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Copper, zinc and lead isotope signatures of sediments from a mediterranean coastal bay impacted by naval activities and urban sources 5
Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Bruzac, Sandrine; Sireau, Teddy; Brach-papa, Christophe.
Toulon bay is severely impacted by metal contamination induced by past and recent naval activities. In this work, Cu, Zn and Pb isotope compositions and elemental concentrations of fifty-five surface sediments were determined in order to map the spatial distribution of anthropogenic and natural sources along this land-sea continuum. Two sub-systems of Toulon Bay, the Small and Large bays, showed well-marked patterns on metal contamination levels and isotope signatures for Cu and Pb. The Small bay had the highest metal concentrations, and displayed average Pb and Cu isotope compositions of 1.1664 ± 0.0043 (1s, expressed as 206Pb/207Pb ratios) and −0.17 ± 0.19‰ (1s, expressed as δ65CuNIST values), respectively. It contrasted with the Large bay, with moderate...
Tipo: Text Palavras-chave: Metal isotopes; Isotope tracers; Geochemical isotopes; Environmental pollution; Coastal pollution; Toulon bay.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00566/67784/67226.pdf
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Assessment of the metal contamination evolution in the Loire estuary using Cu and Zn stable isotopes and geochemical data in sediments 5
Ferreira Araujo, Daniel; Ponzevera, Emmanuel; Briant, Nicolas; Knoery, Joel; Sireau, Teddy; Mojtahid, Meryem; Metzger, Edouard; Brach-papa, Christophe.
In this work, a multi-elemental approach combining Cu and Zn stable isotopes is used to assess the metal contamination evolution in the Loire estuary bulk sediments. Elemental geochemical data indicate an increase of metal concentrations from the beginning of the industrial period peaking in the 1990s, followed by an attenuation of metal contamination inputs to the estuary. Zinc isotope compositions suggest a binary mixing process between Zn derived from terrigenous material and multi-urban anthropogenic sources. Copper isotope systematics indicate a single natural dominant source represented by weathered silicate particles from soils and rocks. This work demonstrates the applicability of Zn isotopes to identify anthropogenic Zn sources in coastal systems,...
Tipo: Text Palavras-chave: Coastal pollution; Coastal biogeochemistry; Geochemical tracers; Metal isotopes; Trace metal; Anthropogenic contamination.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00490/60188/67760.pdf
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Geochemical methods to infer landscape response to Quaternary climate change and land use in depositional archives: A review 5
Francke, Alexander; Holtvoeth, Jens; Codilean, Alexandru; Lacey, Jack H.; Bayon, Germain; Dosseto, Anthony.
Understanding and quantifying the processes and geochemical cycles associated with catchment erosion, the development of soils and weathering horizons, and terrestrial habitat change beyond the scales of modern observations remain challenging. Such research, however, has become increasingly important to help predict future landscape change in light of increasing land use and rapid global warming. We herein review organic and inorganic geochemical tools applied to depositional archives to better understand various aspects of landscape evolution on geological time scales. We highlight the potentials and limitations of inorganic geochemical analytical methods, such as major element geochemistry, metal and radiogenic isotopes, and in-situ cosmogenic nuclides,...
Tipo: Text Palavras-chave: Quaternary landscape evolution; Catchment erosion; Terrestrial habitat change; Land use; Fluvial; Lacustrine; Inorganic geochemistry; Organic geochemistry; Radiogenic isotopes; Metal isotopes; Uranium isotopes; Cosmogenic nuclides.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00632/74383/74084.pdf
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