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GEOTRACES inter-calibration of the stable silicon isotope composition of dissolved silicic acid in seawater ArchiMer
Grasse, Patricia; Brzezinski, Mark A.; Cardinal, Damien; De Souza, Gregory F.; Andersson, Per; Closset, Ivia; Cao, Zhimian; Dai, Minhan; Ehlert, Claudia; Estrade, Nicolas; Francois, Roger; Frank, Martin; Jiang, Guibin; Jones, Janice L.; Kooijman, Ellen; Liu, Qian; Lu, Dawei; Pahnke, Katharina; Ponzevera, Emmanuel; Schmitt, Melanie; Sun, Xiaole; Sutton, Jill; Thil, Francois; Weis, Dominique; Wetzel, Florian; Zhang, Anyu; Zhang, Jing; Zhang, Zhouling.
The first inter-calibration study of the stable silicon isotope composition of dissolved silicic acid in seawater, delta Si-30(OH)(4), is presented as a contribution to the international GEOTRACES program. Eleven laboratories from seven countries analyzed two seawater samples from the North Pacific subtropical gyre (Station ALOHA) collected at 300 m and at 1000 m water depth. Sampling depths were chosen to obtain samples with a relatively low (9 mmol L-1, 300 m) and a relatively high (113 mmol L-1, 1000 m) silicic acid concentration as sample preparation differs for low- and highconcentration samples. Data for the 1000 m water sample were not normally distributed so the median is used to represent the central tendency for the two samples. Median delta...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00381/49270/49681.pdf
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Late summer particulate organic carbon export and twilight zone remineralisation in the Atlantic sector of the Southern Ocean ArchiMer
Planchon, F.; Cavagna, A-j.; Cardinal, Damien; Andre, L.; Dehairs, F..
As part of the GEOTRACES Bonus-GoodHope (BGH) expedition (January-March 2008) in the Atlantic sector of the Southern Ocean, particulate organic carbon (POC) export was examined from the surface to the mesopelagic twilight zone using water column distributions of total Th-234 and biogenic particulate Ba (Ba-xs). Surface POC export production was estimated from steady state and non steady state modelling of Th-234 fluxes, which were converted into POC fluxes, using the POC/Th-234 ratio of large, potentially sinking particles (>53 mu m) collected via in situ pumps. Deficits in Th-234 activities were observed at all stations from the surface to the bottom of the mixed layer, yielding Th-234 export fluxes from the upper 100 m of 496 +/- 214 dpm m(-2) d(-1)...
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Ano: 2013 URL: http://archimer.ifremer.fr/doc/00181/29206/27580.pdf
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Sea ice diatom contributions to Holocene nutrient utilization in East Antarctica ArchiMer
Panizzo, Virginia; Crespin, Julien; Crosta, Xavier; Shemesh, Aldo; Masse, Guillaume; Yam, Ruth; Mattielli, Nadine; Cardinal, Damien.
Combined high-resolution Holocene δ30Sidiat and δ13Cdiat paleorecords are presented from the Seasonal Ice Zone, East Antarctica. Both data sets reflect periods of increased nutrient utilization by diatoms during the Hypsithermal period (circa 7800 to 3500 calendar years (cal years) B.P.), coincident with a higher abundance of open water diatom species (Fragilariopsis kerguelensis), increased biogenic silica productivity (%BSi), and higher regional summer temperatures. The Neoglacial period (after circa 3500 cal years B.P.) is reflected by an increase in sea ice indicative species (Fragilariopsis curta and Fragilariopsis cylindrus, up to 50%) along with a decrease in %BSi and δ13Cdiat (< −18‰ to −23‰). However, over this period, δ30Sidiat data show an...
Tipo: Text Palavras-chave: Diatoms; Silicon isotopes; Diatom bound carbon isotopes; Seasonal ice zone; Holocene; Southern Ocean.
Ano: 2014 URL: https://archimer.ifremer.fr/doc/00290/40157/39098.pdf
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Unveiling the Si cycle using isotopes in an iron fertilized zone of the Southern Ocean: from mixed layer supply to export ArchiMer
Closset, Ivia; Cardinal, Damien; Rembauville, Mathieu; Thil, Francois; Blain, Stephane.
