|
|
|
| Registros recuperados: 32 | |
|
|
| Davies, Peter; Sohier, L.; Cognard, J. -y.; Bourmaud, A.; Choqueuse, Dominique; Rinnert, Emmanuel; Creac'Hcadec, R.. |
| While the geometry of aerospace assemblies is carefully controlled, for many industrial applications such as marine structures bond line thickness can vary significantly. In this study epoxy adhesive joints of different thicknesses between aluminium substrates have been characterized using physico-chemical analyses (differential scanning calorimetry, DSC; dynamic mechanical analysis, DMA; spectroscopy), nano-indentation and mechanical testing. Thermal analyses indicated no influence of thickness on structure. Nano-indentation revealed no evidence of an interphase at the metal/epoxy interface, nor any change in modulus for different thicknesses, though Raman spectroscopy suggested there may be slight variations in composition close to the substrates.... |
| Tipo: Text |
Palavras-chave: Arcan; Mechanical properties; Aluminium; Epoxy. |
| Ano: 2009 |
URL: http://archimer.ifremer.fr/doc/2009/publication-6638.pdf |
| |
|
|
| Baillieul, Marion; Baudet, Emeline; Michel, Karine; Moreau, Jonathan; Němec, Petr; Boukerma, Kada; Colas, Florent; Charrier, Joël; Bureau, Bruno; Rinnert, Emmanuel; Nazabal, Virginie. |
| he objective of this study is to demonstrate the successful functionalization of the surface of a chalcogenide infrared waveguide with the ultimate goal of developing an infrared micro-sensor device. First, a polyisobutylene coating was selected by testing its physico-chemical compatibility with a Ge-Sb-Se selenide surface. To simulate the chalcogenide platform infrared sensor, the detection of benzene, toluene, and ortho-, meta- and para-xylenes was efficaciously performed using a polyisobutylene layer spin-coated on 1 and 2.5 µm co-sputtered selenide films of Ge28Sb12Se60 composition deposited on a zinc selenide prism used for attenuated total reflection spectroscopy. The thickness of the polymer coating was optimized by attenuated total reflection... |
| Tipo: Text |
Palavras-chave: Optical infrared sensor; Chalcogenide glasses; Mid-infrared; Mono-aromatic hydrocarbons; Natural waters; BTEXs; PAHs. |
| Ano: 2021 |
URL: https://archimer.ifremer.fr/doc/00687/79947/82867.pdf |
| |
|
|
| Verger, F.; Pain, T.; Nazabal, V.; Boussard-pledel, C.; Bureau, Bruno; Colas, Florent; Rinnert, Emmanuel; Boukerma, Kada; Compere, Chantal; Guilloux-viry, M.; Deputier, S.; Perrin, A.; Guin, J. P.. |
| The development of infrared sensing platform requires adapted materials. In this work, we used sputtered gold nanoparticles on a chalcogenide glass to demonstrate that these infrared materials can be used as substrate for surface enhanced infrared absorption (SEIRA) spectroscopy. The sputtering parameters were optimized to get the highest possible enhancement. To assess it, a self-assembled monolayer of 4-nitrothiophenol was used. These preliminary results are promising and pave the way for various configurations of waveguide for integrated optical components. (C) 2012 Elsevier B.V. All rights reserved. |
| Tipo: Text |
Palavras-chave: Chalcogenide glass; Sputtering; Gold nanoparticles; 4-Nitrothiophenol; SEIRA; Surface enhanced infrared absorption. |
| Ano: 2012 |
URL: http://archimer.ifremer.fr/doc/00116/22748/20613.pdf |
| |
|
|
| Betelu, S; Tijunelyte, I; Boubekeur Lecaque, L; Ignatiadis, I; Schnepf, Ac; Guenin, E; Bouchemal, N; Felidj, N; Rinnert, Emmanuel; Lamy De La Chapelle, M. |
| The objective of the present work is to use Raman spectroscopy for characterizing, the fate of phenyl-derivatives, from phenyl-amines to aryl-diazonium derivatives (ADD). Four ADD were investigated: (i) benzene diazoniumtetrafluoroborate (DS), (ii) 4-decyl benzene diazoniumtetrafluoroborate (DS-C10H21), (iii) 4-carboxybenzene diazoniumtetrafluoroborate (DS-COOH) and (iv) 4-(aminoethyl) benzene diazoniumtetrafluoroborate (DS-(CH2)2NH2). Raman investigation of the above ADD confirmed the existence of an N≡N bond stretching in the range of 2285-2305 cm-1. Moreover, the strong band related to CH in plane-bending and C-N-stretching modes in the 1073-1080 cm-1 range, is a signature of phenyl derivatives stemming from ADD. Furthermore, we analyzed and discuss the... |
