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| CALDEIRA,Ana Clara Rocha; FRANCA,Wanderley Filho Lopes de; CONVERTI,Attilio; LIMA,William James Nogueira; SAMPAIO,Fábio Coelho; FARIA,Janaína Teles de. |
| Abstract Aqueous two-phase systems (ATPS) are formed by mixtures of chemical species that, under certain conditions, separate into two immiscible phases, with water as the major component in global terms and, at lower concentrations, polymers, salts, ionic liquids and alcohols, depending on the system type. Different parameters influence ATPS equilibrium such as temperature, alcohol carbon chain size, salt type, pH, etc. The present work aimed to obtain the binodal curves for ATPS made up of ethanol, sodium citrate/ammonium sulfate and water at different temperatures (15, 25 and 35 °C) as well as to evaluate the potential of the ethanol/ammonium sulfate system in anthocyanins partition. The results showed that the increase in temperature did not alter the... |
| Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Biphasic region; Phase equilibrium; Liquid-liquid extraction. |
| Ano: 2019 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0101-20612019000600711 |
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| Legoix, Ludovic; Ruffine, Livio; Deusner, Christian; Haeckel, Matthias. |
| This article presents gas hydrate experimental measurements for mixtures containing methane (CH 4 ), carbon dioxide (CO 2 ) and nitrogen (N 2 ) with the aim to better understand the impact of water (H 2 O) on the phase equilibrium. Some of these phase equilibrium experiments were carried out with a very high water-to-gas ratio that shifts the gas hydrate dissociation points to higher pressures. This is due to the significantly different solubilities of the different guest molecules in liquid H 2 O. A second experiment focused on CH 4 -CO 2 exchange between the hydrate and the vapor phases at moderate pressures. The results show a high retention of CO 2 in the gas hydrate phase with small pressure variations within the first hours. However, for our system... |
| Tipo: Text |
Palavras-chave: Gas hydrates; CH4; CO2; N-2; High-pressure experiments; Phase equilibrium; Gas exchange. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00452/56345/57935.pdf |
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