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Calorimetric techniques applied to the thermodynamic study of interactions between proteins and polysaccharides Ciência Rural
Santos,Monique Barreto; Costa,Bernardo de Sá; Rojas,Edwin Elard Garcia.
ABSTRACT: The interactions between biological macromolecules have been important for biotechnology, but further understanding is needed to maximize the utility of these interactions. Calorimetric techniques provide information regarding these interactions through the thermal energy that is produced or consumed during interactions. Notable techniques include differential scanning calorimetry, which generates a thermodynamic profile from temperature scanning, and isothermal titration calorimetry that provide the thermodynamic parameters directly related to the interaction. This review described how calorimetric techniques can be used to study interactions between proteins and polysaccharides, and provided valuable insight into the thermodynamics of their...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Isothermal titration calorimetry; Differential scanning calorimetry; Calorimetric techniques; Biomolecules; Proteins..
Ano: 2016 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-84782016000801491
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Thermodynamic Characterization of Humic Acid-surfactant Interaction: New Insights into the Characteristics and Structure of Humic Acids Rev. Bras. Ciênc. Solo
Vergütz,Leonardus; Silva,Luis Henrique Mendes da; Novais,Roberto Ferreira; Silva,Maria do Carmo Hespanhol da; Mageste,Aparecida Barbosa; Silva,Ivo Ribeiro.
ABSTRACT Humic acids (HA) are a component of humic substances (HS), which are found in nearly all soils, sediments, and waters. They play a key role in many, if not most, chemical and physical properties in their environment. Despite the importance of HA, their high complexity makes them a poorly understood system. Therefore, understanding the physicochemical properties and interactions of HA is crucial for determining their fundamental role and obtaining structural details. Cationic surfactants are known to interact electrostatically and hydrophobically with HA. Because they are a very well-known and characterized system, they offer a good choice as molecular probes for studying HA. The objective of this study was to evaluate the interaction between...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Enthalpy; Humic substances; Isothermal titration calorimetry; Macromolecular structure; Microcalorimetry; Supramolecular structure.
Ano: 2015 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-06832015000601633
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