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Pockmark formation and evolution in deep water Nigeria: Rapid hydrate growth versus slow hydrate dissolution ArchiMer
Sultan, Nabil; Bohrmann, G.; Ruffine, Livio; Pape, T.; Riboulot, Vincent; Colliat, J. -l.; De Prunele, Alexis; Dennielou, Bernard; Garziglia, Sebastien; Himmler, Tobias; Marsset, Tania; Peters, C. A.; Rabiu, A.; Wei, J..
In previous works, it has been suggested that dissolution of gas hydrate can be responsible for pockmark formation and evolution in deep water Nigeria. It was shown that those pockmarks which are at different stages of maturation are characterized by a common internal architecture associated to gas hydrate dynamics. New results obtained by drilling into gas hydrate-bearing sediments with the MeBo seafloor drill rig in concert with geotechnical in situ measurements and pore water analyses indicate that pockmark formation and evolution in the study area are mainly controlled by rapid hydrate growth opposed to slow hydrate dissolution. On one hand, positive temperature anomalies, free gas trapped in shallow microfractures near the seafloor and coexistence of...
Tipo: Text
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00188/29913/28373.pdf
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Phase Equilibria of the CH4-CO2 Binary and the CH4-CO2-H2O Ternary Mixtures in the Presence of a CO2-Rich Liquid Phase ArchiMer
Legoix, Ludovic; Ruffine, Livio; Donval, Jean-pierre; Haeckel, Matthias.
The knowledge of the phase behavior of carbon dioxide (CO2)-rich mixtures is a key factor to understand the chemistry and migration of natural volcanic CO2 seeps in the marine environment, as well as to develop engineering processes for CO2 sequestration coupled to methane (CH4) production from gas hydrate deposits. In both cases, it is important to gain insights into the interactions of the CO2-rich phase—liquid or gas—with the aqueous medium (H2O) in the pore space below the seafloor or in the ocean. Thus, the CH4-CO2 binary and CH4-CO2-H2O ternary mixtures were investigated at relevant pressure and temperature conditions. The solubility of CH4 in liquid CO2 (vapor-liquid equilibrium) was determined in laboratory experiments and then modelled with the...
Tipo: Text Palavras-chave: Gas hydrate; CH4; CO2-rich mixtures; Phase equilibria; Soave-Redlich-Kwong (SRK) cubic equation of state (EoS).
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00414/52538/53349.pdf
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Gas Hydrates 1: Fundamentals, Characterization and Modeling ArchiMer
Broseta, Daniel; Ruffine, Livio; Desmedt, Arnaud.
Gas hydrates, or clathrate hydrates, are crystalline solids resembling ice, in which small (guest) molecules, typically gases, are trapped inside cavities formed by hydrogen-bonded water (host) molecules. They form and remain stable under low temperatures – often well below ambient conditions – and high pressures ranging from a few bar to hundreds of bar, depending on the guest molecule. Their presence is ubiquitous on Earth, in deep-marine sediments and in permafrost regions, as well as in outer space, on planets or comets. In addition to water, they can be synthesized with organic species as host molecules, resulting in milder stability conditions: these are referred to as semi-clathrate hydrates. Clathrate and semi-clathrate hydrates are being...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00453/56506/58852.pdf
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Fluids and processes at the seismically active fault zone in the Sea of Marmara ArchiMer
Ruffine, Livio; Cagatay, M. Namik; Geli, Louis.
Tipo: Text
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00463/57473/59866.pdf
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Gas Hydrates 2 : Geoscience Issues and Potential Industrial Applications ArchiMer
Ruffine, Livio; Broseta, Daniel; Desmedt, Arnaud.
In recent years, interest for clathrate hydrates has increased, motivated both by their fascinating physiochemical and thermophysical properties and their industrial and practical promises in various areas of application. Following the 2017 publication of Volume 1, which focused on fundamental aspects, modeling and characterization methods, this volume gathers a series of contributions addressing the natural occurrence of clathrate hydrates in sediments on Earth, with implications for the methane cycle, geohazards and energy resources, and then a few promising industrial applications. This volume is intended for scientists, PhD students and engineers who wish to start working on clathrate hydrates and/or want to acquire general knowledge in this area. It...
