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Registros recuperados: 39
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Experimental study of gas hydrate formation and destabilisation using a novel high-pressure apparatus ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Charlou, Jean-luc; Cremiere, Antoine; Zehnder, B. H..
A novel variable-volume type high-pressure apparatus has been designed, constructed and used for gas hydrate investigations. The apparatus has an operating temperature ranging from 253 K to 473 K and pressure ranging from 0.1 MPa to 60 MPa. Its central component consists of a viewing windows cell to which several sensors or analytical instruments can be connected. At its present configuration, a Raman spectrometer and a gas chromatograph are connected for the study of the liquid (or solid) and the gas phases respectively. The apparatus was used for the study of two different systems. The first system was composed of carbon dioxide (CO2) and water for which the hydrate formation and dissolution has been investigated by injecting water into liquid CO2. The...
Tipo: Text Palavras-chave: Gas hydrates; Thermogenic; Carbon dioxide; Formation; Destabilisation; Novel apparatus; Raman spectroscopy; Chromatography.
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00006/11759/8472.pdf
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Deepwater mantle He-3 plumes over the northern Mid-Atlantic Ridge (36 degrees N-40 degrees N) and the Azores Platform - art. no. Q03010 ArchiMer
Jean Baptiste, P; Fourre, E; Dapoigny, A; Charlou, Jean-luc; Donval, Jean-pierre.
As part of a multidisciplinary project aimed at studying mid-ocean ridge processes near the Azores, fifty water column profiles were analyzed for He-3/He-4 ratios in dissolved helium (a well-known hydrothermal tracer) from 36 degrees N to 40 degrees N along the Mid-Atlantic Ridge (MAR) and over the Azores Plateau. As expected, large delta(3) He anomalies could be observed over the Rainbow, Lucky Strike, and Menez Gwen hydrothermal sites. The main finding of the present study is the discovery of a large hydrothermal 3 He plume north of the Acor Fracture Zone (north AFZ site), with a CH4/He-3 ratio indicative of a basaltic-hosted hydrothermal system. Clear He-3 and CH4 anomalies, likely corresponding to unknown venting sites too, were also detected in the...
Tipo: Text Palavras-chave: Hydrothermal processes; Helium 3; Mid ocean ridges.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-3876.pdf
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ROV study of a giant pockmark on the Gabon continental margin ArchiMer
Ondreas, Helene; Olu, Karine; Fouquet, Yves; Charlou, Jean-luc; Gay, Aurelien; Dennielou, Bernard; Donval, Jean-pierre; Fifis, Alexis; Nadalig, Thierry; Cochonat, Pierre; Cauquil, E; Bourillet, Jean-francois; Le Moigne, Morgan; Sibuet, Myriam.
A giant, 800-m wide pockmark, called Regab, was discovered along the Equatorial African margin at 3160-m water depth and was explored by remote operated vehicle (ROV) as part of the Zaiango (1998-2000) and Biozaire (2001-2003) projects carried out conjointly by TOTAL and a number of French research institutes. A microbathymetric map obtained using the ROV sensors shows that the pockmark actually consists of a cluster of smaller pockmarks aligned N70 along a 15-m deep depression. Methane was recorded all over the pockmark, the highest values along the axis of the depression where massive carbonate crusts and dense seep communities were also found. Several faunal species belong to the Vesicomyidae and Mytilidae bivalve families, as well as to Siboglinidae...
Tipo: Text Palavras-chave: Gabon; Microbathymetric map; ROV; Exploration; Pockmark; Equatorial African margin.
Ano: 2005 URL: http://archimer.ifremer.fr/doc/2005/publication-1239.pdf
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Campagne RIDELENTE: Structure de la dorsale Atlantique - Hétérogénéité du manteau et hydrothermalisme ArchiMer
Bougault, Henri; Appriou, P; Bienvenu, P; Cambon, Pierre; Charlou, Jean-luc; Collette, B; Donval, Jean-pierre; Dosso, Laure; Floch, G; Fouquet, Yves.
