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Garcia-Guinea,Javier; Correcher,Virgilio; Recio-Vazquez,Lorena; Crespo-Feo,Elena; Gonzalez-Martin,Rafael; Tormo,Laura. |
The presence of high level of heavy metals involves a human healthy risk that could induce chronic diseases. This work reports on the metal contamination due to heaps of steel-slag accumulated during more than 40 years in allotments and industrial areas in the southern part of Madrid (Spain). Several slag and soil samples were collected in an area of 10 km² and characterized by different conventional (XRD and XRF) and no so common methods (ESEM, thermoluminescence and EDS-WDS). The analysis reveal the presence of: (i) important amounts of Fe (43%), Mg (26%), Cr (1.1%), Mn (4.6%), S (6.5%) in the form of Fe-rich slag phases (wustite, magnetite...), Si and Ca-rich phases (larnite, ghelenite...), Cr (chromite), Mn (bustamite) and graphite, (ii) traces of some... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: EDS; ESEM; Metal contamination; Steel slag; TL; XRD; XRF. |
Ano: 2010 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652010000200003 |
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WATANABE,SHIGUEO; CANO,NILO F.; RAO,T.K. GUNDU; SILVA-CARRERA,BETZABEL N.; CARMO,LUCAS S.; QUINA,ANTONIO J.A.; GENNARI,ROSELI F.; MUNITA,CASIMIRO S.; AYALA-ARENAS,JORGE S.; FERNANDES,BRUNO G.. |
ABSTRACT A cylindrical fragment of stalagmite from Caverna do Diabo, State of São Paulo, Brazil, has been studied and dated by thermoluminescence and electron paramagnetic resonance techniques. The thermoluminescence glow curves of stalagmite samples and subsequently gamma irradiated, have shown rise of three peaks at 135, 180 and 265 °C. From electron paramagnetic resonance spectra of stalagmite was possible to clearly identify three paramagnetic centers in the g = 2.0 region: Centers I, II and III are due to , and , respectively. The additive method was applied to calculate the accumulated dose using thermoluminescence peak at 265 °C and the electron paramagnetic resonance signal at g = 1.9973 of CO- 2 radical. The ages of the different slices of... |
Tipo: Info:eu-repo/semantics/article |
Palavras-chave: Stalagmite; Caverna do Diabo; Dating; TL; EPR. |
Ano: 2016 |
URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652016000602137 |
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