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Comparative geochemistry of four ferromanganese crusts from the Pacific Ocean and significance for the use of Ni isotopes as paleoceanographic tracers ArchiMer
Gueguen, Bleuenn; Rouxel, Olivier; Rouget, Marie-laure; Bollinger, Claire; Ponzevera, Emmanuel; Germain, Yoan; Fouquet, Yves.
Ferromanganese (Fe-Mn) crusts are potential archive of the Ni isotope composition of seawater through time. In this study we aim at (1) understanding Ni isotope fractionation mechanisms and metal enrichment processes in Fe-Mn deposits, (2) addressing global vs. local control of Ni isotope composition of these deposits. Two Fe-Mn crusts from the North Pacific Ocean (Apuupuu Seamount, Hawaii) and two Fe-Mn crusts from the South Pacific Ocean (near Rurutu Island, Austral archipelago of French Polynesia) were characterized for their elemental geochemistry and Ni isotope composition. Geochemical analyses were performed at millimeter intervals in order to provide time-resolved record of Ni isotopes. Chronology and growth rates were determined using cosmogenic...
Tipo: Text Palavras-chave: Ferromanganese crusts; Nickel isotopes; Paleoceanography; Pacific Ocean; Biogeochemical cycling.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00341/45255/44696.pdf
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20 ans de suivi de la contamination chimique des eaux côtières méditerranéennes. Résultats & perspectives ArchiMer
Bouchoucha, Marc; Tomasino, Corinne; Amouroux, Isabelle; Andral, Bruno; Brach-papa, Christophe; Briand, Marine; Buchet, Remi; Delmas, Lucile; Galgani, François; Gonzalez, Jean-louis; Grouhel-pellouin, Anne; Mauffret, Aourell; Mille, Tiphaine; Munaron, Dominique; Ponzevera, Emmanuel; Wessel, Nathalie; Boissery, Pierre.
Ce rapport fait le bilan de la surveillance de la contamination chimique opérée par l’Ifremer, en partenariat avec l’agence de l’eau Rhône Méditerranée Corse, entre 1998 et 2018. Il présente sur la forme de graphiques et de cartes les principaux résultats obtenus durant cette période ainsi que l’évolution des méthodes et des stratégies de surveillance des eaux côtières de Méditerranée.
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Ano: 2021 URL: https://archimer.ifremer.fr/doc/00673/78554/80744.pdf
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Environmental Hf–Nd isotopic decoupling in World river clays ArchiMer
Bayon, Germain; Skonieczny, Charlotte; Delvigne, Camille; Toucanne, Samuel; Bermell, Sylvain; Ponzevera, Emmanuel; Andre, Luc.
The hafnium and neodymium radiogenic isotope systems behave differently during Earth surface processes, causing a wide dispersion of Hf and Nd isotopic compositions in sediments and other sedimentary rocks. The decoupling between Hf and Nd isotopes in sediments is generally attributed to a combination of preferential sorting of zircon during sediment transport and incongruent weathering processes on continents. In this study, we analysed size-fractions of sediment samples collected near the mouth of 53 rivers worldwide to better understand the factors controlling the distribution of Hf and Nd isotopes in sediments. Our results for rivers draining old cratonic areas and volcanic provinces demonstrate that both granite and basalt weathering can lead to...
Tipo: Text Palavras-chave: Hafnium isotopes; Neodymium; Rivers; Clays; Weathering; Climate.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00310/42094/41479.pdf
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Nickel distribution and isotopic fractionation in a Brazilian lateritic regolith: coupling Ni isotopes and Ni K-edge XANES. ArchiMer
Ratie, G.; Garnier, J.; Calmels, D.; Vantelon, D.; Guimaraes, E.; Monvoisin, G.; Nouet, J.; Ponzevera, Emmanuel; Quantin, C..
Ultramafic (UM) rocks are known to be nickel (Ni) rich and to weather quickly, which makes them a good candidate to look at the Ni isotope systematics during weathering processes at the Earth’s surface. The present study aims at identifying the Ni solid speciation and discussing the weathering processes that produce Ni isotope fractionation in two deep laterite profiles under tropical conditions (Barro Alto, Goiás State, Brazil). While phyllosilicates and to a lower extent goethite are the main Ni-bearing phases in the saprolitic part of the profile, iron (Fe) oxides dominate the Ni budget in the lateritic unit. Nickel isotopic composition (δ60Ni values) has been measured in each unit of the regolith, i.e., rock, saprock, saprolite and laterite (n=52)....