A massive diatom-bloom is observed annually in the surface waters of the naturally Fe-fertilized Kerguelen Plateau (Southern Ocean). In this study, silicon isotopic signatures (δ30Si) of silicic acid (DSi) and suspended biogenic silica (BSi) were investigated in the whole water column with an unprecedented spatial resolution in this region, during the KEOPS-2 experiment (spring 2011). We use δ30Si measurements to track the silicon sources that fuel the bloom, and investigate the seasonal evolution of Si biogeochemical cycle in the iron fertilized area. We compare the results from a HNLC reference station with stations characterized by different degrees of iron enrichment and bloom conditions. Dissolved and particulate δ30Si signatures were generally highly...
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Ano: 2016 URL: https://archimer.ifremer.fr/doc/00344/45528/45085.pdf
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Assessment of C, N and Si isotopes as tracers of past ocean nutrient and carbon cycling ArchiMer
Farmer, Jesse; Hertzberg, Jennifer; Cardinal, Damien; Fietz, Susanne; Hendry, Katharine; Jaccard, Sam; Paytan, Adina; Rafter, Patrick; Ren, Haojia; Somes, Christopher; Sutton, Jill; Geotraces Pages Biological Productivity Working Group Members,.
Biological productivity in the ocean directly influences the partitioning of carbon between the atmosphere and ocean interior, thereby controlling the distributions of many elements and their isotopes in the ocean. Through this carbon cycle feedback, changing ocean productivity has long been hypothesized as a key pathway for modulating past atmospheric carbon dioxide levels and hence global climate. To reconstruct climate impacts from temporal changes in paleoproductivity, robust proxies are needed to test the connection between past ocean productivity, nutrient biogeochemistry, ocean circulation and climate. Here we compile water column carbon (C), nitrogen (N) and silicon (Si) stable isotopes from GEOTRACES-era data in four key ocean regions to review...
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Ano: 2020 URL: https://archimer.ifremer.fr/doc/00649/76114/77076.pdf
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A Review of the Stable Isotope Bio-geochemistry of the Global Silicon Cycle and Its Associated Trace Elements ArchiMer
Sutton, Jill N.; Andre, Luc; Cardinal, Damien; Conley, Daniel J.; De Souza, Gregory F.; Dean, Jonathan; Dodd, Justin; Ehlert, Claudia; Ellwood, Michael J.; Frings, Patrick J.; Grasse, Patricia; Hendry, Katharine; Leng, Melanie J.; Michalopoulos, Panagiotis; Panizzo, Virginia N.; Swann, George E. A..
Silicon (Si) is the second most abundant element in the Earth's crust and is an important nutrient in the ocean. The global Si cycle plays a critical role in regulating primary productivity and carbon cycling on the continents and in the oceans. Development of the analytical tools used to study the sources, sinks, and fluxes of the global Si cycle (e.g., elemental and stable isotope ratio data for Ge, Si, Zn, etc.) have recently led to major advances in our understanding of the mechanisms and processes that constrain the cycling of Si in the modern environment and in the past. Here, we provide background on the geochemical tools that are available for studying the Si cycle and highlight our current understanding of the marine, freshwater and terrestrial...
