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Measuring production-dissolution rates of marine biogenic silica by Si-30-isotope dilution using a high-resolution sector field inductively coupled plasma mass spectrometer ArchiMer
Fripiat, Francois; Corvaisier, Rudolph; Navez, Jacques; Elskens, Marc; Schoemann, Veronique; Leblanc, Karine; Andre, Luc; Cardinal, Damien.
Regional and seasonal variability of the Si dissolution: production ratios in the surface ocean have not been well assessed. Here, we propose a new method for determining these rates, using the Si-30-isotopic dilution technique with a high-resolution sector field inductively coupled plasma mass spectrometer (HR-SF-ICP-MS). Relative analytical precision of the isotopic measurement is better than 1%, similar to that obtained by thermal ionization-quadrupole mass spectrometry (TIMS). Accuracy and reproducibility of the isotopic measurements have been checked on artificial and natural solutions by intercomparison between two HR-SF-ICP-MS instruments and one TIMS. Measurements of real Si production and dissolution rates are illustrated for two contrasted...
Tipo: Text Palavras-chave: Isotopic fractionation; Southern ocean; Acid uptake; Waters; