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Sulfur and strontium isotopic study of epithermal mineralization: A case study from the SE Afar Rift, Djibouti ArchiMer
Moussa, N.; Rouxel, Olivier; Grassineau, N. V.; Ponzevera, Emmanuel; Nonnotte, P.; Fouquet, Yves; Le Gall, B..
Epithermal mineralization was recently described in synrift volcanic rocks from the SE Afar Rift in Djibouti. To infer fluid sources in this system, coupled sulfur and strontium isotopic analyses were performed on mineralized samples from hydrothermal veins and stockwork zones. Mineralization includes gypsum and chalcedony, and/or quartz ± carbonate containing gold and sulfides. Sulfur isotopic compositions of sulfides and sulfates were determined using Multicollector-Inductively Coupled Plasma Mass Spectrometer (MC ICPMS); Laser Ablation MC ICPMS; and Continuous Flow Elemental Analyzer-Isotope Ratio Mass Spectrometry while strontium isotopes were determined by Thermal Ionisation Mass Spectrometry (TIMS) methods. Sulfur isotopic composition of sulfides...
Tipo: Text Palavras-chave: Hydrothermal system; Sulfur isotopes; Strontium isotopes; SE Afar rift; Epithermal.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00356/46712/46581.pdf
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Enargite-luzonite hydrothermal vents in Manus Back-Arc Basin: submarine analogues of high-sulfidation epithermal mineralization ArchiMer
Dekov, Vesselin M.; Rouxel, Olivier; Kouzmanov, Kalin; Bindi, Luca; Asael, Dan; Fouquet, Yves; Etoubleau, Joel; Burgaud, Gaetan; Walle, Markus.
Active and inactive hydrothermal chimneys composed almost entirely of enargite and luzonite, rare minerals in seafloor hydrothermal deposits, were found at the summits of two submarine volcanoes, North Su and Kaia Natai, in the Manus Back-Arc Basin. Detailed mineralogical and geochemical studies revealed that most probably these deposits precipitated at T = 200°–330 °C and high fS2. The negative δ34S values (− 8.58 to − 3.70‰) of the enargite-luzonite are best explained by disproportionation reactions of magmatic SO2 and suggest that the high fS2 is likely provided by direct magmatic input of SO2 into the hydrothermal system. Fractionation of Cu stable isotopes during the precipitation of enargite-luzonite (δ65Cu ranges from − 0.20 to + 0.35‰) is inferred...
Tipo: Text Palavras-chave: Enargite; Epithermal; Hydrothermal vent; Luzonite; S-Cu isotopes; Seafloor.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00337/44844/44432.pdf
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