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Experimental study of gas hydrate formation and destabilisation using a novel high-pressure apparatus ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Charlou, Jean-luc; Cremiere, Antoine; Zehnder, B. H..
A novel variable-volume type high-pressure apparatus has been designed, constructed and used for gas hydrate investigations. The apparatus has an operating temperature ranging from 253 K to 473 K and pressure ranging from 0.1 MPa to 60 MPa. Its central component consists of a viewing windows cell to which several sensors or analytical instruments can be connected. At its present configuration, a Raman spectrometer and a gas chromatograph are connected for the study of the liquid (or solid) and the gas phases respectively. The apparatus was used for the study of two different systems. The first system was composed of carbon dioxide (CO2) and water for which the hydrate formation and dissolution has been investigated by injecting water into liquid CO2. The...
Tipo: Text Palavras-chave: Gas hydrates; Thermogenic; Carbon dioxide; Formation; Destabilisation; Novel apparatus; Raman spectroscopy; Chromatography.
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00006/11759/8472.pdf
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U-Th isotope constraints on gas hydrate and pockmark dynamics at the Niger delta margin ArchiMer
Bayon, Germain; Henderson, Gideon M.; Etoubleau, Joel; Caprais, Jean-claude; Ruffine, Livio; Marsset, Tania; Dennielou, Bernard; Cauquil, Eric; Voisset, Michel; Sultan, Nabil.
The application of uranium-thorium dating methods to authigenic carbonates provides unique constraints on the temporal evolution of methane seeps at ocean margins. In this study, we report U-Th isotope measurements for carbonate breccias collected from within a hydrate-bearing pockmark located at the Niger Delta margin. These concretions were extracted from a carbonate-rich layer in the upper two meters of a sediment core (N2-KS-44; ~ 1200 m water depth), well above the present-day sulphate-methane transition zone (about 3 m depth) and the presence of gas hydrates in the sediment. The stratigraphy of core N2-KS-44 was established by tuning its downcore Al/Ti profile to a well-dated nearby reference core, and carbonate 230Th/U ages were calculated using...
Tipo: Text Palavras-chave: Gas hydrates; Pockmarks; U-series; Authigenic carbonates; Niger delta.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00286/39708/41518.pdf
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Gas Hydrates 2 : Geoscience Issues and Potential Industrial Applications ArchiMer
Ruffine, Livio; Broseta, Daniel; Desmedt, Arnaud.
In recent years, interest for clathrate hydrates has increased, motivated both by their fascinating physiochemical and thermophysical properties and their industrial and practical promises in various areas of application. Following the 2017 publication of Volume 1, which focused on fundamental aspects, modeling and characterization methods, this volume gathers a series of contributions addressing the natural occurrence of clathrate hydrates in sediments on Earth, with implications for the methane cycle, geohazards and energy resources, and then a few promising industrial applications. This volume is intended for scientists, PhD students and engineers who wish to start working on clathrate hydrates and/or want to acquire general knowledge in this area. It...
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Ano: 2018 URL: http://archimer.ifremer.fr/doc/00453/56507/58855.pdf
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Fluids and processes at the seismically active fault zone in the Sea of Marmara ArchiMer
Ruffine, Livio; Cagatay, M. Namik; Geli, Louis.
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00463/57473/59866.pdf
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Geological and biological diversity of seeps in the Sea of Marmara ArchiMer
Ondreas, Helene; Olu, Karine; Dupre, Stephanie; Scalabrin, Carla; Alix, Anne-sophie; Garrocq, Clément; Ruffine, Livio.
The Sea of Marmara hosts part of the North Anatolian Fault as an active submarine strike-slip fault. This area has suffered numerous earthquakes and presents a major seismic risk. Although the Sea of Marmara has been studied for many years, the link between geological morphostructures, the nature of fluids and biological communities is still rarely described. During the Marsite cruise (November 2014), dives with Remotely Operated Vehicle (ROV) VICTOR 6000 focused on detailed seafloor explorations of four different areas: the Central and Western highs and the Tekirdağ and Çinarcik basins. Based on 130 h of in situ videos, high-resolution seafloor mapping of seeps was conducted, emphasizing their significant geological and biological diversity from one...
