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Nickel Isotope Variations in Terrestrial Silicate Rocks and Geological Reference Materials Measured by MC-ICP-MS ArchiMer
Gueguen, Bleuenn; Rouxel, Olivier; Ponzevera, Emmanuel; Bekker, Andrey; Fouquet, Yves.
Although initial studies have demonstrated the applicability of Ni isotopes for cosmochemistry and as a potential biosignature, the Ni isotope composition of terrestrial igneous and sedimentary rocks, and ore deposits remains poorly known. Our contribution is fourfold: (a) to detail an analytical procedure for Ni isotope determination, (b) to determine the Ni isotope composition of various geological reference materials, (c) to assess the isotope composition of the Bulk Silicate Earth relative to the Ni isotope reference material NIST SRM 986 and (d) to report the range of mass-dependent Ni isotope fractionations in magmatic rocks and ore deposits. After purification through a two-stage chromatography procedure, Ni isotope ratios were measured by MC-ICP-MS...
Tipo: Text Palavras-chave: Nickel; Stable isotopes; MC-ICP-MS; Geological reference materials; Bulk Silicate Earth; Abiotic fractionation.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00159/27069/25332.pdf
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Determining sedimentary material sources in a Brazilian urban lake using Zn stable isotope compositions of bottom sediments: a preliminary study ArchiMer
Ferreira Araujo, Daniel; Boaventura, Geraldo; Mulholland, Daniel; Garnier, Jeremie; Machado, Wilson; Babinski, Marly; Dantas, Elton.
Zinc isotopes ratios provide qualitative and quantitative information about contributions from different Zn sources in the environment. Here we present the results of a preliminary study to identify the main sources controlling Zn isotope signatures of sediments from Lake Paranoá (Brazil), an urban water reservoir. The Zn isotope ratios were measured by MC-ICP-MS and expressed as δ66/64Zn notation relative to the JMC 3-0749-L solution. The studied sediments showed a narrow isotopic range (+0.00 to +0.13 ‰; n = 10) similar to that reported for intensely weathered soils worldwide (from -0.4 to +0.2‰). The geoaccumulation index (Igeo) also suggests low or negligible influence of Zn anthropogenic source. This research provides a baseline assessment of the Zn...
Tipo: Text Palavras-chave: Stable isotopes; MC-ICP-MS; Mass spectrometry; Environmental pollution; Metal contamination; Weathering; Zinc isotopes.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00666/77763/79899.pdf
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U-Pb zircon in situ dating with LA-MC-ICP-MS using a mixed detector configuration Anais da ABC (AABC)
Chemale Jr,Farid; Kawashita,Koji; Dussin,Ivo A.; Ávila,Janaína N.; Justino,Dayvisson; Bertotti,Anelise.
The LA-MC-ICP-MS method applied to U-Pb in situ dating is still rapidly evolving due to improvements in both lasers and ICP-MS. To test the validity and reproducibility of the method, 5 different zircon samples, including the standard Temora-2, ranging in age between 2.2 Ga and 246 Ma, were dated using both LA-MC-ICP-MS and SHRIMP. The selected zircons were dated by SHRIMP and, after gentle polishing, the laser spot was driven to the same site or on the same zircon phase with a 213 nm laser microprobe coupled to a multi-collector mixed system. The data were collected with a routine spot size of 25 μm and, in some cases, of 15 and 40 μm. A careful cross-calibration using a diluted U-Th-Pb solution to calculate the Faraday reading to counting rate conversion...
Tipo: Info:eu-repo/semantics/article Palavras-chave: MC-ICP-MS; SHRIMP; Faraday cups; Multi-ion Counting System; U-Pb in situ zircon dating.
Ano: 2012 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652012000200005
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