|
|
|
|
|
Paluselli, Andrea. |
Phthalic Acid Esters (PAEs) are a group of emerging organic contaminants that have become a serious issue because of their ubiquitous presence on the marine environment worldwide and for the endocrine disrupting effects in animals and humans. However, little is known about their distribution in the Ocean, mainly because of analytical difficulties and the high possibility of ambient sample contamination. Plastic debris in marine environment includes resin pellets, macro- and microplastic fragments, and contains additives such as PAEs that might be released in the aquatic environment in unknown proportion. In our work, we improved an analytical method for the determination of 8 PAEs, at trace levels in marine and fresh waters. In the first part of the... |
Tipo: Text |
Palavras-chave: Phtalates; DEHP; Eau de mer; Perturbateurs endocriniens; Microplastiques; Microplastics; Endocrine disruptors; Seawater; Phthalates; Dehp. |
Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00497/60904/64252.pdf |
| |
|
|
Paluselli, Andrea; Fauvelle, Vincent; Schmidt, Natascha; Galgani, Francois; Net, Sopheak; Sempere, Richard. |
Phthalic Acid Esters (PAEs) are a group of emerging organic contaminants that have become a serious issue because of their ubiquitous presence and hazardous impact on the marine environment worldwide. Seawater samples were collected monthly from December 2013 to November 2014 in the northwestern Mediterranean Sea (Marseille Bay). The samples were analyzed for dissolved organic carbon (DOC) as well as the molecular distribution of dissolved PAEs by using solid phase extraction followed by gas chromatography and mass spectrometry (GC/MS) analyses. The results demonstrated the occurrence of six PAEs, including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-isobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP) and... |
Tipo: Text |
Palavras-chave: Phthalates; DEHP; DMP; Seawater; Dissolved organic matter; Endocrine disruptors. |
Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00413/52482/53358.pdf |
| |
|
|
Hermabessiere, Ludovic; Dehaut, Alexandre; Paul-pont, Ika; Lacroix, Camille; Jezequel, Ronan; Soudant, Philippe; Duflos, Guillaume. |
Plastics debris, especially microplastics, have been found worldwide in all marine compartments. Much research has been carried out on adsorbed pollutants on plastic pieces and hydrophobic organic compounds (HOC) associated with microplastics. However, only a few studies have focused on plastic additives. These chemicals are incorporated into plastics from which they can leach out as most of them are not chemically bound. As a consequence of plastic accumulation and fragmentation in oceans, plastic additives could represent an increasing ecotoxicological risk for marine organisms. The present work reviewed the main class of plastic additives identified in the literature, their occurrence in the marine environment, as well as their effects on and transfers... |
Tipo: Text |
Palavras-chave: Microplastics; Plastic additives; Bisphenol A; Phthalates; Brominated flame retardant. |
Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00391/50227/51394.pdf |
| |
|
|
Paluselli, Andrea; Aminot, Yann; Galgani, Francois; Net, Sopheak; Sempere, Richard. |
Phthalate acid esters (PAEs) which are mainly anthropogenic molecules with endocrine disrupting effects in animals and humans, have been detected in terrestrial and aquatic environments. However, little is known about their distribution in the Mediterranean Sea, mainly because of analytical difficulties and the high possibility of ambient sample contamination. Here, we report the optimization of an existing protocol for the determination of PAEs in seawater and freshwater samples, as well as the first estimation of the source and distribution of phthalates acid esters (PAEs) in coastal waters from the NW Mediterranean Sea. By passing 1 L of sample through glass cartridges packed with 200 mg of Oasis HLB and eluted with 6 mL of ethyl acetate, the recoveries... |
Tipo: Text |
Palavras-chave: Phthalates; DEHP; DMP; Dissolved organic matter; Endocrine disruptors. |
Ano: 2018 |
URL: http://archimer.ifremer.fr/doc/00389/50012/50601.pdf |
| |
|
|
|