| Tipo: Text |
Palavras-chave: Phenyl-amines; Diazonium salts; Synthesis and characterization; Raman; DFT calculations. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00391/50262/50889.pdf |
| |
|
| |
|
|
| Delauney, Laurent; Boukerma, Kada; Bucas, Karenn; Coail, Jean-yves; Debeaumont, Mathieu; Forest, Bertrand; Garello, Celia; Guyader, Gerard; Le Bras, Yves; Peleau, Michel; Rinnert, Emmanuel. |
| Oceans environmental monitoring and seafloor exploitation need in situ sensors and optical devices (cameras, lights) in various locations and on various carriers in order to initiate and to calibrate environmental models or to operate underwater industrial process supervision. For more than 10 years Ifremer deploys in situ monitoring systems for various seawater parameters and in situ observation systems based on lights and HD Cameras. To be economically operational, these systems must be equipped with a biofouling protection dedicated to the sensors and optical devices used in situ. Indeed, biofouling, in less than 15 days [1] will modify the transducing interfaces of the sensors and causes unacceptable bias on the measurements provided by the in situ... |
| Tipo: Text |
|
| Ano: 2015 |
URL: http://archimer.ifremer.fr/doc/00349/45998/45667.pdf |
| |
|
|
| Baudet, Emeline; Gutierrez-arroyo, A.; Nemec, P.; Bodiou, L.; Lemaitre, J.; De Sagazan, O.; Lhermitte, H.; Rinnert, Emmanuel; Michel, K.; Bureau, B.; Charrier, J.; Nazabal, V.. |
| A micro-sensor based on selenide glasses for evanescent wave detection in mid-infrared spectral range was designed and fabricated. Ge-Sb-Se thin films were successfully deposited by radio-frequency magnetron sputtering. In order to characterize them spectroscopic ellipsometry, atomic force microscopy and contact angle measurements were employed to study near and middle infrared refractive index, surface roughness and the wettability, respectively. Selenide sputtered films were micro-patterned by means of reactive ion etching with inductively coupled plasma process enabling single-mode propagation at a wavelength of 7.7 µm for a waveguide width between 8 and 12 µm. Finally, optical waveguide surface was functionalized by deposition of a hydrophobic polymer,... |
| Tipo: Text |
|
| Ano: 2016 |
URL: https://archimer.ifremer.fr/doc/00346/45709/45337.pdf |
| |
|
|
| Betelu, Stephanie; Tijunelyte, Inga; Boubekeur-lecaque, Leila; Ignatiadis, Ioannis; Ibrahim, Joyce; Gaboreau, Stephane; Berho, Catherine; Toury, Timothee; Guenin, Erwann; Lidgi-guigui, Nathalie; Felidj, Nordin; Rinnert, Emmanuel; Lamy De La Chapelle, Marc. |
| Gold nanostructures (GNS) were chemically functionalized using four different diazonium salts: benzene-diazonium-tetrafluoroborate (DS), 4-decylbenzene-diazonium-tetrafluoroborate (DS-C10H21), 4-carboxybenzene-diazonium-tetrafluoroborate (DS-COOH), and 4-(aminoethyl)-benzene-diazonium-tetrafluoroborate (DS-(CH2)(2)NH2). Effective chemical grafting on GNS was shown by surface-enhanced Raman spectroscopy (SERS); aromatic ring deformations in the range of 1570-1591 cm(-1) are of particular interest. The very strong band observed around 1075 cm(-1), related to CH in-plane bending for mono- and para-substituted benzenes (coupled with ring-N stretching mode), provided further irrefutable evidence of the grafting. SERS enhancement of these two bands ascertains... |
| Tipo: Text |
|
| Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00350/46139/46200.pdf |
| |
|
| |
|
|