Tipo: Text Palavras-chave: C - N - O - Si isotopes; Biogenic silica; Element/Si ratios; Biogeochemical cycles; Silicon.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00431/54217/55547.pdf
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The GEOTRACES Intermediate Data Product 2014 ArchiMer
Mawji, Edward; Schlitzer, Reiner; Dodas, Elena Masferrer; Abadie, Cyril; Abouchami, Wafa; Anderson, Robert F.; Baars, Oliver; Bakker, Karel; Baskaran, Mark; Bates, Nicholas R.; Bluhm, Katrin; Bowie, Andrew; Bown, Johann; Boye, Marie; Boyle, Edward A.; Branellec, Pierre; Bruland, Kenneth W.; Brzezinski, Mark A.; Bucciarelli, Eva; Buesseler, Ken; Butler, Edward; Cai, Pinghe; Cardinal, Damien; Casciotti, Karen; Chaves, Joaquin; Cheng, Hai; Chever, Fanny; Church, Thomas M.; Colman, Albert S.; Conway, Tim M.; Croot, Peter L.; Cutter, Gregory A.; De Baar, Hein J. W.; De Souza, Gregory F.; Dehairs, Frank; Deng, Feifei; Huong Thi Dieu,; Dulaquais, Gabriel; Echegoyen-sanz, Yolanda; Edwards, R. Lawrence; Fahrbach, Eberhard; Fitzsimmons, Jessica; Fleisher, Martin; Frank, Martin; Friedrich, Jana; Fripiat, Francois; Galer, Stephen J. G.; Gamo, Toshitaka; Solsona, Ester Garcia; Gerringa, Loes J. A.; Godoy, Jose Marcus; Gonzalez, Santiago; Grossteffan, Emilie; Hatta, Mariko; Hayes, Christopher T.; Heller, Maija Iris; Henderson, Gideon; Huang, Kuo-fang; Jeandel, Catherine; Jenkins, William J.; John, Seth; Kenna, Timothy C.; Klunder, Maarten; Kretschmer, Sven; Kumamoto, Yuichiro; Laan, Patrick; Labatut, Marie; Lacan, Francois; Lam, Phoebe J.; Lannuzel, Delphine; Le Moigne, Frederique; Lechtenfeld, Oliver J.; Lohan, Maeve C.; Lu, Yanbin; Masque, Pere; Mcclain, Charles R.; Measures, Christopher; Middag, Rob; Moffett, James; Navidad, Alicia; Nishioka, Jun; Noble, Abigail; Obata, Hajime; Ohnemus, Daniel C.; Owens, Stephanie; Planchon, Frederic; Pradoux, Catherine; Puigcorbe, Viena; Quay, Paul; Radic, Amandine; Rehkaemper, Mark; Remenyi, Tomas; Rijkenberg, Micha J. A.; Rintoul, Stephen; Robinson, Laura F.; Roeske, Tobias; Rosenberg, Mark; Van Der Loeff, Michiel Rutgers; Ryabenko, Evgenia; Saito, Mak A.; Roshan, Saeed; Salt, Lesley; Sarthou, Geraldine; Schauer, Ursula; Scott, Peter; Sedwick, Peter N.; Sha, Lijuan; Shiller, Alan M.; Sigman, Daniel M.; Smethie, William; Smith, Geoffrey J.; Sohrin, Yoshiki; Speich, Sabrina; Stichel, Torben; Stutsman, Johnny; Swift, James H.; Tagliabue, Alessandro; Thomas, Alexander; Tsunogai, Urumu; Twining, Benjamin S.; Van Aken, Hendrik M.; Van Heuven, Steven; Van Ooijen, Jan; Van Weerlee, Evaline; Venchiarutti, Celia; Voelker, Antje H. L.; Wake, Bronwyn; Warner, Mark J.; Woodward, E. Malcolm S.; Wu, Jingfeng; Wyatt, Neil; Yoshikawa, Hisayuki; Zheng, Xin-yuan; Xue, Zichen; Zieringer, Moritz; Zimmer, Louise A..
The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEls) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data...
Tipo: Text Palavras-chave: GEOTRACES; Trace elements; Isotopes; Electronic atlas.
Ano: 2015 URL: https://archimer.ifremer.fr/doc/00308/41910/41190.pdf
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The GEOTRACES Intermediate Data Product 2017 ArchiMer