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Ano: 2018 URL: http://archimer.ifremer.fr/doc/00453/56507/58855.pdf
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Geochemical Characteristics of Iron in Sediments from the Sea of Marmara ArchiMer
Yang, Hailin; Lu, Hailong; Ruffine, Livio.
Two ~1000 cm long sediment cores were recovered from the Sea of Marmara, one with the occurrence of gas hydrates in the Western High, and the other without hydrates in the Cinarcik Basin. Differences in mineralogical and chemical compositions have been identified between the two sediment cores. Based on the results of the mineralogical and geochemical analyses, the main sources of the sediments are quite similar for both investigated areas, but the authigenic components are different, particularly iron sulfides and carbonates. Authigenic Fe(II) carbonate are much higher in Core MRS-CS-05 in the Western High, while crystalline Fe(III) phases are more abundant in Core MRS-CS-16 in the Cinarcik Basin. Notably, the enrichments of greigite (Fe3S4), a metastable...
Tipo: Text Palavras-chave: Iron geochemistry; The Sea of Marmara; Sediment; Redox environment.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00423/53455/54347.pdf
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The Congolobe project, a multidisciplinary study of Congo deep-sea fan lobe complex: Overview of methods, strategies, observations and sampling ArchiMer
Rabouille, C.; Olu, Karine; Baudin, F.; Khripounoff, Alexis; Dennielou, Bernard; Arnaud-haond, Sophie; Babonneau, Nathalie; Bayle, Christophe; Beckler, J.; Bessette, Sandrine; Bombled, B.; Bourgeois, S.; Brandily, Christophe; Caprais, Jean-claude; Cathalot, Cecile; Charlier, K.; Corvaisier, R.; Croguennec, Chantal; Cruaud, Perrine; Decker, Carole; Droz, L.; Gayet, Nicolas; Godfroy, Anne; Hourdez, S.; Le Bruchec, J.; Saout, Johan; Le Saout, Marie-helene; Lesongeur, Francoise; Martinez, P.; Mejanelle, L.; Michalopoulos, P.; Mouchel, Olivier; Noel, Philippe; Pastor, Lucie; Picot, M.; Pignet, Patricia; Pozzato, L.; Pruski, A. M.; Rabiller, Manuella; Raimonet, M.; Ragueneau, O.; Reyss, J. L.; Rodier, Philippe; Ruesch, Blandine; Ruffine, Livio; Savignac, F.; Senyarich, C.; Schnyder, J.; Sen, Arunima; Stetten, E.; Sun, Ming Yi; Taillefert, M.; Teixeira, S.; Tisnerat-laborde, N.; Toffin, Laurent; Tourolle, Julie; Toussaint, F.; Vetion, G.; Jouanneau, J. M.; Bez, M..
The presently active region of the Congo deep-sea fan (around 330 000 km2), called the terminal lobes or lobe complex, covers an area of 2500 km2 at 4700–5100 m water depth and 750–800 km offshore. It is a unique sedimentary area in the world ocean fed by a submarine canyon and a channel-levee system which presently deliver large amounts of organic carbon originating from the Congo River by turbidity currents. This particularity is due to the deep incision of the shelf by the Congo canyon, up to 30 km into the estuary, which funnels the Congo River sediments into the deep-sea. The connection between the river and the canyon is unique for major world rivers. In 2011, two cruises (WACS leg 2 and Congolobe) were conducted to simultaneously investigate the...
Tipo: Text Palavras-chave: Chemosynthetic habitats; Congo deep-sea fan; Fine sediment; Sedimentation rate; Seafloor morphology; Turbidite; Vesicomyidae.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00335/44580/44298.pdf
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Seep communities from two mud volcanoes in the deep eastern Mediterranean Sea: faunal composition, spatial patterns and environmental control ArchiMer
Ritt, Benedicte; Desbruyeres, Daniel; Caprais, Jean-claude; Gauthier, Olivier; Ruffine, Livio; Buscail, Roselyne; Olu-le Roy, Karine; Sarrazin, Jozee.
