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Thermodynamic Characterization of Humic Acid-surfactant Interaction: New Insights into the Characteristics and Structure of Humic Acids Rev. Bras. Ciênc. Solo
Vergütz,Leonardus; Silva,Luis Henrique Mendes da; Novais,Roberto Ferreira; Silva,Maria do Carmo Hespanhol da; Mageste,Aparecida Barbosa; Silva,Ivo Ribeiro.
ABSTRACT Humic acids (HA) are a component of humic substances (HS), which are found in nearly all soils, sediments, and waters. They play a key role in many, if not most, chemical and physical properties in their environment. Despite the importance of HA, their high complexity makes them a poorly understood system. Therefore, understanding the physicochemical properties and interactions of HA is crucial for determining their fundamental role and obtaining structural details. Cationic surfactants are known to interact electrostatically and hydrophobically with HA. Because they are a very well-known and characterized system, they offer a good choice as molecular probes for studying HA. The objective of this study was to evaluate the interaction between...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Enthalpy; Humic substances; Isothermal titration calorimetry; Macromolecular structure; Microcalorimetry; Supramolecular structure.
Ano: 2015 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832015000601633
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Thermal and spectroscopic analyses on the molecular interaction between eucalyptus kraft pulp components and offset printing inks BABT
Alves,Ericka Figueiredo; Oliveira,Rubens Chaves de; Silva,Luis Henrique Mendes da; Colodette,Jorge Luiz.
Thermal and infrared spectroscopic analyzes were carried out in order to study the kind of interaction between the anatomical components of the bleached eucalyptus kraft pulp with offset inks. A Bauer-McNett fiber classifier was used in order to obtain the anatomical components of the pulp, separately. The determinations of the enthalpy of the processes occurring in the samples of inks and pulp, as well as the enthalpy of these components interactions were obtained by Differential Scanning Calorimetry. In the interaction between pulp and offset ink, the reduced enthalpy values of the endothermic peak were interpreted as due to the released energy for adhesion of the ink pigment to the substratum. The low enthalpy value, 58 to 121 cal.g -, ¹indicated that...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Differential scanning calorimetry; Thermogravimetry; Kraft pulping; Cellulose; Interaction; Eucalyptus sp.
Ano: 2009 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-89132009000300021
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Increased presevation of sliced mozzarella cheese by antimibrobial sachet incorporated with allyl isothiocyanate BJM
Pires,Ana Clarissa dos Santos; Soares,Nilda de Fátima Ferreira; Andrade,Nélio José de; Silva,Luis Henrique Mendes da; Camilloto,Geany Peruch; Bernardes,Patrícia Campos.
There is an increasing tendency to add natural antimicrobials of plant origin into food. The objective of this work was to develop a microbial sachet incorporated with allyl isothiocyanate (AIT), a volatile compound of plant origin, and to test its efficiency against growth of yeasts and molds, Staphylococcus sp. and psychrotrophic bacteria on sliced mozzarella cheese. Another objective was to quantify the concentration of AIT in the headspace of cheese packaging. A reduction of 3.6 log cycles was observed in yeasts and molds counts in the mozzarella packed with the antimicrobial sachet over 15-day storage time. The sachet also showed an antibacterial effect on Staphylococcus sp., reducing 2.4 log cycles after 12-day storage. Psychrotrophic bacteria...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Antimicrobial sachet; Mozzarella cheese; Food protection; Allyl isothiocyanate.
Ano: 2009 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-83822009000400036
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