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| Lacan, F.; Radic, A.; Jeandel, C.; Poitrasson, F.; Sarthou, Geraldine; Pradoux, C.; Freydier, R.. |
| This work demonstrates for the first time the feasibility of the measurement of the isotopic composition of dissolved iron in seawater for a typical open ocean Fe concentration range (0.1-1 nM). It also presents the first data of this kind. Iron is preconcentrated using a Nitriloacetic Acid Superflow resin and purified using an AG1x4 anion exchange resin. The isotopic ratios are measured with a MC-ICPMS Neptune, coupled with a desolvator (Aridus II), using a Fe-57-Fe-58 double spike mass bias correction. Measurement precision (0.13%, 2SD) allows resolving small iron isotopic composition variations within the water column, in the Atlantic sector of the Southern Ocean (from delta Fe-57 = -0.19 to +0.32 parts per thousand). Isotopically light iron found in... |
| Tipo: Text |
Palavras-chave: MC ICP MS; Chelating resin; Southern ocean; Fractionation; Seawater; Earth; Separation; Accuracy; Pacific; FE(III). |
| Ano: 2008 |
URL: https://archimer.ifremer.fr/doc/00202/31374/29781.pdf |
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