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Registros recuperados: 39
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Characterisation of dissolved organic compounds in hydrothermal fluids by stir bar sorptive extraction - gas chomatography - mass spectrometry. Case study: the Rainbow field (36 degrees N, Mid-Atlantic Ridge) ArchiMer
Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Holm, Nils G..
The analysis of the dissolved organic fraction of hydrothermal fluids has been considered a real challenge due to sampling difficulties, complexity of the matrix, numerous interferences and the assumed ppb concentration levels. The present study shows, in a qualitative approach, that Stir Bar Sorptive Extraction (SBSE) followed by Thermal Desorption - Gas Chromatography - Mass Spectrometry (TD-GC-MS) is suitable for extraction of small sample volumes and detection of a wide range of volatile and semivolatile organic compounds dissolved in hydrothermal fluids. In a case study, the technique was successfully applied to fluids from the Rainbow ultramafic-hosted hydrothermal field located at 36 degrees 14'N on the Mid-Atlantic Ridge (MAR). We show that...
Tipo: Text Palavras-chave: Sample preparation; Extraction; Organic compounds; Hydrothermal fluids; Ultramafic rocks.
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00114/22514/20196.pdf
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Organic, Gas, and Element Geochemistry of Hydrothermal Fluids of the Newly Discovered Extensive Hydrothermal Area in the Wallis and Futuna Region (SW Pacific) ArchiMer
Konn, Cecile; Donval, Jean-pierre; Guyader, Vivien; Roussel, Erwan; Fourre, E.; Jean-baptiste, P.; Pelleter, Ewan; Charlou, Jean-luc; Fouquet, Yves.
Two newly discovered hydrothermal vent fields of the Wallis and Futuna region, Kulo Lasi and Fatu Kapa, were sampled for fluid geochemistry. A great geochemical diversity was observed and assigned to the diversity of lithologies as well as the occurrence of various processes. Kulo Lasi fluids likely formed by interaction with fresh volcanic rocks, phase separation, and mixing with magmatic fluid. Conversely, the geochemistry of the Fatu Kapa fluids would be mostly due to water/felsic lavas reactions. In terms of organic geochemistry, fluids from both fields were found to be enriched in formate, acetate, and semivolatile organic compounds (SVOCs): n-alkanes, n-fatty acids, and polyaromatic hydrocarbons (PAHs). Concentrations of SVOCs reached a few ppb at...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00431/54245/55571.pdf
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Extensive hydrothermal activity revealed by multi-tracer survey in the Wallis and Futuna region (SW Pacific) ArchiMer
Konn, Cecile; Fourre, E.; Jean-baptiste, P.; Donval, Jean-pierre; Guyader, Vivien; Birot, Dominique; Alix, Anne-sophie; Gaillot, Arnaud; Perez, Florian; Dapoigny, A.; Pelleter, Ewan; Resing, J. A.; Charlou, Jean-luc; Fouquet, Yves.
The study area is close to the Wallis and Futuna Islands in the French EEZ. It exists on the western boundary of the fastest tectonic area in the world at the junction of the Lau and North-Fiji basins. At this place, the unstable back-arc accommodates the plate motion in three ways: (i) the north Fiji transform fault, (ii) numerous unstable spreading ridges, and (iii) large areas of recent volcanic activity. This instability creates bountiful opportunity for hydrothermal discharge to occur. Based on geochemical (CH4, TDM, 3He) and geophysical (nephelometry) tracer surveys: (1) no hydrothermal activity could be found on the Futuna Spreading Center (FSC) which sets the western limit of hydrothermal activity; (2) four distinct hydrothermal active areas were...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00347/45848/45505.pdf
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Hydrothermal methane venting between 12°N and 26°N along the Mid-Atlantic Ridge ArchiMer
Charlou, Jean-luc; Donval, Jean-pierre.
Hydrographic surveys along the Mid-Atlantic Ridge (MAR) between 12°N and 26°N, carried out from 1984 to 1990, show a variable pattern of CH4-rich water column plumes. The vertical distribution of CH4 at stations located every 20–40 km is presented along this 1200-km-long section of the MAR. CH4 venting is clearly demonstrated. CH4-enriched fluids rise from vents as plumes; spreading is confined to the axial valley due to the topography of the MAR. CH4 contents from 45 nmol to 675 nmol/kg are measured in the buoyant plumes above the two active hydrothermal sites (MARK 23°N; TAG 26°N) known at present, whereas CH4 anomalies up to 3.6 nmol/kg are typically observed in plumes emitted either on the inner floor, on the walls, and/or at the top of the rift...