Tipo: Text Palavras-chave: Nickel cycle; Lateritic regolith; Nickel isotopes; XANES; Ultramafic environment; Weathering.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00436/54712/56149.pdf
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Rare earth elements and neodymium isotopes in sedimentary organic matter ArchiMer
Freslon, Nicolas; Bayon, Germain; Toucanne, Samuel; Bermell, Sylvain; Bollinger, Claire; Chéron, Sandrine; Etoubleau, Joel; Germain, Yoan; Khripounoff, Alexis; Ponzevera, Emmanuel; Rouget, Marie Laure.
We report rare earth element (REE) and neodymium (Nd) isotope data for the organic fraction of sediments collected from various depositional environments, i.e. rivers (n=25), estuaries (n=18), open-ocean settings (n=15), and cold seeps (n=12). Sedimentary Organic Matter (SOM) was extracted using a mixed hydrogen peroxide/nitric acid solution (20%-H2O2 – 0.02M-HNO3), after removal of carbonate and oxy-hydroxide phases with dilute hydrochloric acid (0.25M-HCl). A series of experimental tests indicate that extraction of sedimentary organic compounds using H202 may be complicated occasionally by partial dissolution of sulphide minerals and residual carbonates. However, this contamination is expected to be minor for REE because measured concentrations in H2O2...
Tipo: Text Palavras-chave: Organic matter; Rare earth elements; REE; Neodymium isotopes; ΕNd; Sediment; Boundary Exchange; Paleoceanography.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00191/30250/28682.pdf
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Behaviour of rare earth and trace elements during fluid venting at cold seeps ArchiMer
Birot, Dominique; Bayon, Germain; Ruffine, Livio; Caprais, Jean-claude; Bollinger, C.; Ponzevera, Emmanuel; Rongemaille, Emmanuelle; Voisset, Michel.
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Ano: 2010 URL: http://archimer.ifremer.fr/doc/00023/13414/10493.pdf
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Hf and Nd isotopes in marine sediments: Constraints on global silicate weathering ArchiMer
Bayon, Germain; Burton, K. W.; Soulet, Guillaume; Vigier, N.; Dennielou, Bernard; Etoubleau, Joel; Ponzevera, Emmanuel; German, C. R.; Nesbitt, R. W..
The combined use of Lu-Hf and Sm-Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf-Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (epsilon(Nd)similar to - 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the...
Tipo: Text Palavras-chave: Congo fan; Seawater array; Continental erosion; Silicate weathering; Hafnium isotopes; Neodymium isotopes.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6451.pdf
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Paleo-environmental controls on cold seep carbonate authigenesis in the Sea of Marmara ArchiMer
Cremiere, Antoine; Bayon, Germain; Ponzevera, Emmanuel; Pierre, Catherine.
The factors controlling fluid emission dynamics at ocean margins are poorly understood. In particular, there are significant uncertainties on how fluid seepage at cold seeps may have responded to abrupt environmental changes in the geological past. This study reports on a detailed geochemical investigation of seafloor carbonate crusts sampled at cold seeps along the submerged part of the North Anatolian Fault system in the Sea of Marmara - an inland sea, which has experienced major paleo-environmental changes over the last deglaciation period. We also analyzed a series of authigenic carbonate concretions recovered from two sediment cores at the Western-High ridge, an active fluid venting area. The ages of seafloor carbonate crusts derived from isochron...
Tipo: Text Palavras-chave: U-Th dating; Authigenic carbonates; Sea of Marmara; Cold seeps; Sapropel event; Carbon and oxygen isotopes.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00161/27249/25488.pdf
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The silicon isotopic composition of surface waters in the Atlantic and Indian sectors of the Southern Ocean ArchiMer
De La Rocha, Christina L.; Bescont, Pierre; Croguennoc, Alice; Ponzevera, Emmanuel.
We report here the silicon isotopic composition (delta(30)Si) of dissolved silicon (DSi) from 42 surface water samples from the Drake Passage, the Weddell Gyre, other areas south of the Southern Boundary of the Antarctic Circumpolar Current (ACC), and the ACC near the Kerguelen Plateau, taken between the beginning of February and the end of March 2007. From the beginning to end of the cruise (ANTXXIII/9), DSi diminished in the Antarctic by 50 mu mol L(-1) while concentrations of nitrate + nitrite and phosphate showed no net decline, indicating that the high seasonal Si/N removal ratios well known for the Southern Ocean may be more related to the strength of the silicate pump in the Southern Ocean than to the instantaneous Si/N uptake ratio of diatoms. The...