The Mediterranean Sea constitutes a unique environment to study cold-seep ecosystems due to the presence of different geodynamic settings, from an active margin along the Mediterranean Ridge (MR) to a passive margin in the Nile Deep-Sea Fan (NDSF). We attempted to identify the structure of benthic communities associated with the Napoli and Amsterdam mud volcanoes (MVs) located on the MR and to establish the links between faunal distribution and environmental conditions at different spatial scales. Comparison between the 2 MVs revealed that the faunal distribution seemed to be mainly controlled by the characteristics of the microhabitats. On both geological structures, the variability between the different microhabitats was higher than the variability...
Tipo: Text Palavras-chave: Mediterranean Ridge; Cold seeps; Benthic fauna; Environmental conditions; Diversity indices; Microhabitats.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00106/21725/19292.pdf
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Free gas and gas hydrates from the Sea of Marmara, Turkey Chemical and structural characterization ArchiMer
Bourry, Christophe; Chazallon, Bertrand; Charlou, Jean-luc; Donval, Jean-pierre; Ruffine, Livio; Henry, Pierre; Geli, Louis; Cagatay, M. Namik; Inan, Sedat; Moreau, Myriam.
Gas hydrates and gas bubbles were collected during the MARNAUT cruise (May-June 2007) in the Sea of Marmara along the North Anatolian Fault system, Turkey. Gas hydrates were sampled in the western part of the Sea of Marmara (on the Western High), and three gas-bubble samples were recovered on the Western High, the Central High (center part of the Sea of Marmara) and in the Cinarcik Basin (eastern part of the Sea of Marmara). Methane is the major component of hydrates (66.1%), but heavier gases such as C-2, C-3, and i-C-4 are also present in relatively high concentration. The methane contained within gas hydrate is clearly thermogenic as evidenced by a low C-1/C-2 + C-3 ratio of 3.3, and carbon and hydrogen isotopic data (delta C-13(CH4) of -44.1 parts per...
Tipo: Text Palavras-chave: Isotopes; Thermogenic gas; Gas bubbles; Gas hydrate; Sea of Marmara.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6844.pdf
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Marine Transform Faults and Fracture Zones: A Joint Perspective Integrating Seismicity, Fluid Flow and Life ArchiMer
Hensen, Christian; Duarte, Joao C.; Vannucchi, Paola; Mazzini, Adriano; Lever, Mark A.; Terrinha, Pedro; Géli, Louis; Henry, Pierre; Villinger, Heinrich; Morgan, Jason; Schmidt, Mark; Gutscher, Marc-andre; Bartolome, Rafael; Tomonaga, Yama; Polonia, Alina; Gràcia, Eulàlia; Tinivella, Umberta; Lupi, Matteo; Çağatay, M. Namık; Elvert, Marcus; Sakellariou, Dimitris; Matias, Luis; Kipfer, Rolf; Karageorgis, Aristomenis P.; Ruffine, Livio; Liebetrau, Volker; Pierre, Catherine; Schmidt, Christopher; Batista, Luis; Gasperini, Luca; Burwicz, Ewa; Neres, Marta; Nuzzo, Marianne.
Marine transform faults and associated fracture zones (MTFFZs) cover vast stretches of the ocean floor, where they play a key role in plate tectonics, accommodating the lateral movement of tectonic plates and allowing connections between ridges and trenches. Together with the continental counterparts of MTFFZs, these structures also pose a risk to human societies as they can generate high magnitude earthquakes and trigger tsunamis. Historical examples are the Sumatra-Wharton Basin Earthquake in 2012 (M8.6) and the Atlantic Gloria Fault Earthquake in 1941 (M8.4). Earthquakes at MTFFZs furthermore open and sustain pathways for fluid flow triggering reactions with the host rocks that may permanently change the rheological properties of the oceanic...
