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Whitby, Hannah; Planquette, Helene; Cassar, Nicolas; Bucciarelli, Eva; Osburn, Christopher L.; Janssen, David J.; Cullen, Jay T.; González, Aridane G.; Völker, Christoph; Sarthou, Geraldine. |
Primary production by phytoplankton represents a major pathway whereby atmospheric CO2 is sequestered in the ocean, but this requires iron, which is in scarce supply. As over 99% of iron is complexed to organic ligands, which increase iron solubility and microbial availability, understanding the processes governing ligand dynamics is of fundamental importance. Ligands within humic-like substances have long been considered important for iron complexation, but their role has never been explained in an oceanographically consistent manner. Here we show iron co-varying with electroactive humic substances at multiple open ocean sites, with the ratio of iron to humics increasing with depth. Our results agree with humic ligands composing a large fraction of the... |
Tipo: Text |
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Ano: 2020 |
URL: https://archimer.ifremer.fr/doc/00622/73388/72598.pdf |
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