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Ano: 2011 URL: http://archimer.ifremer.fr/doc/00042/15372/12791.pdf
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Nickel isotope fractionation during laterite Ni ore smelting and refining: implications for tracing the sources of Ni in smelter-affected soils ArchiMer
Ratie, G.; Quantin, C.; Jouvin, D.; Calmels, D.; Ettler, V.; Sivry, Y.; Cruz Vieira, L.; Ponzevera, Emmanuel; Garnier, J..
Nickel isotope ratios were measured in ores, fly ash, slags and FeNi samples from two metallurgical plants located in the Goiás State, Brazil (Barro Alto, Niquelândia). This allowed investigating the mass-dependent fractionation of Ni isotopes during the Ni-laterite ore smelting and refining. Feeding material exhibits a large range of δ60Ni values (from 0.02 ± 0.10 ‰ to 0.20 ± 0.05 ‰, n=7), explained by the diversity of Ni-bearing phases, and the average of δ60Nifeeding materials was found equal to 0.08 ± 0.08‰ (2SD, n=7). Both δ60Ni values of fly ash (δ60Ni = 0.07 ± 0.07‰, n=10) and final FeNi produced (0.05 ± 0.02 ‰, n=2) were not significantly different from the feeding materials ones. These values are consistent with the very high production yield of...
Tipo: Text Palavras-chave: Nickel; Isotope; Smelting; Refining; Source; Soil.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00278/38961/37501.pdf
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Geochemical Dynamics of the Natural-Gas Hydrate System in the Sea of Marmara, Offshore Turkey ArchiMer
Ruffine, Livio; Fandino Torres, Olivia; Etoubleau, Joel; Cheron, Sandrine; Donval, Jean-pierre; Germain, Yoan; Ponzevera, Emmanuel; Guyader, Vivien; Dennielou, Bernard; Etiope, Giuseppe; Gasperini, Luca; Bortoluzzi, Giovanni; Henry, Pierre; Grall, Celine; Cagatay, M. Namik; Charlou, Jean-luc; Geli, Louis.
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Ano: 2012 URL: http://archimer.ifremer.fr/doc/00139/24982/23065.pdf
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Sulfate-dependent anaerobic oxidation of methane at a highly dynamic bubbling site in the Eastern Sea of Marmara (Çinarcik Basin) ArchiMer
Teichert, B. M. A.; Chevalier, N.; Gussone, N.; Bayon, Germain; Ponzevera, Emmanuel; Ruffine, Livio; Strauss, H..
During the MARSITECruise expedition in November 2014 on board the RV Pourquoi Pas?, multidisciplinary sampling was carried out with the ROV Victor 6000 in order to investigate biogeochemical processes taking place at cold seep environments in the Sea of Marmara. Pore water, bottom water, sediment and authigenic carbonate samples were collected from two short push cores (MRS-DV5-PC04 − 8 cm, MRS-DV5-PC01 − 12.5 cm) at an active methane bubbling site in the southeastern part of the Çinarcik Basin. Sulfate sulfur and oxygen isotope data as well as sulfide isotope data indicate that sulfate-dependent anaerobic oxidation of methane is the dominant process in the sediments. This is confirmed by archaeal lipids diagnostic for anaerobic methane oxidizers detected...
Tipo: Text Palavras-chave: Sea of Marmara; Cinarcik Basin; Methane; Sulfate reduction; Anaerobic oxidation of methane; Authigenic carbonate; Lipid biomarker.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00413/52480/53267.pdf
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Living (stained) deep-sea foraminifera from the Sea of Marmara: a preliminary study ArchiMer
Fontanier, Christophe; Dissard, D.; Ruffine, Livio; Mamo, B.; Ponzevera, Emmanuel; Pelleter, Ewan; Baudin, F.; Roubi, Angelique; Cheron, Sandrine; Boissier, Audrey; Gayet, Nicolas; Bermell-fleury, S.; Pitel, M.; Guyader, Vivien; Lesongeur, Francoise; Savignac, F..
