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| Shao, Limin; Bianxia, Liu; Griffiths R, Peter; Leytem, A.B.. |
| A technique of using multiple calibration sets in partial least squares regression (PLS) was proposed to improve the quantitative determination of ammonia from open-path Fourier transform infrared spectra. The spectra were measured near animal farms, and the path-integrated concentration of ammonia fluctuated from nearly zero to a high of about 1000 ppm-m. The PLS regression using a single calibration set over such a large concentration range had decreased quantitative accuracy due to the nonlinear relationship between concentration and absorbance. In the PLS regression with multiple calibration sets, each calibration set accounted for a smaller concentration range, which significantly decreased the serious nonlinearity problem in PLS regression with a... |
| Tipo: Article |
Palavras-chave: Air Emissions; Manure. |
| Ano: 2011 |
URL: http://eprints.nwisrl.ars.usda.gov/1428/1/1398.pdf |
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