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Methane Clathrates in the Solar System ArchiMer
Mousis, Olivier; Chassefiere, Eric; Holm, Nils G.; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-dib, Mohamad; Charlou, Jean-luc; Rousselot, Philippe.
We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form into the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from...
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Ano: 2015 URL: http://archimer.ifremer.fr/doc/00266/37718/41116.pdf
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Characterisation of dissolved organic compounds in hydrothermal fluids by stir bar sorptive extraction - gas chomatography - mass spectrometry. Case study: the Rainbow field (36 degrees N, Mid-Atlantic Ridge) ArchiMer
Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Holm, Nils G..
The analysis of the dissolved organic fraction of hydrothermal fluids has been considered a real challenge due to sampling difficulties, complexity of the matrix, numerous interferences and the assumed ppb concentration levels. The present study shows, in a qualitative approach, that Stir Bar Sorptive Extraction (SBSE) followed by Thermal Desorption - Gas Chromatography - Mass Spectrometry (TD-GC-MS) is suitable for extraction of small sample volumes and detection of a wide range of volatile and semivolatile organic compounds dissolved in hydrothermal fluids. In a case study, the technique was successfully applied to fluids from the Rainbow ultramafic-hosted hydrothermal field located at 36 degrees 14'N on the Mid-Atlantic Ridge (MAR). We show that...
Tipo: Text Palavras-chave: Sample preparation; Extraction; Organic compounds; Hydrothermal fluids; Ultramafic rocks.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00114/22514/20196.pdf
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