Schlitzer, Reiner; Anderson, Robert F.; Dodas, Elena Masferrer; Lohan, Maeve; Geibere, Walter; Tagliabue, Alessandro; Bowie, Andrew; Jeandel, Catherine; Maldonado, Maria T.; Landing, William M.; Cockwell, Donna; Abadie, Cyril; Abouchami, Wafa; Achterberg, Eric P.; Agather, Alison; Aguliar-islas, Ana; Van Aken, Hendrik M.; Andersen, Morten; Archer, Corey; Auro, Maureen; De Baar, Hein J.; Baars, Oliver; Baker, Alex R.; Bakker, Karel; Basak, Chandranath; Baskaran, Mark; Bates, Nicholas R.; Bauch, Dorothea; Van Beek, Pieter; Behrens, Melanie K.; Black, Erin; Bluhm, Katrin; Bopp, Laurent; Bouman, Heather; Bowman, Katlin; Bown, Johann; Boyd, Philip; Boye, Marie; Boyle, Edward A.; Branellec, Pierre; Bridgestock, Luke; Brissebrat, Guillaume; Browning, Thomas; Bruland, Kenneth W.; Brumsack, Hans-juergen; Brzezinski, Mark; Buck, Clifton S.; Buck, Kristen N.; Buesseler, Ken; Bull, Abby; Butler, Edward; Cai, Pinghe; Camara Mor, Patricia; Cardinal, Damien; Carlson, Craig; Carrasco, Gonzalo; Casacuberta, Nuria; Casciotti, Karen L.; Castrillejo, Maxi; Chamizo, Elena; Chance, Rosie; Charette, Matthew A.; Chaves, Joaquin E.; Cheng, Hai; Chever, Fanny; Christl, Marcus; Church, Thomas M.; Closset, Ivia; Colman, Albert; Conway, Tim M.; Cossa, Daniel; Croot, Peter; Cullen, Jay T.; Cutter, Gregory A.; Daniels, Chris; Dehairs, Frank; Deng, Feifei; Dieu, Huong Thi; Duggan, Brian; Dulaquais, Gabriel; Dumousseaud, Cynthia; Echegoyen-sanz, Yolanda; Edwards, R. Lawrence; Ellwood, Michael; Fahrbach, Eberhard; Fitzsimmons, Jessica N.; Flegal, A. Russell; Fleisher, Martin Q.; Van De Flierdt, Tina; Frank, Martin; Friedrich, Jana; Fripiat, Francois; Froellje, Henning; Galer, Stephen J. G.; Gamo, Toshitaka; Ganeshram, Raja S.; Garcia-orellana, Jordi; Garcia-solsona, Ester; Gault-ringold, Melanie; George, Ejin; Gerringa, Loes J. A.; Gilbert, Melissa; Godoy, Jose M.; Goldstein, Steven L.; Gonzalez, Santiago R.; Grissom, Karen; Hammerschmidt, Chad; Hartman, Alison; Hassler, Christel S.; Hathorne, Ed C.; Hatta, Mariko; Hawco, Nicholas; Hayes, Christopher T.; Heimburger, Lars-eric; Helgoe, Josh; Heller, Maija Iris; Henderson, Gideon M.; Henderson, Paul B.; Van Heuven, Steven; Ho, Peng; Horner, Tristan J.; Hsieh, Yu-te; Huang, Kuo-fang; Humphreys, Matthew P.; Isshiki, Kenji; Jacquot, Jeremy E.; Janssen, David J.; Jenkins, William J.; John, Seth; Jones, Elizabeth M.; Jones, Janice L.; Kadko, David C.; Kayser, Rick; Kenna, Timothy C.; Khondoker, Roulin; Kim, Taejin; Kipp, Lauren; Klar, Jessica K.; Klunder, Maarten; Kretschmer, Sven; Kumamoto, Yuichiro; Laan, Patrick; Labatut, Marie; Lacan, Francois; Lam, Phoebe J.; Lambelet, Myriam; Lamborg, Carl H.; Le Moigne, Frederic A. C.; Le Roy, Emilie; Lechtenfeld, Oliver J.; Lee, Jong-mi; Lherminier, Pascale; Little, Susan; Lopez-lora, Mercedes; Lu, Yanbin; Masque, Pere; Mawji, Edward; Mcclain, Charles R.; Measures, Christopher; Mehic, Sanjin; Barraqueta, Jan-lukas Menzel; Van Der Merwe, Pier; Middag, Rob; Mieruch, Sebastian; Milne, Angela; Minami, Tomoharu; Moffett, James W.; Moncoiffe, Gwenaelle; Moore, Willard S.; Morris, Paul J.; Morton, Peter L.; Nakaguchi, Yuzuru; Nakayama, Noriko; Niedermiller, John; Nishioka, Jun; Nishiuchi, Akira; Noble, Abigail; Obata, Hajime; Ober, Sven; Ohnemus, Daniel C.; Van Ooijen, Jan; O'Sullivan, Jeanette; Owens, Stephanie; Pahnke, Katharina; Paul, Maxence; Pavia, Frank; Pena, Leopoldo D.; Petersh, Brian; Planchon, Frederic; Planquette, Helene; Pradoux, Catherine; Puigcorbe, Viena; Quay, Paul; Queroue, Fabien; Radic, Amandine; Rauschenberg, S.; Rehkamper, Mark; Rember, Robert; Remenyi, Tomas; Resing, Joseph A.; Rickli, Joerg; Rigaud, Sylvain; Rijkenberg, Micha J. A.; Rintoul, Stephen; Robinson, Laura F.; Roca-marti, Montserrat; Rodellas, Valenti; Roeske, Tobias; Rolison, John M.; Rosenberg, Mark; Roshan, Saeed; Van Der Loaff, Michiel M. Rutgers; Ryabenko, Evgenia; Saito, Mak A.; Salt, Lesley