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Ano: 1993 URL: http://archimer.ifremer.fr/doc/00070/18103/15651.pdf
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Geochemical Dynamics of the Natural-Gas Hydrate System in the Sea of Marmara, Offshore Turkey ArchiMer
Ruffine, Livio; Fandino Torres, Olivia; Etoubleau, Joel; Cheron, Sandrine; Donval, Jean-pierre; Germain, Yoan; Ponzevera, Emmanuel; Guyader, Vivien; Dennielou, Bernard; Etiope, Giuseppe; Gasperini, Luca; Bortoluzzi, Giovanni; Henry, Pierre; Grall, Celine; Cagatay, M. Namik; Charlou, Jean-luc; Geli, Louis.
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Ano: 2012 URL: http://archimer.ifremer.fr/doc/00139/24982/23065.pdf
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FLORES diving cruise with Nautile near the Azores - First dives on the Rainbow field: hydrothermal seawater/mantle interaction ArchiMer
Fouquet, Yves; Barriga, F; Charlou, Jean-luc; Elderfield, H; German, C.r; Ondreas, Helene; Parson, L; Radford-knoery, Joel; Relvas, J; Ribeiro, A; Schultz, A; Apprioual, R; Cambon, P; Costa, I; Donval, Jean-pierre; Douville, E; Landure, Jy; Normand, A; Pelle, H; Ponsevera, E.
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Ano: 1998 URL: http://archimer.ifremer.fr/doc/00070/18133/15681.pdf
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Extensive magmatic and hydrothermal activity in Manus Basin ArchiMer
Auzende, Jean-marie; Ishibashi, J; Beaudouin, Y; Charlou, Jean-luc; Delteil, J; Donval, Jean-pierre; Fouquet, Yves; Gouillou, Jp; Ildefonse, B; Kimura, H; Nishio, Y; Knoery, Joel; Ruollan, E.
In 1995, a joint French‐Japanese cruise (ManusFlux) explored the Manus Spreading Center and some sites of the South Eastern Rift in the Manus Basin off the coast of Papua New Guinea (Figure 1) with the Japanese submersible [Auzende et al., 1996; Gamo et al., 1997]. In the framework of this joint project, called New STARMER, the French and Japanese teams completed the Manaute cruise with the R/V LAtalante and the Ifremer submersible Nautile in April and May 2000. The Manaute cruise explored and sampled volcanic and hydrothermal sites in the eastern part of Manus Basin and on the spreading axis of the Western Ridge (WR). The eastern part of the Manus Basin (Figure 2) was interpreted as a stretched‐back arc basin crust showing alternatively elongated ridges...
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Ano: 2000 URL: http://archimer.ifremer.fr/doc/00069/18055/15597.pdf
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Helium isotopic composition of hydrothermal fluids from the Manus back-arc Basin, Papua New Guinea ArchiMer
Fourre, E; Jean Baptiste, P; Charlou, Jean-luc; Donval, Jean-pierre; Ishibashi, J.
We present isotopic analysis of helium in hydrothermal fluids from the Manus back-arc basin, collected during the French-Japanese Manusflux and Manaute cruises in 1995 and 2000, respectively. The helium isotope composition of the fluids is comparable to that measured elsewhere in similar subduction environments, with He-3/He-4 values (7.4 to 7.9 R-a) slightly lower than typical MORB values, except on the Manus Spreading Center (MSC) where higher values (12 +/- 0.1 R-a) are observed. The causal link between the narrow spatial extent of the He-3/He-4 anomaly at the MSC and a He-3-rich deep mantle component remains elusive, based on available geophysical data. Thus, the Manus Spreading Center results may be an interesting example of small scale upper-mantle...
Tipo: Text Palavras-chave: Western Pacific; Manus Basin; Back arc basins; Hydrothermal fluids; Helium isotopes.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/2006/publication-4203.pdf
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Caminicella sporogenes gen. nov., sp nov., a novel thermophilic spore-forming bacterium isolated from an East-Pacific Rise hydrothermal vent ArchiMer
Alain, Karine; Pignet, Patricia; Zbinden, M; Quillevere, M; Duchiron, F; Donval, Jean-pierre; Lesongeur, Francoise; Raguenes, Gerard; Crassous, Philippe; Querellou, Joel; Cambon-bonavita, Marie-anne.
