S0100-06832011000400024
Formato: | text/html
Fonte: | Revista Brasileira de Ciência do Solo  v.35 n.4 2011
Fonte: | info:eu-repo/semantics/openAccess