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Increasing the quantitative credibility of open-path FT-IR spectroscopic data with focus on several properties of the background spectrum NWISRL
Shao, L.; Wang, Wanping; Griffiths, P.R.; Leytem, A.B..
The choice of the type of background spectrum affects the credibility of open-path Fourier transform infrared (OP/FT-IR) spectroscopic data, and consequently the quality of data analysis. We systematically investigated several properties of the background spectrum. The results show that a short-path background measured with the lowest amplifier gain could significantly reduce noise in the calculated absorbance spectrum, by at least 30% in our case. We demonstrated that by using a short-path background, data analysis is more resistant to interferences, such as wavenumber shift or resolution alteration that occurs as a consequence of hardware aging or misalignment. We also discussed a systematic error introduced into quantitative analyses by the...
Tipo: Article Palavras-chave: Air Emissions.
Ano: 2013 URL: http://eprints.nwisrl.ars.usda.gov/1507/1/1470.pdf
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