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Modeling the Influence of Eutrophication and Redox Conditions on Mercury Cycling at the Sediment-Water Interface in the Berre Lagoon ArchiMer
Pakhomova, Svetlana; Yakushev, Evgeniy; Protsenko, Elizaveta; Rigaud, Sylvain; Cossa, Daniel; Knoery, Joel; Couture, Raoul-marie; Radakovitch, Olivier; Yakubov, Shamil; Krzeminska, Dominika; Newton, Alice.
This study presents a specifically designed Mercury module in a coupled benthic-pelagic reactive-transport model - Bottom RedOx Model (BROM) that allows to study mercury (Hg) biogeochemistry under different conditions. This module considers the transformation of elemental mercury (Hg(0)), divalent mercury (Hg(II)) and methylmercury (MeHg). The behavior of mercury species in the model is interconnected with changes of oxygen, hydrogen sulfide, iron oxides, organic matter, and biota. We simulated the transformation and transport of Hg species in the water column and upper sediment layer under five different scenarios, combining various levels of oxygenation and trophic state in the Berre lagoon, a shallow eutrophic lagoon of the French Mediterranean coast...
Tipo: Text Palavras-chave: Mercury; Methylmercury; Biogeochemical modeling; Anoxia; Eutrophication; Lagoon; BROM.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00454/56535/58239.pdf
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Mobility and fluxes of trace elements and nutrients at the sediment-water interface of a lagoon under contrasting water column oxygenation conditions ArchiMer
Rigaud, Sylvain; Radakovitch, Olivier; Couture, Raoul-marie; Deflandre, Bruno; Cossa, Daniel; Garnier, Cedric; Garnie, Jean-marie.
The early diagenesis of the major carrier phases (Fe and Mn minerals), trace elements (As, Co, Cr, Hg, MeHg, Ni) and nutrients (Sigma NO3, NH4+, Sigma PO4) and their exchange at the sediment water/interface were studied in the Berre Lagoon, a Mediterranean lagoon in France, at one site under two contrasting oxygenation conditions (strictly anoxic and slightly oxic) and at an adjacent site with perennially well-oxygenated water. From the concentration profiles of the primary biogeochemical constituents and trace elements of the pore and bottom waters, as well as the total and reactive particulate phases, it was possible to locate and identify the diagenetic reactions controlling the mobility of trace elements in the sediments and quantify their rates by...
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Ano: 2013 URL: http://archimer.ifremer.fr/doc/00134/24555/23573.pdf
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