Tipo: Text Palavras-chave: Transform faults; Fractures zones; Coupling of seismicity and fluid flow; Microbial life; Heat flow; Fluid geochemistry; Seafloor observation systems; Seismic precursors.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00489/60085/63422.pdf
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Pore water geochemistry at two seismogenic areas in the Sea of Marmara ArchiMer
Ruffine, Livio; Germain, Yoan; Polonia, Alina; De Prunele, Alexis; Croguennec, Claire; Donval, Jean-pierre; Pitel-roudaut, Mathilde; Ponzevera, Emmanuel; Caprais, Jean-claude; Brandily, Christophe; Grall, Celine; Bollinger, Claire; Geli, Louis; Gasperini, Luca.
Within the Sea of Marmara, the highly active North Anatolian Fault (NAF) is responsible for major earthquakes (Mw>=7), and acts as a pathway for fluid migration from deep sources to the seafloor. This work reports on pore water geochemistry from three sediment cores collected in the Gulfs of Izmit and Gemlik, along the Northern and the Middle strands of the NAF, respectively. The resulting data set shows that anaerobic oxidation of methane (AOM) is the major process responsible for sulfate depletion in the shallow sediment. In the Gulf of Gemlik, depth concentration profiles of both sulfate and alkalinity exhibit a kink-type profile. The Sulfate Methane Transition Zone (SMTZ) is located at moderate depth in the area. In the Gulf of Izmit, the low...
Tipo: Text Palavras-chave: Anaerobic oxidation of methane; North Anatolian Fault; Pore water geochemistry; Sea of Marmara; Seismic activity.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00272/38339/36570.pdf
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Freshwater lake to salt-water sea causing widespread hydrate dissociation in the Black Sea ArchiMer
Riboulot, Vincent; Ker, Stephan; Sultan, Nabil; Thomas, Yannick; Marsset, Bruno; Scalabrin, Carla; Ruffine, Livio; Boulart, Cedric; Ion, Gabriel.
Gas hydrates, a solid established by water and gas molecules, are widespread along the continental margins of the world. Their dynamics have mainly been regarded through the lens of temperature-pressure conditions. A fluctuation in one of these parameters may cause destabilization of gas hydrate-bearing sediments below the seafloor with implications in ocean acidification and eventually in global warming. Here we show throughout an example of the Black Sea, the world’s most isolated sea, evidence that extensive gas hydrate dissociation may occur in the future due to recent salinity changes of the sea water. Recent and forthcoming salt diffusion within the sediment will destabilize gas hydrates by reducing the extension and thickness of their thermodynamic...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00418/52981/53916.pdf
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Geological and biological diversity of seeps in the Sea of Marmara ArchiMer
Ondreas, Helene; Olu, Karine; Dupre, Stephanie; Scalabrin, Carla; Alix, Anne-sophie; Garrocq, Clément; Ruffine, Livio.
The Sea of Marmara hosts part of the North Anatolian Fault as an active submarine strike-slip fault. This area has suffered numerous earthquakes and presents a major seismic risk. Although the Sea of Marmara has been studied for many years, the link between geological morphostructures, the nature of fluids and biological communities is still rarely described. During the Marsite cruise (November 2014), dives with Remotely Operated Vehicle (ROV) VICTOR 6000 focused on detailed seafloor explorations of four different areas: the Central and Western highs and the Tekirdağ and Çinarcik basins. Based on 130 h of in situ videos, high-resolution seafloor mapping of seeps was conducted, emphasizing their significant geological and biological diversity from one...
Tipo: Text Palavras-chave: Sea of Marmara; Cold seeps; Fluids; Seismogenic faults; Chemosynthetic fauna; Methane.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00624/73623/73040.pdf
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Focused hydrocarbon-migration in shallow sediments of a pockmark cluster in the Niger Delta (Off Nigeria) ArchiMer
De Prunele, Alexis; Ruffine, Livio; Riboulot, Vincent; Peters, Carl A.; Croguennec, Claire; Guyader, Vivien; Pape, Thomas; Bollinger, Claire; Bayon, Germain; Caprais, Jean-claude; Germain, Yoan; Donval, Jean-pierre; Marsset, Tania; Bohrmann, Gerhard; Geli, Louis; Rabiu, Abdulkarim; Lescanne, Marc; Cauquil, Eric; Sultan, Nabil.
