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Chemotypes and Biomarkers of Seven Species of New Caledonian Liverworts from the Bazzanioideae Subfamily ArchiMer
Metoyer, Benjamin; Lebouvier, Nicolas; Hnawia, Edouard; Herbette, Gaetan; Thouvenot, Louis; Asakawa, Yoshinori; Nour, Mohammed; Raharivelomanana, Phila.
Volatile components of seven species of the Bazzanioideae sub-family (Lepidoziaceae) native to New Caledonia, including three endemic species (Bazzania marginata, Acromastigum caledonicum and A. tenax), were analyzed by GC-FID-MS in order to index these plants to known or new chemotypes. Detected volatile constituents in studied species were constituted mainly by sesquiterpene, as well as diterpene compounds. All so-established compositions cannot successfully index some of them to known chemotypes but afforded the discovery of new chemotypes such as cuparane/fusicoccane. The major component of B. francana was isolated and characterized as a new zierane-type sesquiterpene called ziera-12(13), 10(14)-dien-5-ol (23). In addition, qualitative intraspecies...
Tipo: Text Palavras-chave: Liverwort; Bazzania; Acromastigum; Sesquiterpene; Diterpene; Bis(bibenzyl); Biosynthesis; Zierane; Vittatin.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00660/77222/78670.pdf
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Chemical constituents from Vellozia graminifolia (Velloziaceae) Anais da ABC (AABC)
Branco,Alexsandro; Pinto,Angelo C.; Braz Filho,Raimundo.
From the hexane and ethyl acetate extracts obtained from stems, roots and leaf sheaths of Vellozia graminifolia, a mixture of linear hydrocarbons, a mixture of pentacyclic triterpenes, five monoisoprenylated flavonoids and one labdane diterpene, (-)-ent-3beta-hydroxy-8(17)-labden-15-oic acid, were isolated. The linear hydrocarbons and minor triterpenes were identified in their corresponding mixtures by High Resolution Gas Chromatography (HRGC) and HRGC coupled to mass spectrometry. The major pentacyclic triterpenes and the diterpene were characterized by spectral data, including 2D NMR experiments, and chemical transformations.
Tipo: Info:eu-repo/semantics/article Palavras-chave: Vellozia graminifolia; Velloziaceae; Triterpenes; Diterpene; Flavonoids.
Ano: 2004 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652004000300005
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Optimization of diterpenes bioconversion process by the fungus Cephalosporium aphidicola BJM
Takahashi,Jacqueline Aparecida; Barroso,Henrique de Almeida; Oliveira,Alaíde Braga de.
Parameters for a more efficient biotransformation of diterpene-like compounds by the fungus Cephalosporium aphidicola were established by carrying out microscale feedings at several conditions. Experiments were guided by thin layer chromatography and gas chromatography analysis. It was observed that the substrate should be added in ethanol at concentrations between 15 to 30 mg per 100 ml of medium. The extraction of the product showed to be more efficient when carried out from both mycelia and broth and using ethylacetate as the extracting solvent. The experiment should be stopped six days after feeding the substrate to the fungus for the best product yield.
Tipo: Info:eu-repo/semantics/article Palavras-chave: Cephalosporium aphidicola; Biotransformation; Diterpene.
Ano: 2000 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1517-83822000000200003
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