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| Paluselli, Andrea. |
| Phthalic Acid Esters (PAEs) are a group of emerging organic contaminants that have become a serious issue because of their ubiquitous presence on the marine environment worldwide and for the endocrine disrupting effects in animals and humans. However, little is known about their distribution in the Ocean, mainly because of analytical difficulties and the high possibility of ambient sample contamination. Plastic debris in marine environment includes resin pellets, macro- and microplastic fragments, and contains additives such as PAEs that might be released in the aquatic environment in unknown proportion. In our work, we improved an analytical method for the determination of 8 PAEs, at trace levels in marine and fresh waters. In the first part of the... |
| Tipo: Text |
Palavras-chave: Phtalates; DEHP; Eau de mer; Perturbateurs endocriniens; Microplastiques; Microplastics; Endocrine disruptors; Seawater; Phthalates; Dehp. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00497/60904/64252.pdf |
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| Paluselli, Andrea; Fauvelle, Vincent; Schmidt, Natascha; Galgani, Francois; Net, Sopheak; Sempere, Richard. |
| Phthalic Acid Esters (PAEs) are a group of emerging organic contaminants that have become a serious issue because of their ubiquitous presence and hazardous impact on the marine environment worldwide. Seawater samples were collected monthly from December 2013 to November 2014 in the northwestern Mediterranean Sea (Marseille Bay). The samples were analyzed for dissolved organic carbon (DOC) as well as the molecular distribution of dissolved PAEs by using solid phase extraction followed by gas chromatography and mass spectrometry (GC/MS) analyses. The results demonstrated the occurrence of six PAEs, including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-isobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP) and... |
| Tipo: Text |
Palavras-chave: Phthalates; DEHP; DMP; Seawater; Dissolved organic matter; Endocrine disruptors. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00413/52482/53358.pdf |
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| Paluselli, Andrea; Aminot, Yann; Galgani, Francois; Net, Sopheak; Sempere, Richard. |
| Phthalate acid esters (PAEs) which are mainly anthropogenic molecules with endocrine disrupting effects in animals and humans, have been detected in terrestrial and aquatic environments. However, little is known about their distribution in the Mediterranean Sea, mainly because of analytical difficulties and the high possibility of ambient sample contamination. Here, we report the optimization of an existing protocol for the determination of PAEs in seawater and freshwater samples, as well as the first estimation of the source and distribution of phthalates acid esters (PAEs) in coastal waters from the NW Mediterranean Sea. By passing 1 L of sample through glass cartridges packed with 200 mg of Oasis HLB and eluted with 6 mL of ethyl acetate, the recoveries... |
| Tipo: Text |
Palavras-chave: Phthalates; DEHP; DMP; Dissolved organic matter; Endocrine disruptors. |
| Ano: 2018 |
URL: http://archimer.ifremer.fr/doc/00389/50012/50601.pdf |
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| Paluselli, Andrea; Fauvelle, Vincent; Galgani, Francois; Sempere, Richard. |
| Plastic debris in the environment contain plasticizers, such as phthalates (PAEs), that can be released during plastic aging. Here, two common plastic materials, i.e., an insulation layer of electric cables (polyvinylchloride, PVC-cables) and plastic garbage bag (polyethylene, PE-bags), were incubated in natural seawater under laboratory conditions, and the PAE migration to the seawater phase was studied with varying light and bacterial conditions over a 90-day time course. Free PAEs diluted in seawater were also studied for bacterial degradation. Our results showed that, within the first month of incubation, both plastic materials significantly leached out PAEs in surrounding water. We found that di-isobutyl phthalate (DiBP) and di-n-butyl phthalate... |
| Tipo: Text |
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| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00470/58137/60607.pdf |
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