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Diagenetic production, accumulation and sediment-water exchanges of methylmercury in contrasted sediment facies of Lake Titicaca (Bolivia) ArchiMer
Guédron, S.; Audry, S.; Acha, D.; Bouchet, S.; Point, D.; Condom, T.; Heredia, C.; Campillo, S.; Baya, A.; Groleau, A.; Amice, Erwan; Amouroux, D..
Monomethylmercury (MMHg) concentrations in aquatic biota from Lake Titicaca are elevated although the mercury (Hg) contamination level of the lake is low. The contribution of sediments to the lake MMHg pool remained however unclear. In this work, seven cores representative of the contrasted sediments and aquatic ecotopes of Lake Titicaca were sliced and analyzed for Hg and redox-sensitive elements (Mn, Fe, N and S) speciation in pore-water (PW) and sediment to document early diagenetic processes responsible for MMHg production and accumulation in PW during organic matter (OM) oxidation. The highest MMHg concentrations (up to 12.2 ng L−1 and 90% of THg) were found in subsurface PWs of the carbonate-rich sediments which cover 75% of the small basin and 20%...
Tipo: Text Palavras-chave: Methylmercury; Lake sediment; Early diagenesis; High altitude ecosystem; Diffusive fluxes.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00615/72735/71843.pdf
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