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| Registros recuperados: 64 | |
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| Michel, Pierre. |
| Introduction: Measuring the chemical oxygen demand (COD) is a way of determining the organic matter in water based on its oxidisibility by bichromate. The presence of organic matter in sea water is one of the factors that determines the productivity of the oceans: whether this organic matter will be absorbed directly or must first be transformed into nutritive substances by bacteria. This beneficial action also has its limits. On the one hand, consumption of organic matter remains limited; when it exceeds a certain rate, there is no longer any increase in productivity. On the other hand, the excess organic matter deteriorates by consuming the dissolved oxygen and thus competes with marine life. In extreme cases, this excess can cause the eutrophication of... |
| Tipo: Text |
Palavras-chave: Methodology; Organic matter; Oxygen demand; Seawater. |
| Ano: 1972 |
URL: http://archimer.ifremer.fr/doc/1972/publication-2060.pdf |
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| Coverly, Stephen; Kerouel, Roger; Aminot, Alain. |
| Modern instruments together with the use of standard reference materials have improved the accuracy and long-term reproducibility of the analysis of nutrients (ammonium, nitrate, nitrite, phosphate and silicate) in sea water using segmented-flow analysis, so that errors arising from matrix effects become more significant. Colorimetric detectors with bubble-through flowcells have become widely used for seawater analysis in recent years and their associated matrix effects are described. A re-examination of all categories of matrix effects, whose main origin is salinity, was thus undertaken to assess how much they are liable to alter the data. Interferences were classified into four types, each of which was examined in order to show its influence on the... |
| Tipo: Text |
Palavras-chave: Nutrient; Determination; Seawater; Estuarine water; Segmented-flow analysis; Matrix effects. |
| Ano: 2012 |
URL: http://archimer.ifremer.fr/doc/00057/16843/14530.pdf |
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| El Sayed, Mohamed A.; Aminot, Alain. |
| Extractable organic copper using C18 Sep-Pak cartridges was investigated in seawater after laboratory experiment showed that the (C18 Sep-Pak) cartridges were reliable, in open and coastal waters with normal levels of dissolved organic carbon, for the separation of a specific fraction of organo-copper complexes.Given that the Sep-Pak cartridges retain the hydrophobic fraction of the dissolved organic matter, this extraction technique was applied for studying the characteristics of this particular hydrophobic dissolved organic copper fraction (hDOCu) in the north-western Mediterranean waters. Surface distribution of hDOC is influenced by organic matter input from the river Rhone and its estuary as well as the physical processes affecting the primary... |
| Tipo: Text |
Palavras-chave: Mediterranean sea; Seawater; Dissolved organic matter; Copper compounds. |
| Ano: 2000 |
URL: http://archimer.ifremer.fr/doc/2000/publication-1681.pdf |
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| Fauvelle, Vincent; Castro-jimenez, Javier; Schmidt, Natascha; Carlez, Benoit; Panagiotopoulos, Christos; Sempere, Richard. |
| A rapid analytical method including one-single solid-phase extraction (SPE) procedure followed by gas and liquid chromatography coupled with high resolution mass spectrometry detection (GC-MS and LC-HRMS respectively) was developed for the quantification of 40 organic compounds (1.6 < log K-ow < 9.5) in seawater including both legacy and emerging contaminants, with a focus on the most common plastic organic additives. This new method allowed for the analyses of nine organophosphate esters (OPEs), seven phthalates (PAEs), six bisphenols (BPs), five perfluorinated compounds (PFCs), and thirteen legacy organochlorinated compounds (OCs, including polychlorobiphenyles and pesticides) with recoveries in the ranges of 57-124% for OPEs, 52-163% for PAEs,... |
| Tipo: Text |
Palavras-chave: Plastic additive; Seawater; Organic contaminants; Legacy contaminants; Phtalates; Bisphenol; Organophosphate esters. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00645/75716/76697.pdf |
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| Cadiou, Jean-francois; Gerigny, Olivia; Koren, Š.; Zeri, C.; Kaberi, H.; Alomar, C.; Panti, C.; Fossi, M.c.; Adamopoulou, A.; Digka, N.; Deudero, S.; Concato, M.; Carbonell, A.; Baini, M.; Galli, M.; Galgani, Francois. |
| An intercalibration exercise on the characterisation of microplastics in marine sediment and water samples was carried out among five laboratories involved in the implementation of the Marine Strategy Framework Directive (MSFD) in their country. The samples were prepared by mixing cleaned natural sediment and sea water with microplastics sets made of particles of various polymers, shapes and colours. Overall, the errors on total counts were under 25% in absolute value. The risk of non-detection and loss of particles is greater than the risk of contamination during sample analysis. Significant differences are observed among particle types. It appears difficult to obtain reliable and comparable data on the colour of microplastics. A comparison of the errors... |
| Tipo: Text |
Palavras-chave: Microplastics; Intercalibration; Protocols; Sediment; Seawater. |
| Ano: 2020 |
URL: https://archimer.ifremer.fr/doc/00622/73397/72812.pdf |