| Decorbie, N.; Tijunelyte, I.; Gam-derouich, S.; Solard, J.; Lamouri, A.; Decorse, P.; Felidj, N.; Gauchotte-lindsay, C.; Rinnert, Emmanuel; Mangeney, C.; Lidgi-guigui, N.. |
| In this article, we propose a new strategy to build a sensor for easy handling and rapid analysis on-site. Our sensor is based on the combination of surface-enhanced Raman spectroscopy (SERS) and molecularly imprinted polymers (MIPs). SERS provides a strong sensitivity for the detection of trace molecules while MIPs offer a highly selective and specific recognition platform. The research presented here focuses on the detection of the interaction between a robust ultra-thin layer of MIPs and of paracetamol, the targeted molecule. This drug is an environmental emerging pollutant, i.e., a molecule whose presence and significance have not yet been elucidated, which gives rise to health and environmental concerns. The results are a combined analysis of the SERS... |
| Tipo: Text |
Palavras-chave: Sensor; SERS; Molecularly imprinted polymers; Emerging pollutant; Paracetamol; Independent component analysis. |
| Ano: 2020 |
URL: https://archimer.ifremer.fr/doc/00628/73962/73386.pdf |
| |
|
|
| Colas, Florent; Crassous, Marie-pierre; Laurent, Sebastien; Litaker, Richard W.; Rinnert, Emmanuel; Le Gall, Erwan; Lunven, Michel; Delauney, Laurent; Compère, Chantal. |
| Over the past decade Surface Plasmon Resonance (SPR) techniques have been applied to the measurement of numerous analytes. In this article, an SPR biosensor system deployed from an oceanographic vessel was used to measure dissolved domoic acid (DA), a common and harmful phycotoxin produced by certain microalgae species belonging to the genus Pseudo-nitzschia. During the biosensor deployment, concentrations of Pseudo-nitzschia cells were very low over the study area and measured DA concentrations were below detection. However, the in situ operational detection limit of the system was established using calibrated seawater solutions spiked with DA. The system could detect the toxin at concentrations as low as 0.1 ng mL−1 and presented a linear dynamic range... |
| Tipo: Text |
|
| Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00324/43481/42921.pdf |
| |
|
| |
|
|
| Peron, Olivier; Rinnert, Emmanuel; Toury, T.; De La Chapelle, M. Lamy; Compere, Chantal. |
| In the investigation of chemical pollutants, such as PAHs (Polycyclic Aromatic Hydrocarbons) at low concentration in aqueous medium, Surface-Enhanced Raman Scattering (SERS) stands for an alternative to the inherent low cross-section of normal Raman scattering. Indeed, SERS is a very sensitive spectroscopic technique due to the excitation of the surface plasmon modes of the nanostructured metallic film. The surface of quartz substrates was coated with a hydrophobic film obtained by silanization and subsequently reacted with polystyrene (PS) beads coated with gold nanoparticles. The hydrophobic surface of the SERS substrates pre-concentrates non-polar molecules such as naphthalene. Under laser excitation, the SERS-active substrates allow the detection and... |
| Tipo: Text |
|
| Ano: 2011 |
URL: http://archimer.ifremer.fr/doc/00026/13760/10890.pdf |
| |
|
|
| Salaun, Stephanie; Rinnert, Emmanuel; Compere, Chantal. |
| Cette étude s’inscrit dans le cadre du projet REI n°2010 34 0010 intitulé « Biofilms et corrosion d’alliages inoxydables en eau de mer », et a pour objectif de caractériser le biofilm responsable de l’activation de la corrosion des alliages inoxydables en eau de mer par une approche pluridisciplinaire, dans le but d’identifier les composantes responsables de ce type de corrosion. Ce biofilm spécifique est ainsi en cours de caractérisation par des méthodes de microscopie Apotome et de spectroscopie Raman. Ce poster a fait l'objet d'une présentation lors de l'Ecole thématique du CNRS : Voyage au centre d'un biofilm : physico-chimie des exopolymères de l'espace inter-cellulaire. Nancy, les 27 et 29 septembre 2011. |