Tipo: Text Palavras-chave: Sea of Marmara; Cold seeps; Fluids; Seismogenic faults; Chemosynthetic fauna; Methane.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00624/73623/73040.pdf
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Phase Equilibria of the CH4-CO2 Binary and the CH4-CO2-H2O Ternary Mixtures in the Presence of a CO2-Rich Liquid Phase ArchiMer
Legoix, Ludovic; Ruffine, Livio; Donval, Jean-pierre; Haeckel, Matthias.
The knowledge of the phase behavior of carbon dioxide (CO2)-rich mixtures is a key factor to understand the chemistry and migration of natural volcanic CO2 seeps in the marine environment, as well as to develop engineering processes for CO2 sequestration coupled to methane (CH4) production from gas hydrate deposits. In both cases, it is important to gain insights into the interactions of the CO2-rich phase—liquid or gas—with the aqueous medium (H2O) in the pore space below the seafloor or in the ocean. Thus, the CH4-CO2 binary and CH4-CO2-H2O ternary mixtures were investigated at relevant pressure and temperature conditions. The solubility of CH4 in liquid CO2 (vapor-liquid equilibrium) was determined in laboratory experiments and then modelled with the...
Tipo: Text Palavras-chave: Gas hydrate; CH4; CO2-rich mixtures; Phase equilibria; Soave-Redlich-Kwong (SRK) cubic equation of state (EoS).
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00414/52538/53349.pdf
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Gas hydrate distributions in sediments of pockmarks from the Nigerian Margin - Results and interpretation from shallow drilling ArchiMer
Wei, Jiangong; Pape, Thomas; Sultan, Nabil; Colliat, Jean-louis; Himmler, Tobias; Ruffine, Livio; De Prunele, Alexis; Dennielou, Bernard; Garziglia, Sebastien; Marsset, Tania; Peters, Carl A.; Rabiu, Abdulkarim; Bohrmann, Gerhard.
A joint research expedition between the French IFREMER and the German MARUM was conducted in 2011 using the R/V Pourquoi pas? to study gas hydrate distributions in a pockmark field (1141 – 1199 meters below sea surface) at the continental margin of Nigeria. The sea floor drill rig MeBo of MARUM was used to recover sediments as deep as 56.74 meters below seafloor. The presence of gas hydrates in specific core sections was deduced from temperature anomalies recorded during continuous records of infrared thermal scanning and anomalies in pore water chloride concentrations. In situ sediment temperature measurements showed elevated geothermal gradients of up to 258 °C/km in the center of the so-called pockmark A which is up to 4.6 times higher than that in the...
Tipo: Text Palavras-chave: Gas hydrate; Pockmark; Chloride profile; Infrared thermal imaging; Fluid flow; Nigerian continental margin; MeBo drill rig.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00213/32382/30846.pdf
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MARSITECruise Report. 2014 1st ‐ 13th November ‐ Leg 2 ArchiMer
Ruffine, Livio; Geli, Louis.
Summary of Marsitecruise The scientific cruise MARSITECRUISE of R/V Pourquoi pas? Took place from 28 October to 17 November 2014. Part of the operations were carried out within the frame of the MARSITE programme supported by the European Union, which aims at better understanding the behaviour of the North Anatolian fault in the Marmara sea in view of improving the assessment of the seismic hazard weighing on the Istanbul region. Coordinated by the Observatory of the University of Kandilli (KOERI, based in Istanbul), MARSITE groups 23 partners and includes different components: land, spatial and marine. The marine operations of the programme were coordinated by Ifremer and conducted using Italian (R/V Urania) and French (R/V Pourquoi pas?) naval means....
Tipo: Text Palavras-chave: Sea of Marmara; Geochemistry; Seismicity.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00453/56480/58177.pdf
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Shallow gas hydrate accumulations at a Nigerian deep‐water pockmark ‐ Quantities and dynamics ArchiMer
Pape, Thomas; Ruffine, Livio; Hong, Wei‐li; Sultan, Nabil; Riboulot, Vincent; Peters, Carl A.; Kölling, Martin; Zabel, Matthias; Garziglia, Sebastien; Bohrmann, Gerhard.
The evolution of submarine pockmarks is often related to the ascent of fluid from the subsurface. For pockmarks located within the gas hydrate stability zone, methane oversaturation can result in the formation of gas hydrates in the sediment. A ca. 600 m‐wide sea floor depression in deep‐waters offshore Nigeria, Pockmark A, was investigated for distributions and quantities of shallow gas hydrates, origins of hydrocarbons and time elapsed since the last major fluid ascent event. For the first time, pressure coring of shallow sediments and drilling of more than 50‐m‐long cores with the sea floor drill rig MARUM‐MeBo70 were conducted in this pockmark. Unusually high hydrate saturations of up to 51% of pore volume in the uppermost 2.5 meters of sediment in the...