A.; Sanial, Virginie; Sarthou, Geraldine; Schallenberg, Christina; Schauer, Ursula; Scher, Howie; Schlosser, Christian; Schnetger, Bernhard; Scott, Peter; Sedwick, Peter N.; Semiletov, Igor; Shelley, Rachel; Sherrell, Robert M.; Shiller, Alan M.; Sigman, Daniel M.; Singh, Sunil Kumar; Slagter, Hans A.; Slater, Emma; Smethie, William M.; Snaith, Helen; Sohrin, Yoshiki; Sohst, Bettina; Sonke, Jeroen E.; Speich, Sabrina; Steinfeldt, Reiner; Stewart, Gillian; Stichel, Torben; Stirling, Claudine H.; Stutsman, Johnny; Swarr, Gretchen J.; Swift, James H.; Thomas, Alexander; Thorne, Kay; Till, Claire P.; Till, Ralph; Townsend, Ashley T.; Townsend, Emily; Tuerena, Robyn; Twining, Benjamin S.; Vance, Derek; Velazquez, Sue; Venchiarutti, Celia; Villa-alfageme, Maria; Vivancos, Sebastian M.; Voelker, Antje H. L.; Wake, Bronwyn; Warner, Mark J.; Watson, Ros; Van Weerlee, Evaline; Weigand, M. Alexandra; Weinstein, Yishai; Weiss, Dominik; Wisotzki, Andreas; Woodward, E. Malcolm S.; Wu, Jingfeng; Wu, Yingzhe; Wuttig, Kathrin; Wyatt, Neil; Xiang, Yang; Xie, Ruifang C.; Xue, Zichen; Yoshikawa, Hisayuki; Zhang, Jing; Zhang, Pu; Zhao, Ye; Zheng, Linjie; Zheng, Xin-yuan; Zieringer, Moritz; Zimmer, Louise A.; Ziveri, Patrizia; Zunino, Patricia; Zurbrick, Cheryl.
The new IDP2017 is a significant improvement over the earlier IDP2014 and roughly doubles the number of included cruises, stations, samples and parameters. The IDP2017 is a truly international product containing data from 326 researchers from 25 countries. The IDP2017 provides data for the Pacific Ocean, and the Mediterranean and Black seas, in addition to Atlantic, Arctic and Indian Oceans that were already represented in the previous data product. For the first time, the IDP2017 contains significant amounts of biogeochemistry data as well as TEI data for aerosols and rain. As before, users can obtain complete IDP2017 data sets as bulk downloads. Alternatively, there is now a customisable online data extraction service that allows data selections by...
Tipo: Text Palavras-chave: GEOTRACES; Trace elements; Isotopes; Electronic atlas; IDP2017.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00442/55362/56877.pdf
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Measuring production-dissolution rates of marine biogenic silica by Si-30-isotope dilution using a high-resolution sector field inductively coupled plasma mass spectrometer ArchiMer
Fripiat, Francois; Corvaisier, Rudolph; Navez, Jacques; Elskens, Marc; Schoemann, Veronique; Leblanc, Karine; Andre, Luc; Cardinal, Damien.
Regional and seasonal variability of the Si dissolution: production ratios in the surface ocean have not been well assessed. Here, we propose a new method for determining these rates, using the Si-30-isotopic dilution technique with a high-resolution sector field inductively coupled plasma mass spectrometer (HR-SF-ICP-MS). Relative analytical precision of the isotopic measurement is better than 1%, similar to that obtained by thermal ionization-quadrupole mass spectrometry (TIMS). Accuracy and reproducibility of the isotopic measurements have been checked on artificial and natural solutions by intercomparison between two HR-SF-ICP-MS instruments and one TIMS. Measurements of real Si production and dissolution rates are illustrated for two contrasted...
Tipo: Text Palavras-chave: Isotopic fractionation; Southern ocean; Acid uptake; Waters; Phytoplankton; Environments; Biosilica; Recovery; Balance; Tracer.
Ano: 2009 URL: https://archimer.ifremer.fr/doc/00205/31607/30033.pdf
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