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| Santos,Éder José dos; Baika,Loana Mara; Herrmann,Amanda Beatriz; Kulik,Suzete; Sato,Charyane Satie; Santos,Arlene Bispo dos; Curtius,Adilson José. |
| A method for evaluating inorganic constituents in the grass by ICP OES is proposed. The samples were digested with nitric acid plus hydrogen peroxide in a microwave system. Seventeen samples were collected in the metropolitan area of Curitiba and Castro in the Paraná State, Brazil. The following elements were studied: Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Na, Ni, P, Pb, Sb, Se and Zn. The linear coefficients of the curves were higher than 0.999 and the precision, expressed as the relative standard deviation, which was below 10%, being considered adequate. The accuracy was validated by using the recovery test (recoveries from 80 to 107%) and by the analysis of botanical certified materials. For one sample, two other digestion procedures, using... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: ICP OES; Inorganic constituents; Acid digestion; PCA. |
| Ano: 2012 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132012000300017 |
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| Santos,Éder José dos; Santos,Arlene Bispo dos; Herrmann,Amanda Beatriz; Kulik,Suzete; Baika,Loana Mara; Tormen,Luciano; Curtius,Adilson José. |
| An on-line method for Cd and Pb pre-concentration and simultaneous determination in acid digested seafood by inductively coupled plasma optical emission spectrometry (ICP OES) was developed. The on-line pre-concentration was based on the complex formation of the analytes with the ammonium salt of O,O-diethyldithiophosphate (DDTP) and using the Amberlite XAD-4 resin as a solid support in a homemade column. Different conditions of the flow injection system, such as solutions flow rates, nebulizer pressure and eluent concentration were optimized. Three certified reference materials of lobster hepatopancreas, dogfish liver and fish protein, three samples of fish muscle and three samples of shrimp were digested with HNO3, H2O2 and H2SO4 in a microwave system... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Cd; Pb; ICP OES; Diethyldithiophosphate; XAD-4; Seafood; Solid phase extraction. |
| Ano: 2013 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132013000100017 |
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