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| Roclin, Lea. |
| microplastics are ubiquitous in the marine environment, particularly in ocean gyres. this review makes an assessment of the current knowledge about microplastics as support of chemical contaminants in marine environment. 121 papers were included in this report, with 53 on the theme "microplastics, contaminants and marine environment". adsorption and desorption capacities of contaminants on microplastic depend on the contaminant, the microplastic, and external factors (salinity, organic matter and interaction with other contaminants). regardless of the sampled matrix (water and sand) and the geographical area, results have shown the presence of chemical contaminants on microplastics, which are persistent organic pollutants (pops) in the water (pcbs, pahs,... |
| Tipo: Text |
Palavras-chave: Microplastiques; Contaminants chimiques; Polluant organique persistant; Milieu marin; Microplastic; Chemical contaminant; Persistent organic pollutants; Seawater. |
| Ano: 2015 |
URL: http://archimer.ifremer.fr/doc/00278/38914/37454.pdf |
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| Vong, Lilita; Laes, Agathe; Blain, Stéphane. |
| A new method for the non-specific determination of iron-porphyrin-like complexes in natural waters has been developed. It is based on the chemiluminescent oxidation of the luminol in the presence of dioxygen (O-2) at pH 13. The method has been implemented in a FIA manifold that allowed the direct injection of seawater. The limit of detection is 0.11 nM of equivalent hemin (Fe-protoporphyrin IX). Fe2+, Fe3+, H2O2, siderophore (deferoxamin mesylate), humic acid and phytic acid did not interfere when the), were present at the concentrations expected in seawater. Metal free porphyrin and Mg, Cu, Co porphyrin complexes did not induce a significant chemiluminescent signal. Poisoned unfiltered samples could be stored for several weeks before analyses. The new... |
| Tipo: Text |
Palavras-chave: Chemiluminescence; Complexation; Flow injection; Seawater; Porphyrin; Iron. |
| Ano: 2007 |
URL: http://archimer.ifremer.fr/doc/2007/publication-3298.pdf |
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| Paluselli, Andrea; Fauvelle, Vincent; Schmidt, Natascha; Galgani, Francois; Net, Sopheak; Sempere, Richard. |
| Phthalic Acid Esters (PAEs) are a group of emerging organic contaminants that have become a serious issue because of their ubiquitous presence and hazardous impact on the marine environment worldwide. Seawater samples were collected monthly from December 2013 to November 2014 in the northwestern Mediterranean Sea (Marseille Bay). The samples were analyzed for dissolved organic carbon (DOC) as well as the molecular distribution of dissolved PAEs by using solid phase extraction followed by gas chromatography and mass spectrometry (GC/MS) analyses. The results demonstrated the occurrence of six PAEs, including dimethyl phthalate (DMP), diethyl phthalate (DEP), di-isobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), benzylbutyl phthalate (BzBP) and... |
| Tipo: Text |
Palavras-chave: Phthalates; DEHP; DMP; Seawater; Dissolved organic matter; Endocrine disruptors. |
| Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00413/52482/53358.pdf |
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| Laguionie, Philippe; Bailly-du-bois, Pascal; Boust, D.; Fievet, B.; Garreau, Pierre; Connan, O.; Charmasson, Sabine; Arnaud, M.; Duffa, Celine; Champion, D.. |
| The accident at the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) in March 2011 led to an unprecedented direct input of artificial radioactivity into the marine environment. The Institute for Radioprotection and Nuclear Safety was requested by the French authorities to investigate the radioecological impact of this input, in particular the potential contamination of products of marine origin used for human consumption. This article describes the close link between the responses provided and the availability of the data, as well as their nature and ability to meet the requirements of expert investigation. These responses were needed: (i) to evaluate the inputs of radionuclides into the marine environment, (ii) to understand their dispersion in seawater,... |
| Tipo: Text |
Palavras-chave: Nuclear power plant; Accident analysis; Seawater; Sediment; Biota. |
| Ano: 2012 |
URL: http://archimer.ifremer.fr/doc/00096/20690/18353.pdf |
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| Gantzer, Christophe; Dubois, Éric; Crance, Jean-marc; Billaudel, Sylviane; Kopecka, Helena; Schwartzbrod, Louis; Pommepuy, Monique; Le Guyader, Françoise. |
| To improve the knowledge of the survival of enteric viruses in a marine environment, the influence of physico-chemical parameters (temperature, UV, salinity) on the survival of infectious poliovirus 1 and hepatitis A Virus (HAV) in seawater was first studied, the influence of suspended solids (SS) on poliovirus adsorption and survival in seawater was then evaluated and the detection of rotavirus genome in environmental samples (shellfish, river water, treated wastewater) was finally investigated. The results show that temperature has a major impact on virus survival in seawater as the time necessary to inactivate 90 % of the virus (T-90) is 671 days at 4 degrees C and only 25 days at 25 degrees C. Ultraviolet light (42 mW s cm(-2)) rapidly inactivates... |
| Tipo: Text |
Palavras-chave: Environmental factors; Survival; Seawater; Enteric viruses; Facteurs environnementaux; Survie; Eau de mer; Virus entériques. |
| Ano: 1998 |