Tipo: Text Palavras-chave: Pockmark; Gas hydrate; Methane; MeBo; Pressure coring; Pore water modeling.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00643/75491/76344.pdf
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The Aquitaine Shelf edge (Bay of Biscay): a primary outlet for microbial methane release ArchiMer
Dupré, Stephanie; Loubrieu, Benoit; Pierre, C.; Scalabrin, Carla; Guerin, Charline; Ehrhold, Axel; Ogor, Andre; Gautier, Emeric; Ruffine, Livio; Biville, Romain; Saout, Johan; Breton, C; Floodpage, J.; Lescanne, M..
A few thousand (2612) seeps are releasing microbial methane bubbles from the seafloor at the Aquitaine Shelf edge (Bay of Biscay) at shallow water depths (140‐220 m). This methane contributes to the formation of meter‐scale subcircular carbonate structures, which are (sub‐)outcropping over 375 km2. Based on in situ flow rate measurements and acoustic data, and assuming steady and continuous fluxes over time, the methane entering the water column is estimated to 144 Mg/yr. Microbial methane circulation has been on‐going for at least a few thousand years. This discovery highlights the importance of microbial methane generation, disconnected from deep thermogenic sources and gas hydrates, at continental shelves. The shelf edge may be viewed as a focus area...
Tipo: Text Palavras-chave: Microbial methane; Continental shelf; Fluid emissions; High‐resolution acoustics; Aquitaine Margin; Methane‐derived authigenic carbonates.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00618/72982/72057.pdf
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Gas Hydrates 1: Fundamentals, Characterization and Modeling ArchiMer
Broseta, Daniel; Ruffine, Livio; Desmedt, Arnaud.
Gas hydrates, or clathrate hydrates, are crystalline solids resembling ice, in which small (guest) molecules, typically gases, are trapped inside cavities formed by hydrogen-bonded water (host) molecules. They form and remain stable under low temperatures – often well below ambient conditions – and high pressures ranging from a few bar to hundreds of bar, depending on the guest molecule. Their presence is ubiquitous on Earth, in deep-marine sediments and in permafrost regions, as well as in outer space, on planets or comets. In addition to water, they can be synthesized with organic species as host molecules, resulting in milder stability conditions: these are referred to as semi-clathrate hydrates. Clathrate and semi-clathrate hydrates are being...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00453/56506/58852.pdf
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Evidence and age estimation of mass wasting at the distal lobe of the Congo deep-sea fan ArchiMer
Croguennec, Claire; Ruffine, Livio; Dennielou, Bernard; Baudin, Francois; Caprais, Jean-claude; Guyader, Vivien; Bayon, Germain; Brandily, Christophe; Le Bruchec, Julie; Bollinger, Claire; Germain, Yoan; Droz, Laurence; Babonneau, Nathalie; Rabouille, Christophe.
On continental margins, sulfate reduction occurs within the sedimentary column. It is coupled with the degradation of organic matter and the anaerobic oxidation of methane. These processes may be significantly disturbed by sedimentary events, leading to transient state profiles for the involved chemical species. Yet, little is known about the impact of turbidity currents and mass wasting on the migration of chemical species and the redox reactions in which they are involved. Due to its connection to the River, the Congo deep-sea fan continuously receives huge amount of organic matter-rich sediments primarily transported by turbidity currents, which impact on the development of the associated ecosystems (Rabouille et al., 2016). Thus, it is well suited to...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00363/47410/47403.pdf
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Pore water geochemistry at two seismogenic areas in the Sea of Marmara ArchiMer
Ruffine, Livio; Germain, Yoan; Polonia, Alina; De Prunele, Alexis; Croguennec, Claire; Donval, Jean-pierre; Pitel-roudaut, Mathilde; Ponzevera, Emmanuel; Caprais, Jean-claude; Brandily, Christophe; Grall, Celine; Bollinger, Claire; Geli, Louis; Gasperini, Luca.