| Tipo: Text |
|
| Ano: 2011 |
URL: http://archimer.ifremer.fr/doc/00057/16775/14228.pdf |
| |
|
|
| Verger, F.; Nazabal, V.; Colas, Florent; Nemec, P.; Cardinaud, C.; Baudet, E.; Chahal, R.; Rinnert, Emmanuel; Boukerma, Kada; Peron, Isabelle; Deputier, S.; Guilloux-viry, M.; Guin, J. P.; Lhermite, H.; Moreac, A.; Compere, Chantal; Bureau, Bruno. |
| The primary objective of this study is the development of transparent thin film materials in the IR enabling strong infrared absorption of organic compounds in the vicinity of metal nanoparticles by the surface plasmon effect. For developing these optical micro-sensors, hetero-structures combining gold nanoparticles and chalcogenide planar waveguides are fabricated and adequately characterized. Single As2S3 and Ge25Sb10Se65 amorphous chalcogenide thin films are prepared by radio-frequency magnetron sputtering. For the fabrication of gold nanoparticles on a chalcogenide planar waveguide, direct current sputtering is employed. Fabricated single layers or hetero-structures are characterized using various techniques to investigate the influence of deposition... |
| Tipo: Text |
|
| Ano: 2013 |
URL: http://archimer.ifremer.fr/doc/00170/28094/26679.pdf |
| |
|
|
| Baudet, Emeline; Gutierrez-arroyo, A.; Baillieul, Marion; Charrier, J.; Němec, P.; Bodiou, L.; Lemaitre, J.; Rinnert, Emmanuel; Michel, K.; Bureau, B.; Adam, J. L.; Nazabal, V.. |
| The detection of molecules dissolved in liquid medium can be envisaged by means of an optical integrated sensor operating in middle infrared range. The intended sensor is composed of a cladding and a guiding selenide sputtered layers transparent in middle infrared. Hence, Ge-Sb-Se thin films were selected in view of tailored refractive index contrast, successfully deposited by radio frequency magnetron sputtering and characterized. To maximize the evanescent field at a wavelength of 7.7 µm, a suitable selenide waveguide allowing measuring the optical transmitted power was designed by performing computer simulations based on the effective index method enabling single-mode propagation for a waveguide width between 8 and 12 µm. Selenide sputtered films were... |
| Tipo: Text |
Palavras-chave: Optical sensing and sensors; Mid-infrared; Integrated optics devices; Chalcogenide glasses; Thin films. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00389/50014/50603.pdf |
| |
|
|
| Tijunelyte, Inga; Dupont, Nathalie; Milosevic, Irena; Barbey, Carole; Rinnert, Emmanuel; Lidgi-guigui, Nathalie; Guenin, Erwann; De La Chapelle, Marc Lamy. |
| Among various cavitand molecules, cyclodextrins are extensively studied due to their ability to form host-guest complexes with small hydrophobic molecules. Aiming to explore cyclodextrin implementation on the scopes related to the environmental pollution monitoring or remediation, extensive studies for understanding the cyclodextrin-based host-guest complex formation with selected targeted substances are conducted. In this context, two polycyclic aromatic hydrocarbons, naphthalene and fluoranthene as well as toluene as a member of volatile organic compounds, were studied regarding their ability to encapsulate into cyclodextrin cavities. Synthesised complexes were examined by thermogravimetric analysis combined with Raman spectroscopy. The obtained results... |
| Tipo: Text |
Palavras-chave: Raman spectroscopy; Thermogravimetric analysis; Cyclodextrin; Polyaromatic hydrocarbons; PAH; Host-guest complex. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00417/52845/53907.pdf |
| |
|
|
