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Spéciation des contaminants métalliques en milieu estuarien : Intérêt de la modélisation et application au cadmium ArchiMer
Gonzalez, Jean-louis; Dange, Catherine; Thouvenin, Benedicte.
In estuarine environment, cadmium has a nonconservative behavior. It can be present under various species: dissolved (mineral and organic complexes), colloidal and particulate forms (adsorbed, precipitated), or integrated by various mechanisms in the organisms. This distribution is the result of processes (physical, chemical and biological) which are controlled by many factors (salinity, pH, Eh, nature and concentration of suspended matter, primary production). Geochemical modeling is a very useful approach to understand the dynamics of this type of contaminant, especially in the complex systems which are the estuaries. A speciation model was used to simulate the measurements taken (dissolved and particulate Cd) during various cruises carried out in the...
Tipo: Text Palavras-chave: Cadmium; Estuary; Speciation; Modeling; Surface complexation; Cadmium; Estuaire; Spéciation; Modélisation; Complexation de surface.
Ano: 2001 URL: https://archimer.ifremer.fr/doc/00480/59120/61749.pdf
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Large nickel isotope fractionation caused by surface complexation reactions with hexagonal birnessite ArchiMer
Sorensen, Jeffry V.; Gueguen, Bleuenn; Stewart, Brandy D.; Peña, Jasquelin; Rouxel, Olivier; Toner, Brandy M..
Manganese oxides are an important sink for Ni in the ocean. To explore the potential of Ni stable isotopes as a geochemical tracer, we conducted two types of sorption reactions between Ni and hexagonal birnessite in 0.05 M NaNO3 media: one where we varied pH from 5 to 8 (constant initial Ni concentration = 170 μmol/L), and a second where we varied the initial dissolved Ni concentration from 17 to 426 μmol/L (constant pH = 7.7). Isotopic measurements were made on both the solid phase and the supernatant solutions to determine the Ni isotope fractionation factors (∆60/58Nimin-aq = δ60/58Nimin − δ60/58Niaq) between the mineral and aqueous phases. Nickel extended X-ray absorption fine structure (EXAFS) spectroscopy showed Ni in two distinct bonding...
Tipo: Text Palavras-chave: Ni stable isotope fractionation; Ni EXAFS; Surface complexation; Birnessite; Tracer development.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00606/71799/73086.pdf
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