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| Cuartero, Maria; Crespo, Gaston; Cherubini, Thomas; Pankratova, Nadezda; Confalonieri, Fabio; Massa, Francesco; Tercier-waeber, Mary-lou; Abdou, Melina; Schafer, Jorg; Bakker, Eric. |
| A new submersible probe for the in situ detection of nitrate, nitrite and chloride in seawater is presented. Inline coupling of a desalination unit, an acidification unit and a sensing flow cell containing all-solid-state membrane electrodes allows for the potentiometric detection of nitrate and nitrite after removal of the key interfering ions in seawater, chloride and hydroxide. Thus, the electrodes exhibited attractive analytical performances for the potentiometric detection of nitrate and nitrite in desalinated and acidified seawater: fast response time (t95<12 s), excellent stability (long-term drifts of < 0.5 mV h-1), good reproducibility (calibration parameter deviation of < 3 %) and satisfactory accuracy (uncertainties < 8 %Diff... |
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| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00431/54230/55554.pdf |
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| Abdou, Melina; Schafer, Jorg; Hu, Ruoyu; Gil-diaz, Teba; Garnier, Cedric; Brach-papa, Christophe; Chiffoleau, Jean-francois; Charmasson, Sabine; Giner, Franck; Dutruch, Lionel; Blanc, Gerard. |
| Platinum (Pt) is considered a Technology Critical Element (TCE) and an emerging metallic contaminant with increasing release into the environment. Gaps in knowledge and understanding of environmental levels, fate and effects of Pt still exist, especially in the marine environment. This work presents Pt concentrations in the northwestern Mediterranean coast including: (i) temporal variability from sediment cores and farmed mussels in the Toulon Bay (historically affected by intense human activities) and (ii) spatial distribution from recent wild mussels collected along ∼ 300 km coastline with contrasting ecosystems (including natural reserves), quantified using voltammetry and inductively coupled plasma-mass spectrometry. The historical (> 100 years)... |
| Tipo: Text |
Palavras-chave: Platinum; Sediments; Mussels; Biomonitoring; Mediterranean coast. |
| Ano: 2019 |
URL: https://archimer.ifremer.fr/doc/00460/57134/59055.pdf |
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| Cossa, Daniel; De Madron, Xavier Durrieu; Schafer, Jorg; Guedron, Stephane; Marusczak, Nicolas; Castelle, Sabine; Naudin, Jean-jacques. |
| Ocean margins are focal regions in terms of mercury (Hg) exchanges between the continent and the open sea. The aim of this paper is to describe the distribution and partition of Hg between the gaseous, dissolved and particulate phases in the waters of the Northwestern Mediterranean (NWM) margin, in order to assess the Hg sources and exchanges within the continuum between the continental shelf (Gulf of Lions) and the open sea (Northern Gyre). Mean (± standard deviation) of total Hg species (HgT) concentrations in unfiltered water samples were 1.52 ± 1.00 pmol L-1 (n=36) in the inner shelf, 1.09 ± 0.15 pmol L-1 (n=30) along the slope, and 1.10 ± 0.13 pmol L-1 (n=99) in the Northern Gyre. The dissolved phase (<0.45µm) average concentrations were 0.80 ±... |
| Tipo: Text |
Palavras-chave: Mercury; Ocean margin; Coastal area; Mediterranean. |
| Ano: 2018 |
URL: http://archimer.ifremer.fr/doc/00384/49563/50055.pdf |
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| Cossa, Daniel; De Madron, Xavier Durrieu; Schafer, Jorg; Lanceleur, Laurent; Guedron, Stephane; Buscail, Roselyne; Thomas, Bastien; Castelle, Sabine; Naudin, Jean-jacques. |
| Despite the ecologic and economical importance of coastal areas, the neurotoxic bioaccumulable monomethylmercury (MMHg) fluxes within the ocean margins and exchanges with the open sea remain unassessed. The aim of this paper is to address the questions of the abundance, distribution, production and exchanges of methylated mercury species (MeHgT), including MMHg and dimethylmercury (DMHg), in the waters, atmosphere and sediments of the Northwestern Mediterranean margin including the Rhône River delta, the continental shelf and its slope (Gulf of Lions) and the adjacent open sea (North Gyre). Concentrations of MeHgT ranged from <0.02 to 0.48 pmol L−1 with highest values associated with the oxygen-deficient zone of the open sea. The methylated mercury to... |
| Tipo: Text |
Palavras-chave: Mercury; Methylmercury; Ocean margin; Coastal area; Mediterranean. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00363/47399/47477.pdf |
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