A novel thermophilic, anaerobic, strictly chemoorganoheterotrophic bacterium, designated as AM1114(T), was isolated from a deep-sea hydrothermal vent sample from the East-Pacific Rise (EPR 13degrees N). The cells were long (3-10 mum) rods, motile with peritrichous flagella, and exhibited a Gram-negative cell wall ultrastructure. In the late stationary phase of growth, cells formed an ovoid, refractile, terminal endospore. They grew at 45-65 degreesC inclusive (optimum 55-60 degreesC; doubling time approx. 45 min), at pH 4.5-8.0 inclusive (optimum pH 7.5-8.0) and at sea salt concentrations of 20-60 g l(-1) inclusive (optimum 25-30 g l(-1)). Strain AM1114(T) was an obligately heterotrophic bacterium able to ferment a mixture of 20 amino acids, complex...
Tipo: Text Palavras-chave: Caminicella sporogenes; Clostridiales; Thermophile; Deep sea hydrothermal vent.
Ano: 2002 URL: http://archimer.ifremer.fr/doc/2002/publication-528.pdf
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Contrasted hydrothermal activity along the South-East Indian Ridge (130°E-140°E): From crustal to ultramafic circulation ArchiMer
Boulart, Cedric; Briais, Anne; Chavagnac, Valerie; Revillon, Sidonie; Ceuleneer, Georges; Donval, Jean-pierre; Guyader, Vivien; Barrere, Fabienne; Ferreira, Nicolas; Hanan, Barry; Hemond, Christophe; Macleod, Sarah; Maia, Marcia; Maillard, Agnes; Merkuryev, Sergey; Park, Sung-hyun; Ruellan, Etienne; Schohn, Alexandre; Watson, Sally; Yang, Yun-seok.
Using a combined approach of seafloor mapping, MAPR and CTD survey, we report evidence for active hydrothermal venting along the 130°-140°E section of the poorly-known South-East Indian Ridge (SEIR) from the Australia-Antarctic Discordance (AAD) to the George V Fracture Zone (FZ). Along the latter, we report Eh and CH4 anomalies in the water column above a serpentinite massif, which unambiguously testify for ultramafic-related fluid flow. This is the first time that such circulation is observed on an intermediate-spreading ridge. The ridge axis itself is characterized by numerous off-axis volcanoes, suggesting a high magma supply. The water column survey indicates the presence of at least ten distinct hydrothermal plumes along the axis. The CH4:Mn ratios...
Tipo: Text Palavras-chave: Hydrothermal plumes; Mid-ocean ridges; South-East Indian Ridge.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00387/49821/50400.pdf
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Gas Seepage along the Edge of the Aquitaine Shelf (France): Origin and Local Fluxes ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Bignon, Laurent; Birot, Dominique; Battani, Anne; Bayon, Germain; Caprais, Jean-claude; Lanteri, Nadine; Levache, Denis; Dupre, Stephanie.
During the scientific expedition GAZCOGNE2 at the Bay of Biscay nine gas seeps were sampled for the first time and their flux was measured using an in situ pressure-preservation sampler (PEGAZ, ©IFREMER). Overall, three sites were investigated to determine the nature and the origin of the gases bubbling at the seafloor and forming acoustic plumes into the water column, as this was the question raised fromthe first geologic study of the area.This has guided our study and accordingly corresponds to themain purpose of the present article.Thus, themolecular and isotopic (𝛿D and 𝛿13C) analyses revealed that the gas seeps were primarily composed of methane. Both methane and ethane are of microbial origin, and the former has been generated by...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00394/50579/51270.pdf
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Experimental study of gas hydrate formation and destabilisation using a novel high-pressure apparatus ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Charlou, Jean-luc; Cremiere, Antoine; Zehnder, B. H..
A novel variable-volume type high-pressure apparatus has been designed, constructed and used for gas hydrate investigations. The apparatus has an operating temperature ranging from 253 K to 473 K and pressure ranging from 0.1 MPa to 60 MPa. Its central component consists of a viewing windows cell to which several sensors or analytical instruments can be connected. At its present configuration, a Raman spectrometer and a gas chromatograph are connected for the study of the liquid (or solid) and the gas phases respectively. The apparatus was used for the study of two different systems. The first system was composed of carbon dioxide (CO2) and water for which the hydrate formation and dissolution has been investigated by injecting water into liquid CO2. The...
