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Provedor de dados:  Scientia Agricola
País:  Brazil
Título:  Copper and zinc quantification in contaminated soil as evaluated by chemical extractants
Autores:  Silva,Maria Ligia de Souza
Trevizam,Anderson Ricardo
Vitti,Godofredo César
Data:  2008-12-01
Ano:  2008
Palavras-chave:  DTPA
HCl
Crops
Mehlich-1
Sequential extraction
Resumo:  Trace elements are potentially toxic to the environment. Their toxicity in soils relies on their type of chemical associations. Hence it is important to determine the chemical form they occur in the soils in order to assess their quantities. The objective the present work was to evaluate the possibility of using the concentrations of Cu and Zn in different soil fractions and the total concentration as predictors of their quantification by comparing the classical extractants DTPA, Mehlich-1 and HCl. Comparisons were made also with the concentrations of absorbed by rice and soybean in contaminated soil. Seven soil samples with a different degree of contamination were studied using a randomized experimental design, with four replicates. By using an ICP-OES we analyzed the concentrations of Cu and Zn in the diagnostic leafs, at the end of the cycle (LCE) and several of its content in the soil: available extracted with the DTPA, Mehlich-1 and HCl extractants, soluble+exchangeable contents, bound to organic matter, to oxides and the total content. For both, soybean and rice, the concentrations of Cu and Zn extracted from the sequential extraction was found to be correlated with the concentration in LCE. For soybean, Zn concentration extracted with DTPA was correlated with the total concentration, while Cu concentration extracted with three extractors, DTPA, Mehlich-1 and HCl, correlated with the total concentration, probably due to the high concentration of Cu and Zn in this soil. For rice, both Cu and Zn concentration as extracted by the three extracting solutions correlated with the concentration of all the fractions and with the total concentration.
Tipo:  Info:eu-repo/semantics/article
Idioma:  Inglês
Identificador:  http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-90162008000600015
Editor:  São Paulo - Escola Superior de Agricultura "Luiz de Queiroz"
Relação:  10.1590/S0103-90162008000600015
Formato:  text/html
Fonte:  Scientia Agricola v.65 n.6 2008
Direitos:  info:eu-repo/semantics/openAccess
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