Sabiia Seb
PortuguêsEspañolEnglish
Embrapa
        Busca avançada

Botão Atualizar


Botão Atualizar

Ordenar por: 

RelevânciaAutorTítuloAnoImprime registros no formato resumido
Registros recuperados: 2
Primeira ... 1 ... Última
Imagem não selecionada

Imprime registro no formato completo
Accelerated ageing and lifetime prediction of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in distilled water ArchiMer
Deroine, Morgan; Le Duigou, Antoine; Corre, Yves-marie; Le Gac, Pierre-yves; Davies, Peter; Cesar, Guy; Bruzaud, Stephane.
Accelerated ageing was performed in distilled water at different temperatures (25, 30, 40 and 50°C) on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), which is a biodegradable biopolymer, in order to estimate its lifetime in aqueous environment. In a first part, degradation mechanisms were followed by gravimetry, tensile tests and steric exclusion chromatography. Both immersion and relative humidity have been examined. In a second part, the strain at break was used as an indicator for lifetime prediction with an Arrhenius extrapolation. The study revealed the presence of only one irreversible degradation mechanism, i.e. hydrolytic degradation, which is temperature dependant. So, within the approach assumptions, the lifetime in distilled water of PHBV...
Tipo: Text Palavras-chave: Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Accelerated ageing; Hydrothermal degradation; Lifetime prediction.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00203/31396/29785.pdf
Imagem não selecionada

Imprime registro no formato completo
Limits in the validity of Arrhenius predictions for field ageing of a silica filled polychloroprene in a marine environment ArchiMer
Le Saux, V.; Le Gac, Pierre-yves; Marco, Y.; Calloch, S..
Accelerated ageing in natural sea water at different temperatures from 20°C to 80°C was performed on a silica filled polychloroprene rubber. Degradation when monitored with mechanical properties at both macroscopic and microscopic scale led to a large increase of the modulus coupled with a strong decrease of strain and stress at break. Data from tensile tests were used for lifetime prediction with an Arrhenius extrapolation for modulus, strain and stress at break. The validity of this lifetime prediction was evaluated using a 23 year-old sample aged in natural conditions. Strain at break could be predicted using an Arrhenius extrapolation with an activation energy of 50 kJ/mol. However, an extrapolation based on linear Arrhenius behavior did not apply for...
Tipo: Text Palavras-chave: Polychloroprene rubber; Accelerated and natural ageing tests; Arrhenius extrapolation; Lifetime prediction; Sea water.
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00164/27523/25679.pdf
Registros recuperados: 2
Primeira ... 1 ... Última
 

Empresa Brasileira de Pesquisa Agropecuária - Embrapa
Todos os direitos reservados, conforme Lei n° 9.610
Política de Privacidade
Área restrita

Embrapa
Parque Estação Biológica - PqEB s/n°
Brasília, DF - Brasil - CEP 70770-901
Fone: (61) 3448-4433 - Fax: (61) 3448-4890 / 3448-4891 SAC: https://www.embrapa.br/fale-conosco

Valid HTML 4.01 Transitional