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Isotopic composition and speciation of sedimentary nitrogen and carbon in the Okinawa Trough over the past 30 ka ArchiMer
Zheng, Li-wei; Hsiao, Silver Sung-yun; Ding, Xiao-dong; Li, Dawei; Chang, Yuan-pin; Kao, Shuh-ji.
Total organic carbon to total nitrogen ratios (C/N) and their isotopic compositions (δ13CTOC and δ15NTN) are oft-applied proxies to discern terrigenous from marine-sourced organics and to unravel ancient environmental information. In high depositional Asian marginal seas, the inclusion of N-bearing minerals in the bulk sediment dilutes or masks signals sought after in δ15N and δ13C analyses, thus leading to incorrect and even contradictory interpretations. We used KOH-KOBr to separate operationally defined total organic matter into oxidizable (labile) and residual fractions for content and isotope measurements. In a sediment core in the Okinawa Trough, significant amounts of carbon and nitrogen existed in the residual phase, in which the C/N ratio was ~9,...
Tipo: Text Palavras-chave: Carbon; Nitrogen; Isotope; Okinawa Trough; Sediment; Total organic carbon.
Ano: 2015 URL: https://archimer.ifremer.fr/doc/00295/40584/39503.pdf
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