URL: http://archimer.ifremer.fr/doc/1998/publication-846.pdf |
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| Loisy, Fabienne; Atmar, Robert L.; Cohen, Jean; Bosch, Albert; Le Guyader, Soizick. |
| The potential of rotavirus 2/6-virus-like-particles (VLP2/6) for use as tracers in the marine environment was investigated. The stability of bovine rotavirus (strain RF) and VLP2/6 in natural seawater at 25degreesC for six days was studied. ELISA and western blot methods were used to quantify the particles. The rates of decline of rotavirus particles and VLP2/6 were similar (approximately 0.5 log 10 per day). Western blot analysis showed that the integrity of capsid proteins VP2 and VP6 was conserved during the incubation time. These results demonstrate that VLP2/6 particles have the same stability in seawater as rotavirus particles. Thus, VLP2/6 can be used as a tracer, which should be of particular value for studying the fate of rotavirus particles in... |
| Tipo: Text |
Palavras-chave: Stability; Tracer; Seawater; Virus like particles; Rotavirus. |
| Ano: 2004 |
URL: https://archimer.ifremer.fr/doc/2004/publication-330.pdf |
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| Deroine, Morgan; Le Duigou, Antoine; Corre, Yves-marie; Le Gac, Pierre-yves; Davies, Peter; Cesar, Guy; Bruzaud, Stephane. |
| The aim of this study is to establish a baseline for poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) lifetime prediction in a marine environment, by means of mechanical and physico-chemical characterization of specimens immersed in continuously renewed and filtered natural seawater in the laboratory at different temperatures (4, 25 and 40°C). Samples were also aged at sea in Lorient harbour in order to compare laboratory and natural degradation mechanisms and kinetics. Due to its morphology, hydrolysis of PHBV in natural seawater is quite slow, and samples were observed to undergo preferentially an enzymatic surface degradation. Increasing the aging temperature in the laboratory promotes the water uptake and causes hydrolysis. As two degradation... |
| Tipo: Text |
Palavras-chave: Poly(3-hydroxybutyrate-co-3-hydroxyvalerate); Accelerated ageing; Hydrothermal degradation; Seawater. |
| Ano: 2014 |
URL: http://archimer.ifremer.fr/doc/00188/29972/28425.pdf |
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| Davies, Peter; Le Gac, Pierre-yves; Le Gall, Maelenn. |
| A new matrix resin was recently introduced for composite materials, based on acrylic resin chemistry allowing standard room temperature infusion techniques to be used to produce recyclable thermoplastic composites. This is a significant advance, particularly for more environmentally-friendly production of large marine structures such as boats. However, for such applications it is essential to demonstrate that composites produced with these resins resist sea water exposure in service. This paper presents results from a wet aging study of unreinforced acrylic and glass and carbon fibre reinforced acrylic composites. It is shown that the acrylic matrix resin is very stable in seawater, showing lower property losses after seawater aging than those of a... |
| Tipo: Text |
Palavras-chave: Acrylic; Thermoplastic; Infusion; Seawater; Immersion. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00347/45815/45541.pdf |
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| Ulu, K. Narynbek; Huneau, B.; Le Gac, Pierre-yves; Verron, E.. |
| Fatigue properties of filled natural rubber in seawater environment are investigated by uniaxial fatigue and crack propagation experiments, and the damage is analyzed by scanning electron microscopy. The behavior under relaxing and non-relaxing loading conditions is studied and the results are compared to those obtained in air environment. For relaxing loading conditions, fatigue behavior is the same in both environments. Under non-relaxing conditions at large strain levels, for which the influence of strain-induced crystallization is important, fatigue life is longer in seawater. Such behavior could be explained by increased internal temperatures of specimens tested in air due to lower heat conductivity of air as compared to seawater. Such conclusion is... |
| Tipo: Text |
Palavras-chave: Natural rubber; Fatigue; Environmental effects; Seawater; Strain-induced crystallization. |
| Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00324/43523/43055.pdf |
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| Tchalla, Siwavi Tatiana; Le Gac, Pierre-yves; Maurin, R.; Creac'Hcadec, R.. |
| Polychloroprene rubbers are widely used in marine structures and often filled with silica in order to increase mechanical properties. The presence of silica fillers leads to a complex degradation of the material. This study aims to understand the deeper degradation mechanisms involved when a silica filled polychloroprene is used in sea water. To do so, 4 polychloroprene rubbers filled with different amounts of silica (from 0 to 45 phr) were aged in natural sea water for 6 months at temperatures ranging from 25 to 60 °C. Moreover, a natural rubber with similar formulation was also considered in order to evaluate the role of the chlorine atom in the degradation. . The chemistry and mechanics of the rubber degradation were also studied. In the presence of... |
| Tipo: Text |
Palavras-chave: Polychloroprene; Seawater; Silica filler; Hydrolysis. |
| Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00376/48689/49020.pdf |
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| Registros recuperados: 64 | |
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