In this preliminary study, we investigate living (stained) foraminifera from the Sea of Marmara. We focus on the faunal composition and geochemical signatures (trace elements, carbon and oxygen stable isotopes) in foraminiferal tests at two deep-sea sites (329 and ~1240 m depth respectively). Documented by ROV observations and sampling, both study areas are heterogeneous (including bacterial mats and carbonate concretions), proximal to cold seeps and consist of dysoxic bottom water (O2<20 µmol/L). The prevailing dysoxia at both study areas restricts foraminiferal diversity to very low values (S<9, H’<0.97). Stress-tolerant species Bolivina vadescens and Globobulimina affinis dominate living faunas at both sites. The highest foraminiferal standing...
Tipo: Text Palavras-chave: Living (stained) benthic foraminifera; Sea of Marmara; Extreme ecosystems; Trace elements; Stable isotopes.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00416/52774/53646.pdf
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Rare earth elements and neodymium isotopes in world river sediments revisited ArchiMer
Bayon, Germain; Toucanne, Samuel; Skonieczny, Charlotte; Andre, L.; Bermell, Sylvain; Cheron, Sandrine; Dennielou, Bernard; Etoubleau, Joel; Freslon, Nicolas; Gauchery, T.; Germain, Yoan; Jorry, Stephan; Menot, G.; Monin, L.; Ponzevera, Emmanuel; Rouget, M. -l.; Tachikawa, K.; Barrat, Jean-alix.
Over the past decades, rare earth elements (REE) and their radioactive isotopes have received tremendous attention in sedimentary geochemistry, as tracers for the geological history of the continental crust and provenance studies. In this study, we report on elemental concentrations and neodymium (Nd) isotopic compositions for a large number of sediments collected near the mouth of rivers worldwide, including some of the world’s major rivers. Sediments were leached for removal of non-detrital components, and both clay and silt fractions were retained for separate geochemical analyses. Our aim was to re-examine, at the scale of a large systematic survey, whether or not REE and Nd isotopes could be fractionated during Earth surface processes. Our results...
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Ano: 2015 URL: http://archimer.ifremer.fr/doc/00276/38733/37249.pdf
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Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments ArchiMer
Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Sireau, Teddy; Mojtahid, Meryem; Metzger, Edouard; Brach-papa, Christophe.
In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems,...
Tipo: Text Palavras-chave: Coastal pollution; Coastal biogeochemistry; Geochemical tracers; Metal isotopes; Trace metal; Anthropogenic contamination.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00490/60188/67760.pdf
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The Amsterdam-St. Paul Plateau: A complex hot spot/DUPAL-flavored MORB interaction ArchiMer
Janin, M.; Hemond, Christophe; Maia, Marcia; Nonnotte, Philippe; Ponzevera, Emmanuel; Johnson, K. T. M..
The Amsterdam-St Paul (ASP) oceanic plateau results from the interaction between the ASP hot spot and the Southeast Indian ridge. A volcanic chain, named the Chain of the Dead Poets (CDP), lies to its northward tip and is related to the hot spot intraplate activity. The ASP plateau and CDP study reveals that ASP plume composition is inherited from oceanic crust and pelagic sediments recycled in the mantle through a 1.5 Ga subduction process. The ASP plateau lavas have a composition (major and trace elements and Sr-Nd-Pb-Hf isotopes) reflecting the interaction between ASP plume and the Indian MORB mantle, including some clear DUPAL input. The Indian upper mantle below ASP plateau is heterogeneous and made of a depleted mantle with lower continental crust...
Tipo: Text Palavras-chave: DUPAL anomaly; Indian Ocean; Sr-Nd-Pb-Hf isotopes; Ridge-hot spot interaction.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00102/21368/19008.pdf
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Intensifying Weathering and Land Use in Iron Age Central Africa ArchiMer
Bayon, Germain; Dennielou, Bernard; Etoubleau, Joel; Ponzevera, Emmanuel; Toucanne, Samuel; Bermell, Sylvain.
About 3000 years ago, a major vegetation change occurred in Central Africa, when rainforest trees were abruptly replaced by savannas. The consensus is that the forest disturbance was caused by climate change. We show here that chemical weathering in Central Africa, reconstructed from geochemical analyses of a marine sediment core, intensified abruptly at the same period, departing significantly from the long-term weathering fluctuations related to the Late Quaternary climate. Evidence that this weathering event was also contemporaneous with the migration of Bantu-speaking farmers across Central Africa suggests that human land-use intensification at that time already had a significant impact on the rainforest.
Tipo: Text
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00069/18031/15574.pdf
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Abrupt drainage cycles of the Fennoscandian Ice Sheet ArchiMer
Soulet, Guillaume; Menot, Guillemette; Bayon, Germain; Rostek, Frauke; Ponzevera, Emmanuel; Toucanne, Samuel; Lericolais, Gilles; Bard, Edouard.