The Niger Delta is one of the largest hydrocarbon basin offshore Africa and it is well known for the presence of active pockmarks on the seabed. During the Guineco-MeBo cruise in 2011, long cores were taken from a pockmark cluster in order to investigate the state of its current activity. Gas hydrates, oil and pore-water were sampled for geochemical studies. The resulting dataset combined with seismic data reveal that shallow hydrocarbon migration in the upper sedimentary section was focused exclusively within the pockmarks. There is a clear tendency for gas migration within the hydrate-bearing pockmarks, and oil migration within the carbonate-rich one. This trend is interpreted as a consequence of hydrate dissolution followed by carbonate precipitation...
Tipo: Text Palavras-chave: Anaerobic oxidation of methane; Cluster of pockmarks; Fluid flow; Gas hydrates; Pore-water profiles; Transient state.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00365/47647/47676.pdf
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Investigation on the geochemical dynamics of a hydrate-bearing pockmark in the Niger Delta ArchiMer
Ruffine, Livio; Caprais, Jean-claude; Bayon, Germain; Riboulot, Vincent; Donval, Jean-pierre; Etoubleau, Joel; Birot, Dominique; Pignet, Patricia; Rongemaille, Emmanuelle; Chazallon, Bertrand; Grimaud, Sylvie; Adamy, Jerome; Charlou, Jean-luc; Voisset, Michel.
A joint industrial project with IFREMER and Total provides insights into the tectonic setting and the geochemistry of a large active pockmark offshore W-Africa in the Niger Delta. The study combines both geophysical (seismic) and geochemical data to infer the dynamics of a 300 m wide pockmark located at 667 m water depth. Two Calypso cores, one at the centre and one outside the pockmark, along with three box-cores, two inside the pockmark and one outside, were collected to study the geochemistry of gas hydrates, carbonates and pore waters. Two seismic lines, a 3D high resolution random line and a 2D high resolution seismic line, provide a good description of the plumbing of the system. The integrated results depict a very active pockmark characterized by...
Tipo: Text Palavras-chave: Active pockmark; Anaerobic oxidation of methane; Gas hydrates; Carbonates; Seismic surveys; Fault system; U/Th dating.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00139/24981/23102.pdf
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Gas and seismicity within the Istanbul seismic gap ArchiMer
Geli, Louis; Henry, P.; Grall, Celine; Tary, Jean-baptiste; Lomax, A.; Batsi, Evangelia; Riboulot, Vincent; Cros, Estelle; Gurbuz, C.; Isik, S. E.; Sengor, A. M. C.; Le Pichon, X.; Ruffine, Livio; Dupre, Stephanie; Thomas, Yannick; Kalafat, D.; Bayrakci, G.; Coutellier, Q.; Regnier, Thibaut; Westbrook, Graham; Saritas, H.; Cifci, G.; Cagatay, M. N.; Ozeren, M. S.; Gorur, N.; Tryon, M.; Bohnhoff, M.; Gasperini, L.; Klingelhoefer, Frauke; Scalabrin, Carla; Augustin, Jean-marie; Embriaco, D.; Marinaro, G.; Frugoni, F.; Monna, S.; Etiope, G.; Favali, P.; Becel, A..
Understanding micro-seismicity is a critical question for earthquake hazard assessment. Since the devastating earthquakes of Izmit and Duzce in 1999, the seismicity along the submerged section of North Anatolian Fault within the Sea of Marmara (comprising the “Istanbul seismic gap”) has been extensively studied in order to infer its mechanical behaviour (creeping vs locked). So far, the seismicity has been interpreted only in terms of being tectonic-driven, although the Main Marmara Fault (MMF) is known to strike across multiple hydrocarbon gas sources. Here, we show that a large number of the aftershocks that followed the M 5.1 earthquake of July, 25th 2011 in the western Sea of Marmara, occurred within a zone of gas overpressuring in the 1.5–5 km depth...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00439/55072/56500.pdf
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Corrigendum to “Multiple gas reservoirs are responsible for the gas emissions along the Marmara fault network” ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Çağatay, M. Namık; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Géli, Louis.