Tipo: Text
Ano: 1990 URL: http://archimer.ifremer.fr/doc/00070/18105/15653.pdf
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Comparison of microbial communities associated with three Atlantic ultramafic hydrothermal systems ArchiMer
Roussel, Erwan; Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Fouquet, Yves; Querellou, Joel; Prieur, Daniel; Cambon-bonavita, Marie-anne.
The distribution of Archaea and methanogenic, methanotrophic and sulfate-reducing communities in three Atlantic ultramafic-hosted hydrothermal systems (Rainbow, Ashadze, Lost City) was compared using 16S rRNA gene and functional gene (mcrA, pmoA and dsrA) clone libraries. The overall archaeal community was diverse and heterogeneously distributed between the hydrothermal sites and the types of samples analyzed (seawater, hydrothermal fluid, chimney and sediment). The Lost City hydrothermal field, characterized by high alkaline warm fluids (pH>11; T<95 °C), harbored a singular archaeal diversity mostly composed of unaffiliated Methanosarcinales. The archaeal communities associated with the recently discovered Ashadze 1 site, one of the deepest active...
Tipo: Text Palavras-chave: Archaea; Hydrothermal vent; Mid-Atlantic Ridge; 16S rRNA gene; Sediment; Ultramafic.
Ano: 2011 URL: http://archimer.ifremer.fr/doc/00067/17836/15573.pdf
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Phase Equilibria of the CH4-CO2 Binary and the CH4-CO2-H2O Ternary Mixtures in the Presence of a CO2-Rich Liquid Phase ArchiMer
Legoix, Ludovic; Ruffine, Livio; Donval, Jean-pierre; Haeckel, Matthias.
The knowledge of the phase behavior of carbon dioxide (CO2)-rich mixtures is a key factor to understand the chemistry and migration of natural volcanic CO2 seeps in the marine environment, as well as to develop engineering processes for CO2 sequestration coupled to methane (CH4) production from gas hydrate deposits. In both cases, it is important to gain insights into the interactions of the CO2-rich phase—liquid or gas—with the aqueous medium (H2O) in the pore space below the seafloor or in the ocean. Thus, the CH4-CO2 binary and CH4-CO2-H2O ternary mixtures were investigated at relevant pressure and temperature conditions. The solubility of CH4 in liquid CO2 (vapor-liquid equilibrium) was determined in laboratory experiments and then modelled with the...
Tipo: Text Palavras-chave: Gas hydrate; CH4; CO2-rich mixtures; Phase equilibria; Soave-Redlich-Kwong (SRK) cubic equation of state (EoS).
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00414/52538/53349.pdf
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Volcanic and hydrothermal processes in submarine calderas: the Kulo Lasi example (SW Pacific) ArchiMer
Fouquet, Yves; Pelleter, Ewan; Konn, Cecile; Chazot, Gilles; Dupre, Stephanie; Alix, Anne-sophie; Cheron, Sandrine; Donval, Jean-pierre; Guyader, Vivien; Etoubleau, Joel; Charlou, Jean-luc; Labanieh, Shasa; Scalabrin, Carla.
The study area is located at the transition between the northern end of the Tonga Trench and the North Fiji fracture zone, where tectonic movements are reputed to be the fastest in the world. To the southeast of Futuna Island, a broad area of volcanism occurs within a region characterized by a change in the tectonic fabric between a NE-SW oriented volcanic graben and the N-S oriented Alofi ridge. In 2010, the active volcano Kulo Lasi, which represents the most recent volcanic episode in the Futuna area, was discovered in the center of this extensive volcanic zone. Kulo Lasi is a 20 km diameter shield volcano that rises 400 m above the seafloor. It is composed of basaltic to trachy-andesitic lava with no obvious geochemical affinity with the Tonga...
Tipo: Text Palavras-chave: Subaqueous volcanism; Hydrothermal activity; Kulo Lasi caldera; Sulfides; SW Pacific.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00445/55633/57279.pdf
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Extensive magmatic and hydrothermal activity in Manus Basin ArchiMer
Auzende, Jean-marie; Ishibashi, J; Beaudouin, Y; Charlou, Jean-luc; Delteil, J; Donval, Jean-pierre; Fouquet, Yves; Gouillou, Jp; Ildefonse, B; Kimura, H; Nishio, Y; Knoery, Joel; Ruollan, E.
