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| Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Sireau, Teddy; Mojtahid, Meryem; Metzger, Edouard; Brach-papa, Christophe. |
| In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems,... |
| Tipo: Text |
Palavras-chave: Coastal pollution; Coastal biogeochemistry; Geochemical tracers; Metal isotopes; Trace metal; Anthropogenic contamination. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00490/60188/67760.pdf |
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| Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Bruzac, Sandrine; Sireau, Teddy; Brach-papa, Christophe. |
| Toulon bay is severely impacted by metal contamination induced by past and recent naval activities. In this work, Cu, Zn and Pb isotope compositions and elemental concentrations of fifty-five surface sediments were determined in order to map the spatial distribution of anthropogenic and natural sources along this land-sea continuum. Two sub-systems of Toulon Bay, the Small and Large bays, showed well-marked patterns on metal contamination levels and isotope signatures for Cu and Pb. The Small bay had the highest metal concentrations, and displayed average Pb and Cu isotope compositions of 1.1664 ± 0.0043 (1s, expressed as 206Pb/207Pb ratios) and −0.17 ± 0.19‰ (1s, expressed as δ65CuNIST values), respectively. It contrasted with the Large bay, with moderate... |
| Tipo: Text |
Palavras-chave: Metal isotopes; Isotope tracers; Geochemical isotopes; Environmental pollution; Coastal pollution; Toulon bay. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00566/67784/67226.pdf |
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| Ferreira Araujo, Daniel; Machado, Wilson; Weiss, Dominik; Mulholland, Daniel S.; Garnier, Jeremie; Souto-oliveira, Carlos E.; Babinski, Marly. |
| Recent work has shown that variations in zinc (Zn) isotope ratios enable us to identify contamination sources in the terrestrial environment and uptake processes in higher plants. Here in this study, we demonstrate that this also holds true for mangrove forests, which play an important role in the biogeochemical cycling of metals in tropical coastal ecosystems and that are seriously threatened by anthropogenic pollution. To this end, we determined zinc concentration and isotope composition (expressed using the δ66Zn notation relative to the JMC 3-0749-L standard) in sediments and tree leaves collected from a mangrove close to Rio de Janeiro in Brazil. The δ66ZnJMC values of sediments vary between +0.36 and + 0.84‰ and fall on a mixing line between detrital... |
| Tipo: Text |
Palavras-chave: Metal transition isotopes; Metal contamination; Mass spectrometry; Coastal ecosystems; Mangrove leaves. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00440/55196/56660.pdf |
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