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A Review of the Stable Isotope Bio-geochemistry of the Global Silicon Cycle and Its Associated Trace Elements ArchiMer
Sutton, Jill N.; Andre, Luc; Cardinal, Damien; Conley, Daniel J.; De Souza, Gregory F.; Dean, Jonathan; Dodd, Justin; Ehlert, Claudia; Ellwood, Michael J.; Frings, Patrick J.; Grasse, Patricia; Hendry, Katharine; Leng, Melanie J.; Michalopoulos, Panagiotis; Panizzo, Virginia N.; Swann, George E. A..
Silicon (Si) is the second most abundant element in the Earth's crust and is an important nutrient in the ocean. The global Si cycle plays a critical role in regulating primary productivity and carbon cycling on the continents and in the oceans. Development of the analytical tools used to study the sources, sinks, and fluxes of the global Si cycle (e.g., elemental and stable isotope ratio data for Ge, Si, Zn, etc.) have recently led to major advances in our understanding of the mechanisms and processes that constrain the cycling of Si in the modern environment and in the past. Here, we provide background on the geochemical tools that are available for studying the Si cycle and highlight our current understanding of the marine, freshwater and terrestrial...
Tipo: Text Palavras-chave: C - N - O - Si isotopes; Biogenic silica; Element/Si ratios; Biogeochemical cycles; Silicon.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00431/54217/55547.pdf
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GEOTRACES inter-calibration of the stable silicon isotope composition of dissolved silicic acid in seawater ArchiMer
Grasse, Patricia; Brzezinski, Mark A.; Cardinal, Damien; De Souza, Gregory F.; Andersson, Per; Closset, Ivia; Cao, Zhimian; Dai, Minhan; Ehlert, Claudia; Estrade, Nicolas; Francois, Roger; Frank, Martin; Jiang, Guibin; Jones, Janice L.; Kooijman, Ellen; Liu, Qian; Lu, Dawei; Pahnke, Katharina; Ponzevera, Emmanuel; Schmitt, Melanie; Sun, Xiaole; Sutton, Jill; Thil, Francois; Weis, Dominique; Wetzel, Florian; Zhang, Anyu; Zhang, Jing; Zhang, Zhouling.
The first inter-calibration study of the stable silicon isotope composition of dissolved silicic acid in seawater, delta Si-30(OH)(4), is presented as a contribution to the international GEOTRACES program. Eleven laboratories from seven countries analyzed two seawater samples from the North Pacific subtropical gyre (Station ALOHA) collected at 300 m and at 1000 m water depth. Sampling depths were chosen to obtain samples with a relatively low (9 mmol L-1, 300 m) and a relatively high (113 mmol L-1, 1000 m) silicic acid concentration as sample preparation differs for low- and highconcentration samples. Data for the 1000 m water sample were not normally distributed so the median is used to represent the central tendency for the two samples. Median delta...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00381/49270/49681.pdf
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