Within the Sea of Marmara, the highly active North Anatolian Fault (NAF) is responsible for major earthquakes (Mw>=7), and acts as a pathway for fluid migration from deep sources to the seafloor. This work reports on pore water geochemistry from three sediment cores collected in the Gulfs of Izmit and Gemlik, along the Northern and the Middle strands of the NAF, respectively. The resulting data set shows that anaerobic oxidation of methane (AOM) is the major process responsible for sulfate depletion in the shallow sediment. In the Gulf of Gemlik, depth concentration profiles of both sulfate and alkalinity exhibit a kink-type profile. The Sulfate Methane Transition Zone (SMTZ) is located at moderate depth in the area. In the Gulf of Izmit, the low...
Tipo: Text Palavras-chave: Anaerobic oxidation of methane; North Anatolian Fault; Pore water geochemistry; Sea of Marmara; Seismic activity.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00272/38339/36570.pdf
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Multiple gas reservoirs are responsible for the gas emissions along the Marmara fault network ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Cagatay, M. Namik; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Geli, Louis.
On continental margins, upward migration of fluids from various sources and various subsurface accumulations, through the sedimentary column to the seafloor, leads to the development of cold seeps where chemical compounds are discharged into the water column. MarsiteCruise was undertaken in November 2014 to investigate the dynamics of cold seeps characterized by vigorous gas emissions in the Sea of Marmara (SoM). A previous paper published by Bourry et al. (2009) presented the gas geochemistry of three seeps sampled along three different segments in the SoM. Their findings showed that the seeps were sourced by three different reservoirs. In this paper, seventeen seeps were investigated to determine the gas sources, unravel reservoir contributions, and...
Tipo: Text Palavras-chave: Abiotic CO2-source; Gas bubbles; Molecular and isotopic compositions; Primary and secondary methanogenesis; Sea of Marmara; Seeps; Thermogenic gases.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00411/52203/52926.pdf
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Gas Seepage along the Edge of the Aquitaine Shelf (France): Origin and Local Fluxes ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Bignon, Laurent; Birot, Dominique; Battani, Anne; Bayon, Germain; Caprais, Jean-claude; Lanteri, Nadine; Levache, Denis; Dupre, Stephanie.
During the scientific expedition GAZCOGNE2 at the Bay of Biscay nine gas seeps were sampled for the first time and their flux was measured using an in situ pressure-preservation sampler (PEGAZ, ©IFREMER). Overall, three sites were investigated to determine the nature and the origin of the gases bubbling at the seafloor and forming acoustic plumes into the water column, as this was the question raised fromthe first geologic study of the area.This has guided our study and accordingly corresponds to themain purpose of the present article.Thus, themolecular and isotopic (𝛿D and 𝛿13C) analyses revealed that the gas seeps were primarily composed of methane. Both methane and ethane are of microbial origin, and the former has been generated by...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00394/50579/51270.pdf
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Interpretation of Late‐Pleistocene/Holocene transition in the Sea of Marmara from geochemistry of bulk carbonates ArchiMer
Liu, Yujia; Lu, Hailong; Yin, Xijie; Ruffine, Livio; Çağatay, M. Namik; Yang, Hailin; Chen, Chunqing; He, Dong; Zhu, Zhenli; Yalamaz, Burak.
Isotopic, mineralogical and elemental analyses have been conducted for the geochemical characteristics of the bulk carbonates in the sediment cores from the Western High and Çınarcık Basin in the Sea of Marmara to investigate the authigenic, biogenic and detrital components and their possible use in paleoceanographic studies. The Western High is a relatively shallow (‐500 to ‐800 m) compressional area characterized by relatively low sedimentation rates (30‐40 cm/kyr) whereas the Çnarcık Basin is a deep (~1250 m) transtentional area represented by high sedimentation rates (>1 m/kyr). Both 87Sr/86Sr and δ18O of bulk carbonates from the Western High exhibit significant variations, increasing steeply from 87Sr/86Sr of 0.708437 to 0.708916 and δ18O of ‐3.2‰...
Tipo: Text Palavras-chave: Bulk carbonates; Carbon and oxygen isotopes; Strontium isotopes; Transgression; Anaerobic biodegradation; Sea of Marmara.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00514/62518/66821.pdf
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Experimental Study of Mixed Gas Hydrates from Gas Feed Containing CH4, CO2 and N2: Phase Equilibrium in the Presence of Excess Water and Gas Exchange ArchiMer
Legoix, Ludovic; Ruffine, Livio; Deusner, Christian; Haeckel, Matthias.
