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Two dimensional mapping of iron release in marine sediments at submillimetre scale 5
Thibault De Chanvalon, A.; Metzger, E.; Mouret, A.; Knoery, Joel; Geslin, E.; Meysman, F. J. R..
Coastal and shelf sediments are considered as an important source of dissolved iron to the ocean. Here, we present a new numerical approach to estimate geochemical fluxes and production rates in an estuarine sediment at sub-millimetre resolution. This approach is based on application of Savitsky–Golay filter (SGF) procedure to two-dimensional concentration distributions of dissolved iron. We verified the procedure by applying it to artificial data of known production rates, and analysed the resulting uncertainty on production rates and fluxes across the water–sediment interface. This SGF procedure was applied to data from an intertidal mudflat that is densely inhabited by macrofauna (e.g. 630 ind m− 2 of Hediste diversicolor, I. Métais, pers.com.). Our...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00332/44365/43970.pdf
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Modeling biogeochemical processes in sediments from the Rhone River prodelta area (NW Mediterranean Sea) 5
Pastor, L.; Cathalot, C.; Deflandre, B.; Viollier, E.; Soetaert, K.; Meysman, F. J. R.; Ulses, C.; Metzger, E.; Rabouille, C..
In situ oxygen microprofiles, sediment organic carbon content, and pore-water concentrations of nitrate, ammonium, iron, manganese, and sulfides obtained in sediments from the Rhone River prodelta and its adjacent continental shelf were used to constrain a numerical diagenetic model. Results showed that (1) the organic matter from the Rhone River is composed of a fraction of fresh material associated to high first-order degradation rate constants (11-33 yr(-1)); (2) the burial efficiency (burial/input ratio) in the Rh boolean AND one prodelta (within 3 km of the river outlet) can be up to 80 %, and decreases to similar to 20% on the adjacent continental shelf 10-15 km further offshore; (3) there is a large contribution of anoxic processes to total...
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Ano: 2011 URL: https://archimer.ifremer.fr/doc/00303/41423/40614.pdf
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