In 1995, a joint French‐Japanese cruise (ManusFlux) explored the Manus Spreading Center and some sites of the South Eastern Rift in the Manus Basin off the coast of Papua New Guinea (Figure 1) with the Japanese submersible [Auzende et al., 1996; Gamo et al., 1997]. In the framework of this joint project, called New STARMER, the French and Japanese teams completed the Manaute cruise with the R/V LAtalante and the Ifremer submersible Nautile in April and May 2000. The Manaute cruise explored and sampled volcanic and hydrothermal sites in the eastern part of Manus Basin and on the spreading axis of the Western Ridge (WR). The eastern part of the Manus Basin (Figure 2) was interpreted as a stretched‐back arc basin crust showing alternatively elongated ridges...
Tipo: Text
Ano: 2000 URL: http://archimer.ifremer.fr/doc/00069/18055/15597.pdf
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Natural gas hydrates investigated by X-ray synchrotron diffraction ArchiMer
Chazallon, B; Bourry, Christophe; Charlou, Jean-luc; Donval, Jean-pierre; Brunelli, M; Focsa, C.
Tipo: Text
Ano: 2007 URL: http://archimer.ifremer.fr/doc/00068/17924/15460.pdf
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Analysis of light hydrocarbons in marine sediments by headspace technique: Optimization using design of experiments ArchiMer
Donval, Jean-pierre; Charlou, Jean-luc; Lucas, L..
Headspace technique is a common method to analyze light hydrocarbons in deep marine sediments. The use of an automatic headspace sampler instead of a manual injection is the guarantee for a better repeatability and furthermore it is less time consuming. But to increase the sensitivity and therefore, to achieve a better detection limit, it is necessary to optimize the automatic headspace sampler parameters. The theory of design of experiments was applied here by studying them. As a response, methane, which is an important gas in marine sediments, was chosen for its short analysis time. Regarding the parameters for automatic headspace sampler, eight variables were selected and then, a screening of them was carried out with a fractional factorial design to...
Tipo: Text Palavras-chave: Design of experiments; Headspace technique; Gas; Sediments.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-6235.pdf
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Pore water geochemistry at two seismogenic areas in the Sea of Marmara ArchiMer
Ruffine, Livio; Germain, Yoan; Polonia, Alina; De Prunele, Alexis; Croguennec, Claire; Donval, Jean-pierre; Pitel-roudaut, Mathilde; Ponzevera, Emmanuel; Caprais, Jean-claude; Brandily, Christophe; Grall, Celine; Bollinger, Claire; Geli, Louis; Gasperini, Luca.
Within the Sea of Marmara, the highly active North Anatolian Fault (NAF) is responsible for major earthquakes (Mw>=7), and acts as a pathway for fluid migration from deep sources to the seafloor. This work reports on pore water geochemistry from three sediment cores collected in the Gulfs of Izmit and Gemlik, along the Northern and the Middle strands of the NAF, respectively. The resulting data set shows that anaerobic oxidation of methane (AOM) is the major process responsible for sulfate depletion in the shallow sediment. In the Gulf of Gemlik, depth concentration profiles of both sulfate and alkalinity exhibit a kink-type profile. The Sulfate Methane Transition Zone (SMTZ) is located at moderate depth in the area. In the Gulf of Izmit, the low...
Tipo: Text Palavras-chave: Anaerobic oxidation of methane; North Anatolian Fault; Pore water geochemistry; Sea of Marmara; Seismic activity.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00272/38339/36570.pdf
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Multiple gas reservoirs are responsible for the gas emissions along the Marmara fault network ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Cagatay, M. Namik; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Geli, Louis.
On continental margins, upward migration of fluids from various sources and various subsurface accumulations, through the sedimentary column to the seafloor, leads to the development of cold seeps where chemical compounds are discharged into the water column. MarsiteCruise was undertaken in November 2014 to investigate the dynamics of cold seeps characterized by vigorous gas emissions in the Sea of Marmara (SoM). A previous paper published by Bourry et al. (2009) presented the gas geochemistry of three seeps sampled along three different segments in the SoM. Their findings showed that the seeps were sourced by three different reservoirs. In this paper, seventeen seeps were investigated to determine the gas sources, unravel reservoir contributions, and...