Tipo: Text Palavras-chave: Gas hydrates; Thermogenic; Carbon dioxide; Formation; Destabilisation; Novel apparatus; Raman spectroscopy; Chromatography.
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00006/11759/8472.pdf
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Multiple gas reservoirs are responsible for the gas emissions along the Marmara fault network ArchiMer
Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Cagatay, M. Namik; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Geli, Louis.
On continental margins, upward migration of fluids from various sources and various subsurface accumulations, through the sedimentary column to the seafloor, leads to the development of cold seeps where chemical compounds are discharged into the water column. MarsiteCruise was undertaken in November 2014 to investigate the dynamics of cold seeps characterized by vigorous gas emissions in the Sea of Marmara (SoM). A previous paper published by Bourry et al. (2009) presented the gas geochemistry of three seeps sampled along three different segments in the SoM. Their findings showed that the seeps were sourced by three different reservoirs. In this paper, seventeen seeps were investigated to determine the gas sources, unravel reservoir contributions, and...
Tipo: Text Palavras-chave: Abiotic CO2-source; Gas bubbles; Molecular and isotopic compositions; Primary and secondary methanogenesis; Sea of Marmara; Seeps; Thermogenic gases.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00411/52203/52926.pdf
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Analysis of hydrogen and methane in seawater by “Headspace” method: Determination at trace level with an automatic headspace sampler ArchiMer
Donval, Jean-pierre; Guyader, Vivien.
“Headspace” technique is one of the methods for the onboard measurement of hydrogen (H2) and methane (CH4) in deep seawater. Based on the principle of an automatic headspace commercial sampler, a specific device has been developed to automatically inject gas samples from 300 ml syringes (gas phase in equilibrium with seawater). As valves, micro pump, oven and detector are independent, a gas chromatograph is not necessary allowing a reduction of the weight and dimensions of the analytical system. The different steps from seawater sampling to gas injection are described. Accuracy of the method is checked by a comparison with the “purge and trap” technique. The detection limit is estimated to 0.3 nM for hydrogen and 0.1 nM for methane which is close to the...
Tipo: Text Palavras-chave: Gas; Seawater; Headspace method.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00354/46523/46287.pdf
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Hydrocarbons and oxidized organic compounds in hydrothermal fluids from Rainbow and Lost City ultramafic-hosted vents ArchiMer
Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Holm, N. G.; Dehairs, F.; Bouillon, S..
The first building blocks of life could be produced in ultramafic-hosted hydrothermal systems considering the large amounts of hydrogen and methane generated by serpentinisation and Fischer-Tropsch-Type synthesis, respectively, in those systems. The purpose of this study was to detect and characterise organic molecules in hydrothermal fluids from ultramafic-hosted hydrothermal systems in the Mid-Atlantic Ridge (MAR) region. During the EXOMAR cruise 2005, fluids from the Rainbow (36°14'N) and the Lost City (30°N) hydrothermal fields were collected and treated by Stir Bar Sorptive Extraction (SBSE) and Solid Phase Extraction (SPE). The extracts were analysed by Thermal Desorption-Gas Chromatography-Mass Spectrometry (TD-GC-MS) and GC-MS, respectively....
Tipo: Text Palavras-chave: Serpentinisation; Organic; Ultramafic; Hydrothermal; Origin of life.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/00067/17828/15576.pdf
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Multidisciplinary investigation on cold seeps with vigorous gas emissions in the Sea of Marmara (MarsiteCruise): Strategy for site detection and sampling and first scientific outcome ArchiMer
Ruffine, Livio; Ondreas, Helene; Blanc-valleron, Marie-madeleine; Teichert, Barbara M. A.; Scalabrin, Carla; Rinnert, Emmanuel; Birot, Dominique; Croguennec, Claire; Ponzevera, Emmanuel; Pierre, Catherine; Donval, Jean-pierre; Alix, Anne-sophie; Germain, Yoan; Bignon, Laurent; Etoubleau, Joel; Caprais, Jean-claude; Knoery, Joel; Lesongeur, Francoise; Thomas, Bastien; Roubi, Angelique; Legoix, Ludovic Nicolas; Burnard, Pete; Chevalier, Nicolas; Lu, Hailong; Dupre, Stephanie; Fontanier, Christophe; Dissard, Delphine; Olgun, Nazli; Yang, Hailin; Strauss, Harald; Ozaksoy, Volkan; Perchoc, Jonathan; Podeur, Christian; Tarditi, Corinne; Ozbeki, Eyyup; Guyader, Vivien; Marty, Bernard; Madre, David G; Pitel-roudaut, Mathilde; Grall, Celine; Embriaco, Davide; Polonia, Mina; Gasperini, Lucas; Cagatay, M. Namik; Henry, Pierre; Geli, Louis.