The authors regret a mistake on the value of δ13C of methane for one of the investigated gas samples. This concerns sample MRS-DV3-PE03, taken as end member and for which the correct methane δ13C value is -41.9‰ and not -34‰. The sample was collected at in situ pressure (~100 bars) from a CO2-rich seep, in a liquid state. The mistake likely results from a partial extraction (i.e. done by expansion of the sampler volume to allow vaporization) of the pressurized sample for subsampling. Additional analyses have been carried out from fully vaporized samples. This error has resulted in updating the geochemical diagrams used for the discussion, and revising both the gas origin for sample MRS-DV3-PE03 and the section entitled “Delineation of sources, reservoirs...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00471/58253/61076.pdf
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Seafloor authigenic carbonate crusts along the submerged part of the North Anatolian Fault in the Sea of Marmara: Mineralogy, geochemistry, textures and genesis ArchiMer
Cagatay, M. Namik; Yildiz, Guliz; Bayon, Germain; Ruffine, Livio; Henry, Pierre.
Extensive seafloor authigenic carbonate crusts occur as pavements, mounds and chimneys along the North Anatolian Fault System (NAFS) in the Sea of Marmara. They are often covered or surrounded by patches of black Fe-sulphide-rich sediments, and associated with hydrocarbon-rich gas and brackish-water emissions in the 1250 m-deep deep basins and with deep saline formation waters and hydrocarbons emissions from mud volcanoes and anticlines on the 350 to 650 m-deep compressional highs. The authigenic carbonate crusts are commonly porous with sinter-like, botryoidal and sugary- granular textures, and constructed from cementation of framework elements consisting mainly of bivalve shells and shell fragments, serpulid tubes, fibrous microbial organic matter and...
Tipo: Text Palavras-chave: Authigenic carbonates; Mineral and isotopic compositions; Textures and structures; U-Th ages; North Anatolian Fault; Sea of Marmara.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00399/51047/51819.pdf
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New insights into the transport processes controlling the sulfate-methane-transition-zone near methane vents ArchiMer
Sultan, Nabil; Garziglia, Sebastien; Ruffine, Livio.
Over the past years, several studies have raised concerns about the possible interactions between methane hydrate decomposition and external change. To carry out such an investigation, it is essential to characterize the baseline dynamics of gas hydrate systems related to natural geological and sedimentary processes. This is usually treated through the analysis of sulfate-reduction coupled to anaerobic oxidation of methane (AOM). Here, we model sulfate reduction coupled with AOM as a two-dimensional (2D) problem including, advective and diffusive transport. This is applied to a case study from a deep-water site off Nigeria’s coast where lateral methane advection through turbidite layers was suspected. We show by analyzing the acquired data in combination...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00339/45068/44493.pdf
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U-Th isotope constraints on gas hydrate and pockmark dynamics at the Niger delta margin ArchiMer
Bayon, Germain; Henderson, Gideon M.; Etoubleau, Joel; Caprais, Jean-claude; Ruffine, Livio; Marsset, Tania; Dennielou, Bernard; Cauquil, Eric; Voisset, Michel; Sultan, Nabil.
The application of uranium-thorium dating methods to authigenic carbonates provides unique constraints on the temporal evolution of methane seeps at ocean margins. In this study, we report U-Th isotope measurements for carbonate breccias collected from within a hydrate-bearing pockmark located at the Niger Delta margin. These concretions were extracted from a carbonate-rich layer in the upper two meters of a sediment core (N2-KS-44; ~ 1200 m water depth), well above the present-day sulphate-methane transition zone (about 3 m depth) and the presence of gas hydrates in the sediment. The stratigraphy of core N2-KS-44 was established by tuning its downcore Al/Ti profile to a well-dated nearby reference core, and carbonate 230Th/U ages were calculated using...
Tipo: Text Palavras-chave: Gas hydrates; Pockmarks; U-series; Authigenic carbonates; Niger delta.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00286/39708/41518.pdf
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