Tipo: Text Palavras-chave: Abiotic CO2-source; Gas bubbles; Molecular and isotopic compositions; Primary and secondary methanogenesis; Sea of Marmara; Seeps; Thermogenic gases.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00411/52203/52926.pdf
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Gas Seepage along the Edge of the Aquitaine Shelf (France): Origin and Local Fluxes ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Bignon, Laurent; Birot, Dominique; Battani, Anne; Bayon, Germain; Caprais, Jean-claude; Lanteri, Nadine; Levache, Denis; Dupre, Stephanie.
During the scientific expedition GAZCOGNE2 at the Bay of Biscay nine gas seeps were sampled for the first time and their flux was measured using an in situ pressure-preservation sampler (PEGAZ, ©IFREMER). Overall, three sites were investigated to determine the nature and the origin of the gases bubbling at the seafloor and forming acoustic plumes into the water column, as this was the question raised fromthe first geologic study of the area.This has guided our study and accordingly corresponds to themain purpose of the present article.Thus, themolecular and isotopic (𝛿D and 𝛿13C) analyses revealed that the gas seeps were primarily composed of methane. Both methane and ethane are of microbial origin, and the former has been generated by...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00394/50579/51270.pdf
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Hydrothermal methane venting between 12°N and 26°N along the Mid-Atlantic Ridge ArchiMer
Charlou, Jean-luc; Donval, Jean-pierre.
Hydrographic surveys along the Mid-Atlantic Ridge (MAR) between 12°N and 26°N, carried out from 1984 to 1990, show a variable pattern of CH4-rich water column plumes. The vertical distribution of CH4 at stations located every 20–40 km is presented along this 1200-km-long section of the MAR. CH4 venting is clearly demonstrated. CH4-enriched fluids rise from vents as plumes; spreading is confined to the axial valley due to the topography of the MAR. CH4 contents from 45 nmol to 675 nmol/kg are measured in the buoyant plumes above the two active hydrothermal sites (MARK 23°N; TAG 26°N) known at present, whereas CH4 anomalies up to 3.6 nmol/kg are typically observed in plumes emitted either on the inner floor, on the walls, and/or at the top of the rift...
Tipo: Text
Ano: 1993 URL: http://archimer.ifremer.fr/doc/00070/18103/15651.pdf
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Extensive hydrothermal activity revealed by multi-tracer survey in the Wallis and Futuna region (SW Pacific) ArchiMer
Konn, Cecile; Fourre, E.; Jean-baptiste, P.; Donval, Jean-pierre; Guyader, Vivien; Birot, Dominique; Alix, Anne-sophie; Gaillot, Arnaud; Perez, Florian; Dapoigny, A.; Pelleter, Ewan; Resing, J. A.; Charlou, Jean-luc; Fouquet, Yves.
The study area is close to the Wallis and Futuna Islands in the French EEZ. It exists on the western boundary of the fastest tectonic area in the world at the junction of the Lau and North-Fiji basins. At this place, the unstable back-arc accommodates the plate motion in three ways: (i) the north Fiji transform fault, (ii) numerous unstable spreading ridges, and (iii) large areas of recent volcanic activity. This instability creates bountiful opportunity for hydrothermal discharge to occur. Based on geochemical (CH4, TDM, 3He) and geophysical (nephelometry) tracer surveys: (1) no hydrothermal activity could be found on the Futuna Spreading Center (FSC) which sets the western limit of hydrothermal activity; (2) four distinct hydrothermal active areas were...
Tipo: Text
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00347/45848/45505.pdf
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Hydrothermalisme oceanique, exploration, methodologie et instrumentation associee ArchiMer
Bougault, Henri; Charlou, Jean-luc; Donval, Jean-pierre; Fouquet, Yves; Pelle, H.
Responsible for large exchanges between the Ocean and the Lithosphere, oceanic hydrothermalism covers wide scientific domains, from the ocean chemistry to metallogeny. The exploration covers all scales, from the hydrothermal site to the Mid-oceanic ridge system. Modern bathymetry and imagery are required. Physical and chemical anomalies created in the ocean are used to detect and map its distribution. A specific effort in the field of ROV (Remote Operated Vehicle) is needed to acquire data at the corresponding working scale.
