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Atmospheric CO2 estimates for the Miocene to Pleistocene based on foraminiferal δ11B at Ocean Drilling Program Sites 806 and 807 in the Western Equatorial Pacific ArchiMer
Guillermic, Maxence; Misra, Sambuddha; Eagle, Robert; Tripati, Aradhna.
Constraints on the evolution of atmospheric CO2 levels throughout Earth's history are foundational to our understanding of past variations in climate. Despite considerable effort, estimates of past CO2 levels do not always converge and therefore new records and proxies are valuable. Here we reconstruct atmospheric CO2 values across major climate transitions over the past 17 million years using the boron isotopic composition (δ11B) of planktic foraminifera from 89 samples obtained from two sites in the West Pacific Warm Pool, Ocean Drilling Program (ODP) Sites 806 and 807. These sites are in a region that today is in equilibrium with the atmosphere and are thought to have been in equilibrium with the atmosphere for the interval studied. We use...
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Ano: 2021 URL: https://archimer.ifremer.fr/doc/00678/79045/81493.pdf
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Carbonate "clumped" isotope signatures in aragonitic scleractinian and calcitic gorgonian deep-sea corals ArchiMer
Kimball, Justine; Eagle, Robert; Dunbar, Robert.
Deep-sea corals are a potentially valuable archive of the temperature and ocean chemistry of intermediate and deep waters. Living in near-constant temperature, salinity, and pH and having amongst the slowest calcification rates observed in carbonate-precipitating biological organisms, deep-sea corals can provide valuable constraints on processes driving mineral equilibrium and disequilibrium isotope signatures. Here we report new data to further develop "clumped" isotopes as a paleothermometer in deep-sea corals as well as to investigate mineral-specific, taxon-specific, and growth-rate-related effects. Carbonate clumped isotope thermometry is based on measurements of the abundance of the doubly substituted isotopologue (COO2)-C-13-O-18-O-16 in carbonate...
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Ano: 2016 URL: https://archimer.ifremer.fr/doc/00369/48042/72992.pdf
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Seawater pH reconstruction using boron isotopes in multiple planktonic foraminifera species with different depth habitats and their potential to constrain pH and pCO(2) gradients ArchiMer
Guillermic, Maxence; Misra, Sambuddha; Eagle, Robert; Villa, Alexandra; Chang, Fengming; Tripati, Aradhna.
Boron isotope systematics of planktonic foraminifera from core-top sediments and culture experiments have been studied to investigate the sensitivity of delta B-11 of calcite tests to seawater pH. However, our knowledge of the relationship between delta B-11 and pH remains incomplete for many taxa. Thus, to expand the potential scope of application of this proxy, we report delta B-11 data for seven different species of planktonic foraminifera from sediment core tops. We utilize a method for the measurement of small samples of foraminifera and calculate the delta B-11-calcite sensitivity to pH for Globigerinoides ruber, Trilobus sacculifer (sacc or without sacc), Orbulina universa, Pulleniatina obliquiloculata, Neogloboquadrina dutertrei, Globorotalia...
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Ano: 2020 URL: https://archimer.ifremer.fr/doc/00687/79861/82712.pdf
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