This article presents gas hydrate experimental measurements for mixtures containing methane (CH 4 ), carbon dioxide (CO 2 ) and nitrogen (N 2 ) with the aim to better understand the impact of water (H 2 O) on the phase equilibrium. Some of these phase equilibrium experiments were carried out with a very high water-to-gas ratio that shifts the gas hydrate dissociation points to higher pressures. This is due to the significantly different solubilities of the different guest molecules in liquid H 2 O. A second experiment focused on CH 4 -CO 2 exchange between the hydrate and the vapor phases at moderate pressures. The results show a high retention of CO 2 in the gas hydrate phase with small pressure variations within the first hours. However, for our system...
Tipo: Text Palavras-chave: Gas hydrates; CH4; CO2; N-2; High-pressure experiments; Phase equilibrium; Gas exchange.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00452/56345/57935.pdf
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New insights into the transport processes controlling the sulfate-methane-transition-zone near methane vents ArchiMer
Sultan, Nabil; Garziglia, Sebastien; Ruffine, Livio.
Over the past years, several studies have raised concerns about the possible interactions between methane hydrate decomposition and external change. To carry out such an investigation, it is essential to characterize the baseline dynamics of gas hydrate systems related to natural geological and sedimentary processes. This is usually treated through the analysis of sulfate-reduction coupled to anaerobic oxidation of methane (AOM). Here, we model sulfate reduction coupled with AOM as a two-dimensional (2D) problem including, advective and diffusive transport. This is applied to a case study from a deep-water site off Nigeria’s coast where lateral methane advection through turbidite layers was suspected. We show by analyzing the acquired data in combination...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00339/45068/44493.pdf
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Methane Hydrate Formation and Dissociation in Sand Media: Effect of Water Saturation, Gas Flowrate and Particle Size ArchiMer
Benmesbah, Fatima; Ruffine, Livio; Clain, Pascal; Osswald, Véronique; Fandino Torres, Olivia; Fournaison, Laurence; Delahaye, Anthony.
Assessing the influence of key parameters governing the formation of hydrates and determining the capacity of the latter to store gaseous molecules is needed to improve our understanding of the role of natural gas hydrates in the oceanic methane cycle. Such knowledge will also support the development of new industrial processes and technologies such as those related to thermal energy storage. In this study, high-pressure laboratory methane hydrate formation and dissociation experiments were carried out in a sandy matrix at a temperature around 276.65 K. Methane was continuously injected at constant flowrate to allow hydrate formation over the course of the injection step. The influence of water saturation, methane injection flowrate and particle size on...
Tipo: Text Palavras-chave: Gas hydrate; Porous media; Kinetics; Methane storage estimate; Water saturation; Gas flowrate; Particle size.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00654/76593/77741.pdf
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Gas and seismicity within the Istanbul seismic gap ArchiMer
Geli, Louis; Henry, P.; Grall, Celine; Tary, Jean-baptiste; Lomax, A.; Batsi, Evangelia; Riboulot, Vincent; Cros, Estelle; Gurbuz, C.; Isik, S. E.; Sengor, A. M. C.; Le Pichon, X.; Ruffine, Livio; Dupre, Stephanie; Thomas, Yannick; Kalafat, D.; Bayrakci, G.; Coutellier, Q.; Regnier, Thibaut; Westbrook, Graham; Saritas, H.; Cifci, G.; Cagatay, M. N.; Ozeren, M. S.; Gorur, N.; Tryon, M.; Bohnhoff, M.; Gasperini, L.; Klingelhoefer, Frauke; Scalabrin, Carla; Augustin, Jean-marie; Embriaco, D.; Marinaro, G.; Frugoni, F.; Monna, S.; Etiope, G.; Favali, P.; Becel, A..
Understanding micro-seismicity is a critical question for earthquake hazard assessment. Since the devastating earthquakes of Izmit and Duzce in 1999, the seismicity along the submerged section of North Anatolian Fault within the Sea of Marmara (comprising the “Istanbul seismic gap”) has been extensively studied in order to infer its mechanical behaviour (creeping vs locked). So far, the seismicity has been interpreted only in terms of being tectonic-driven, although the Main Marmara Fault (MMF) is known to strike across multiple hydrocarbon gas sources. Here, we show that a large number of the aftershocks that followed the M 5.1 earthquake of July, 25th 2011 in the western Sea of Marmara, occurred within a zone of gas overpressuring in the 1.5–5 km depth...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00439/55072/56500.pdf
Registros recuperados: 44
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