Tipo: Text Palavras-chave: ISE; East Pacific Rise A; Mid Atlantic Ridge Oceanic crust Cartography Marine technology Underwater exploration Unmanned vehicles Imagery Bathymetry Hydrothermal activity.
Ano: 1990 URL: http://archimer.ifremer.fr/doc/1990/acte-1159.pdf
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A detailed study of the Lucky-Strike hydrothermal site and discovery of a new hydrothermal site: « Menez-Gwen ». Preliminary results of DIVA 1 cruise (5-29 May, 1994) ArchiMer
Fouquet, Yves; Charlou, Jean-luc; Donval, Jean-pierre; Radford-knoery, Joel; Pelle, P; Ondreas, Helene; Lourenco, N; Segonzac, Michel; Tivey, Mk.
Tipo: Text
Ano: 1994 URL: http://archimer.ifremer.fr/doc/00070/18134/15682.pdf
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Distribution and behavior of dissolved hydrogen sulfide in hydrothermal plumes ArchiMer
Radford Knoery, Joel; German, C; Charlou, Jean-luc; Donval, Jean-pierre; Fouquet, Yves.
Through the deep ocean, hydrothermal plumes disperse high concentrations of key chemical tracers including He-3, CH4, Mn, Fe, H2S, etc. This paper focuses on the distribution and behavior of total dissolved sulfide (sulfide hereafter) in hydrothermal plumes to show that its plume concentration decreases to subnanomolar a few kilometers from the vents. We also report on sulfide removal rates determined at in situ conditions; we observe that they are two orders of magnitude greater than for open ocean seawater, consistent with sulfide being detected only in the vicinity of hydrothermal vents. From our observations, we infer that the sole presence of sulfide in hydrothermal plumes locates active venting at the kilometer scale.
Tipo: Text Palavras-chave: Chemical oceanography; Mid ocean ridges; Metals; Helium isotopes; Methane; Tracers; Hydrogen sulphide; Plumes; Hydrothermal activity.
Ano: 2001 URL: https://archimer.ifremer.fr/doc/2001/publication-688.pdf
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Corrigendum to “Multiple gas reservoirs are responsible for the gas emissions along the Marmara fault network” ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Çağatay, M. Namık; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Géli, Louis.
The authors regret a mistake on the value of δ13C of methane for one of the investigated gas samples. This concerns sample MRS-DV3-PE03, taken as end member and for which the correct methane δ13C value is -41.9‰ and not -34‰. The sample was collected at in situ pressure (~100 bars) from a CO2-rich seep, in a liquid state. The mistake likely results from a partial extraction (i.e. done by expansion of the sampler volume to allow vaporization) of the pressurized sample for subsampling. Additional analyses have been carried out from fully vaporized samples. This error has resulted in updating the geochemical diagrams used for the discussion, and revising both the gas origin for sample MRS-DV3-PE03 and the section entitled “Delineation of sources, reservoirs...
Tipo: Text
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00471/58253/61076.pdf
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A comparative Raman spectroscopic study of natural gas hydrates collected at different geological sites ArchiMer
Chazallon, B; Focsa, C; Charlou, Jean-luc; Bourry, Christophe; Donval, Jean-pierre.
Intact natural gas hydrates recovered on the West Aftican margin in the South Atlantic Ocean (ZaiAngo and Neris IIrojects) and from the Norwegian Sea (Hakon Mosby Mud Volcano) are investigated by micro-Raman spectroscopy at ambient pressure and low temperature. The gas hydrates collected at different geological sites contain a high methane concentration relative to other minor components that are slightly dispersed in the samples. They crystallize in a type I cubic lattice structure as also confirmed by our preliminary synchrotron diffraction results obtained on the ZaiAngo specimen. However, detailed analysis of selected microscopic areas reveals a variation in the gas distribution among the different specimens. Trace amounts of CO2 and H2S can be...
Tipo: Text Palavras-chave: Micro Raman spectroscopy; H2S hydrate; CH4 hydrate; Natural clathrate hydrates.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/publication-4303.pdf
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