| Ruffine, Livio; Ondreas, Helene; Blanc-valleron, Marie-madeleine; Teichert, Barbara M. A.; Scalabrin, Carla; Rinnert, Emmanuel; Birot, Dominique; Croguennec, Claire; Ponzevera, Emmanuel; Pierre, Catherine; Donval, Jean-pierre; Alix, Anne-sophie; Germain, Yoan; Bignon, Laurent; Etoubleau, Joel; Caprais, Jean-claude; Knoery, Joel; Lesongeur, Francoise; Thomas, Bastien; Roubi, Angelique; Legoix, Ludovic Nicolas; Burnard, Pete; Chevalier, Nicolas; Lu, Hailong; Dupre, Stephanie; Fontanier, Christophe; Dissard, Delphine; Olgun, Nazli; Yang, Hailin; Strauss, Harald; Ozaksoy, Volkan; Perchoc, Jonathan; Podeur, Christian; Tarditi, Corinne; Ozbeki, Eyyup; Guyader, Vivien; Marty, Bernard; Madre, David G; Pitel-roudaut, Mathilde; Grall, Celine; Embriaco, Davide; Polonia, Mina; Gasperini, Lucas; Cagatay, M. Namik; Henry, Pierre; Geli, Louis. |
| MarsiteCruise was undertaken in October/November 2014 in the Sea of Marmara to gain detailed insight into the fate of fluids migrating within the sedimentary column and partially released into the water column. The overall objective of the project was to achieve a more global understanding of cold-seep dynamics in the context of a major active strike-slip fault. Five remotely operated vehicle (ROV) dives were performed at selected areas along the North Anatolian Fault and inherited faults. To efficiently detect, select and sample the gas seeps, we applied an original procedure. It combines sequentially (1) the acquisition of ship-borne multibeam acoustic data from the water column prior to each dive to detect gas emission sites and to design the tracks of... |
| Tipo: Text |
Palavras-chave: Acoustic survey; Authigenic carbonates; Biogeochemistry; Chemical analyses; Cold seeps; Dissolved major elements; Fluid seepage; Geology; In situ Raman analysis; Methane; ROV dives. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00433/54434/55783.pdf |
| |
|
|
| Dribek, Mohamed; Rinnert, Emmanuel; Colas, Florent; Crassous, Marie-pierre; Thioune, Nene; David, Catalina; De La Chapelle, Marc; Compere, Chantal. |
| We demonstrated the use of a new organometallic nanoprobe for competitive surface-enhanced Raman scattering (SERS) immunoassay devoted to the detection of polycyclic aromatic hydrocarbons (PAH) such as benzo[a]pyrene (BaP) in seawater. The nanoprobes are gold nanoparticles (GNPs) labeled by a Raman reporter, the 5,5'-dithiobis(succinimidyl-2-nitrobenzoate) (DSNB) and functionalized with monoclonal antibodies anti-BaP. The antibodies are bound with a high specificity to the analyte while the GNPs enhanced the Raman scattering of the DSNB. This type of immunoassay involved the grafting of BaP onto a sensing surface. Thus, NH2-terminated self-assembled monolayer is formed on the surface of gold substrate using cysteamine. Amines finally reacted with... |
| Tipo: Text |
Palavras-chave: Biosensor; Surface-enhanced Raman scattering; Polycyclic aromatic hydrocarbons; Benzo[a]pyrene antibody; Organometallic nanoprobe. |
| Ano: 2017 |
URL: https://archimer.ifremer.fr/doc/00417/52844/53870.pdf |
| |
|
|
| Frere, L.; Paul-pont, I.; Rinnert, Emmanuel; Petton, Sebastien; Jaffre, J; Bihannic, Isabelle; Soudant, P.; Lambert, C.; Huvet, Arnaud. |
| The concentration and spatial distribution of microplastics in the Bay of Brest (Brittany, France) was investigated in two surveys. Surface water and sediment were sampled at nine locations in areas characterized by contrasting anthropic pressures, riverine influences or water mixing. Microplastics were categorized by their polymer type and size class. Microplastic contamination in surface water and sediment was dominated by polyethylene fragments (PE, 53–67%) followed by polypropylene (PP, 16–30%) and polystyrene (PS, 16–17%) microparticles. The presence of buoyant microplastics (PE, PP and PS) in sediment suggests the existence of physical and/or biological processes leading to vertical transfer of lightweight microplastics in the bay. In sediment (upper... |
| Tipo: Text |
Palavras-chave: Microplastic; Coastal ecosystem; Surface water; Sediment; Raman spectroscopy; Hydrodynamic; Dispersal particle modelling. |
| Ano: 2017 |
URL: https://archimer.ifremer.fr/doc/00379/48994/51083.pdf |
| |
| Registros recuperados: 32 | |
|
|
|
