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Element enrichment and provenance of the detrital component in Holocene sediments from the western Black Sea ArchiMer
Dekov, Vesselin M.; Darakchieva, Valentina Y.; Billström, Kjell; Garbe-schönberg, C-dieter; Kamenov, George D.; Gallinari, Morgane; Dimitrov, Lyubo; Ragueneau, Olivier; Kooijman, Ellen.
Concentrations of a large set of major and trace elements, and Sr, Nd and Pb isotope ratios were measured in Holocene sediments cored in the western deep Black Sea in order to unravel: (1) the controls of element enrichment, and (2) sources of the detrital component. The transition of the basin from oxic to euxinic resulted in enrichment or depletion in a number of elements in the deep-sea sediments. Authigenic Fe enrichment appears to depend on the amount of Fe mobilized from the sediment through the benthic redox shuttle mechanism and free H2S in the water column (degree of “euxinization”). Manganese enrichment is controlled by diagenetic reactions within the sediment: the dissolution of Mn minerals, Mn2+ diffusion upward and reprecipitation. Barium...
Tipo: Text Palavras-chave: Anoxic; Black Sea; Element enrichment; Sr-Nd-Pb-isotopes; Holocene.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00590/70164/68171.pdf
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GEOTRACES inter-calibration of the stable silicon isotope composition of dissolved silicic acid in seawater ArchiMer
Grasse, Patricia; Brzezinski, Mark A.; Cardinal, Damien; De Souza, Gregory F.; Andersson, Per; Closset, Ivia; Cao, Zhimian; Dai, Minhan; Ehlert, Claudia; Estrade, Nicolas; Francois, Roger; Frank, Martin; Jiang, Guibin; Jones, Janice L.; Kooijman, Ellen; Liu, Qian; Lu, Dawei; Pahnke, Katharina; Ponzevera, Emmanuel; Schmitt, Melanie; Sun, Xiaole; Sutton, Jill; Thil, Francois; Weis, Dominique; Wetzel, Florian; Zhang, Anyu; Zhang, Jing; Zhang, Zhouling.
The first inter-calibration study of the stable silicon isotope composition of dissolved silicic acid in seawater, delta Si-30(OH)(4), is presented as a contribution to the international GEOTRACES program. Eleven laboratories from seven countries analyzed two seawater samples from the North Pacific subtropical gyre (Station ALOHA) collected at 300 m and at 1000 m water depth. Sampling depths were chosen to obtain samples with a relatively low (9 mmol L-1, 300 m) and a relatively high (113 mmol L-1, 1000 m) silicic acid concentration as sample preparation differs for low- and highconcentration samples. Data for the 1000 m water sample were not normally distributed so the median is used to represent the central tendency for the two samples. Median delta...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00381/49270/49681.pdf
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