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A Review of the Stable Isotope Bio-geochemistry of the Global Silicon Cycle and Its Associated Trace Elements ArchiMer
Sutton, Jill N.; Andre, Luc; Cardinal, Damien; Conley, Daniel J.; De Souza, Gregory F.; Dean, Jonathan; Dodd, Justin; Ehlert, Claudia; Ellwood, Michael J.; Frings, Patrick J.; Grasse, Patricia; Hendry, Katharine; Leng, Melanie J.; Michalopoulos, Panagiotis; Panizzo, Virginia N.; Swann, George E. A..
Silicon (Si) is the second most abundant element in the Earth's crust and is an important nutrient in the ocean. The global Si cycle plays a critical role in regulating primary productivity and carbon cycling on the continents and in the oceans. Development of the analytical tools used to study the sources, sinks, and fluxes of the global Si cycle (e.g., elemental and stable isotope ratio data for Ge, Si, Zn, etc.) have recently led to major advances in our understanding of the mechanisms and processes that constrain the cycling of Si in the modern environment and in the past. Here, we provide background on the geochemical tools that are available for studying the Si cycle and highlight our current understanding of the marine, freshwater and terrestrial...
Tipo: Text Palavras-chave: C - N - O - Si isotopes; Biogenic silica; Element/Si ratios; Biogeochemical cycles; Silicon.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00431/54217/55547.pdf
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Biogeochemical controls of surface ocean phosphate ArchiMer
Martiny, Adam C.; Lomas, Michael W.; Fu, Weiwei; Boyd, Philip W.; Chen, Yuh-ling L.; Cutter, Gregory A.; Ellwood, Michael J.; Furuya, Ken; Hashihama, Fuminori; Kanda, Jota; Karl, David M.; Kodama, Taketoshi; Li, Qian P.; Ma, Jian; Moutin, Thierry; Woodward, E. Malcolm S.; Moore, J. Keith.
Surface ocean phosphate is commonly below the standard analytical detection limits, leading to an incomplete picture of the global variation and biogeochemical role of phosphate. A global compilation of phosphate measured using high-sensitivity methods revealed several previously unrecognized low-phosphate areas and clear regional differences. Both observational climatologies and Earth system models (ESMs) systematically overestimated surface phosphate. Furthermore, ESMs misrepresented the relationships between phosphate, phytoplankton biomass, and primary productivity. Atmospheric iron input and nitrogen fixation are known important controls on surface phosphate, but model simulations showed that differences in the iron-to-macronutrient ratio in the...
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Ano: 2019 URL: https://archimer.ifremer.fr/doc/00511/62308/66557.pdf
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