Continental ice sheets are a key component of the Earth’s climate system, but their internal dynamics need to be further studied. Since the last deglaciation, the northern Eurasian Fennoscandian Ice Sheet (FIS) has been connected to the Black Sea (BS) watershed, making this basin a suitable location to investigate former ice-sheet dynamics. Here, from a core retrieved in the BS, we combine the use of neodymium isotopes, high-resolution elemental analysis, and biomarkers to trace changes in sediment provenance and river runoff. We reveal cyclic releases of meltwater originating from Lake Disna, a proglacial lake linked to the FIS during Heinrich Stadial 1. Regional interactions within the climate–lake–FIS system, linked to changes in the availability of...
Tipo: Text Palavras-chave: Ice dynamics; Meltwater routing; European hydrographic network.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00134/24489/22516.pdf
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Multidisciplinary investigation on cold seeps with vigorous gas emissions in the Sea of Marmara (MarsiteCruise): Strategy for site detection and sampling and first scientific outcome ArchiMer
Ruffine, Livio; Ondreas, Helene; Blanc-valleron, Marie-madeleine; Teichert, Barbara M. A.; Scalabrin, Carla; Rinnert, Emmanuel; Birot, Dominique; Croguennec, Claire; Ponzevera, Emmanuel; Pierre, Catherine; Donval, Jean-pierre; Alix, Anne-sophie; Germain, Yoan; Bignon, Laurent; Etoubleau, Joel; Caprais, Jean-claude; Knoery, Joel; Lesongeur, Francoise; Thomas, Bastien; Roubi, Angelique; Legoix, Ludovic Nicolas; Burnard, Pete; Chevalier, Nicolas; Lu, Hailong; Dupre, Stephanie; Fontanier, Christophe; Dissard, Delphine; Olgun, Nazli; Yang, Hailin; Strauss, Harald; Ozaksoy, Volkan; Perchoc, Jonathan; Podeur, Christian; Tarditi, Corinne; Ozbeki, Eyyup; Guyader, Vivien; Marty, Bernard; Madre, David G; Pitel-roudaut, Mathilde; Grall, Celine; Embriaco, Davide; Polonia, Mina; Gasperini, Lucas; Cagatay, M. Namik; Henry, Pierre; Geli, Louis.
MarsiteCruise was undertaken in October/November 2014 in the Sea of Marmara to gain detailed insight into the fate of fluids migrating within the sedimentary column and partially released into the water column. The overall objective of the project was to achieve a more global understanding of cold-seep dynamics in the context of a major active strike-slip fault. Five remotely operated vehicle (ROV) dives were performed at selected areas along the North Anatolian Fault and inherited faults. To efficiently detect, select and sample the gas seeps, we applied an original procedure. It combines sequentially (1) the acquisition of ship-borne multibeam acoustic data from the water column prior to each dive to detect gas emission sites and to design the tracks of...
Tipo: Text Palavras-chave: Acoustic survey; Authigenic carbonates; Biogeochemistry; Chemical analyses; Cold seeps; Dissolved major elements; Fluid seepage; Geology; In situ Raman analysis; Methane; ROV dives.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00433/54434/55783.pdf
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Rock-type control of Ni, Cr, and Co phytoavailability in ultramafic soils ArchiMer
Pedziwiatr, Artur; Kierczak, Jakub; Waroszewski, Jaroslaw; Ratie, Gildas; Quantin, Cecile; Ponzevera, Emmanuel.
Background and aims Ultramafic soils constitute an extreme environment for plants because of specific physico-chemical properties and the presence of Ni, Cr, and Co. We hypothesized that type of ultramafic parent rock depending on their origin affects the composition of soils and plants. Therefore, phytoavailability of metals would be higher in soil derived from serpentinized peridotite compared to serpentinite because of differences in susceptibility of minerals to weathering. Results Based on DTPA-CaCl2 extractions, we noted that soil derived from the serpentinized peridotite is characterized by a higher phytoavailability of Ni compared to soil derived from the serpentinite. On the contrary, plant species growing on soil derived from the serpentinite...
Tipo: Text Palavras-chave: Peridotite; Serpentinite; Excluders; Ni isotopes; Ca/mg ratio.
Ano: 2018 URL: http://archimer.ifremer.fr/doc/00414/52537/53344.pdf
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