MarsiteCruise was undertaken in October/November 2014 in the Sea of Marmara to gain detailed insight into the fate of fluids migrating within the sedimentary column and partially released into the water column. The overall objective of the project was to achieve a more global understanding of cold-seep dynamics in the context of a major active strike-slip fault. Five remotely operated vehicle (ROV) dives were performed at selected areas along the North Anatolian Fault and inherited faults. To efficiently detect, select and sample the gas seeps, we applied an original procedure. It combines sequentially (1) the acquisition of ship-borne multibeam acoustic data from the water column prior to each dive to detect gas emission sites and to design the tracks of...
Tipo: Text Palavras-chave: Acoustic survey; Authigenic carbonates; Biogeochemistry; Chemical analyses; Cold seeps; Dissolved major elements; Fluid seepage; Geology; In situ Raman analysis; Methane; ROV dives.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00433/54434/55783.pdf
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Volcanic and hydrothermal processes in submarine calderas: the Kulo Lasi example (SW Pacific) ArchiMer
Fouquet, Yves; Pelleter, Ewan; Konn, Cecile; Chazot, Gilles; Dupre, Stephanie; Alix, Anne-sophie; Cheron, Sandrine; Donval, Jean-pierre; Guyader, Vivien; Etoubleau, Joel; Charlou, Jean-luc; Labanieh, Shasa; Scalabrin, Carla.
The study area is located at the transition between the northern end of the Tonga Trench and the North Fiji fracture zone, where tectonic movements are reputed to be the fastest in the world. To the southeast of Futuna Island, a broad area of volcanism occurs within a region characterized by a change in the tectonic fabric between a NE-SW oriented volcanic graben and the N-S oriented Alofi ridge. In 2010, the active volcano Kulo Lasi, which represents the most recent volcanic episode in the Futuna area, was discovered in the center of this extensive volcanic zone. Kulo Lasi is a 20 km diameter shield volcano that rises 400 m above the seafloor. It is composed of basaltic to trachy-andesitic lava with no obvious geochemical affinity with the Tonga...
Tipo: Text Palavras-chave: Subaqueous volcanism; Hydrothermal activity; Kulo Lasi caldera; Sulfides; SW Pacific.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00445/55633/57279.pdf
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Gaining insight into Clipperton's lagoon hydrology using tritium ArchiMer
Jean-baptiste, Philippe; Fourre, Elise; Charlou, Jean-luc; Donval, Jean-pierre; Correge, Thierry.
Historical descriptions of the Clipperton lagoon appear to converge on the fact that it became isolated from the surrounding ocean around 1858. Since then, because of the high precipitation rate which largely exceeds evaporation in this region of the eastern tropical Pacific, a brackish lens has formed on top of the saline oceanic waters. In 1980, literature data show that the thickness of this water body was reaching 14 m. During the 2005 Etienne's Clipperton expedition, we collected lagoon water on two vertical profiles. Salinity, delta O-18 and tritium analyses were performed on these samples with the objective of gaining further insight into the lagoon hydrology and age of the deep waters. The upper 15 m were characterized by low salinities (5.4 +/-...
Tipo: Text Palavras-chave: Oxygen isotopes; Tritium; Enclosed lagoon hydrology; Clipperton atoll.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6457.pdf
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Evidence for intense REE scavenging at cold seeps from the Niger Delta margin ArchiMer
Bayon, Germain; Birot, Dominique; Ruffine, Livio; Caprais, Jean-claude; Ponzevera, Emmanuel; Bollinger, C.; Donval, Jean-pierre; Charlou, Jean-luc; Voisset, Michel; Grimaud, S..
For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable...
Tipo: Text Palavras-chave: Rare earth elements; Neodymium isotopes; Seawater; Cold seeps; Fe-Mn oxyhydroxides; Benthic fluxes.
Ano: 2011 URL: http://archimer.ifremer.fr/doc/00066/17754/15571.pdf
Registros recuperados: 39
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