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| Ginigini, Joape; Lecellier, Gael J.; Nicolas, Mael; Nour, Mohammed; Hnawia, Edouard; Lebouvier, Nicolas; Herbette, Gaetan; Lockhart, Peter; Raharivelomanana, Phila. |
| Background: Different parts of the tree Calophyllum inophyllum L. (nuts, leaves, roots, bark, fruits, nut oil and resin) are used as traditional medicines and cosmetics in most of the Pacific Islands. The oil efficiency as a natural cure and in traditional cosmetics has been largely described throughout the South Pacific, which led us to investigate C. inophyllum's chemical and genetic diversity. A correlative study of the nut resin and leaf DNA from three distinct archipelagos in the South Pacific was carried out in order to identify diversity patterns in C. inophyllum across the South Pacific. Methods: Calophyllum inophyllum plants were sampled from French Polynesia, New Caledonia and Fiji. We extracted tamanu oil (nut oil) resin for chemo-diversity... |
| Tipo: Text |
Palavras-chave: Calophyllum inophyllum; Chemodiversity; South Pacific; Neoflavonoids; Oil; Biodiversity. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00659/77126/78506.pdf |
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| Metoyer, Benjamin; Lebouvier, Nicolas; Hnawia, Edouard; Herbette, Gaetan; Thouvenot, Louis; Asakawa, Yoshinori; Nour, Mohammed; Raharivelomanana, Phila. |
| Volatile components of seven species of the Bazzanioideae sub-family (Lepidoziaceae) native to New Caledonia, including three endemic species (Bazzania marginata, Acromastigum caledonicum and A. tenax), were analyzed by GC-FID-MS in order to index these plants to known or new chemotypes. Detected volatile constituents in studied species were constituted mainly by sesquiterpene, as well as diterpene compounds. All so-established compositions cannot successfully index some of them to known chemotypes but afforded the discovery of new chemotypes such as cuparane/fusicoccane. The major component of B. francana was isolated and characterized as a new zierane-type sesquiterpene called ziera-12(13), 10(14)-dien-5-ol (23). In addition, qualitative intraspecies... |
| Tipo: Text |
Palavras-chave: Liverwort; Bazzania; Acromastigum; Sesquiterpene; Diterpene; Bis(bibenzyl); Biosynthesis; Zierane; Vittatin. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00660/77222/78670.pdf |
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| Tahtinen, Petri; Guella, Graziano; Saielli, Giacomo; Debitus, Cecile; Hnawia, Edouard; Mancini, Ines. |
| Arsenicin A (C3H6As4O3) was isolated from the New Caledonian poecilosclerid sponge Echinochalina bargibanti, and described as the first natural organic polyarsenic compound. Further bioguided fractionation of the extracts of this sponge led us to isolate the first sulfur-containing organic polyarsenicals ever found in Nature. These metabolites, called arsenicin B and arsenicin C, are built on a noradamantane-type framework that is characterized by an unusual As-As bonding. Extensive NMR measurements, in combination with mass spectra, enabled the assignment of the structure for arsenicin B (C3H6As4S2) as 2. The scarcity of arsenicin C and its intrinsic chemical instability only allowed the collection of partial spectral data, which prevented the full... |
| Tipo: Text |
Palavras-chave: Antibacterial; Arsenical; Calculated NMR spectrum; Density functional theory; Natural products; NMR spectroscopy; Structure elucidation; Sulfur metabolite. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00469/58051/72242.pdf |
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| Leguillier, Teddy; Lecso-bornet, Marylin; Lemus, Christelle; Rousseau-ralliard, Delphine; Lebouvier, Nicolas; Hnawia, Edouard; Nour, Mohammed; Aalbersberg, William; Ghazi, Kamelia; Raharivelomanana, Phila; Rat, Patrice. |
| Background Calophyllum inophyllum L. (Calophyllaceae) is an evergreen tree ethno-medically used along the seashores and islands of the Indian and Pacific Oceans, especially in Polynesia. Oil extracted from the seeds is traditionally used topically to treat a wide range of skin injuries from burn, scar and infected wounds to skin diseases such as dermatosis, urticaria and eczema. However, very few scientific studies reported and quantified the therapeutic properties of Calophyllum inophyllum oil (CIO). In this work, five CIO from Indonesia (CIO1), Tahiti (CIO2, 3), Fiji islands (CIO4) and New Caledonia (CIO5) were studied and their cytotoxic, wound healing, and antibacterial properties were presented in order to provide a scientific support to their... |
| Tipo: Text |
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| Ano: 2015 |
URL: https://archimer.ifremer.fr/doc/00667/77934/80119.pdf |
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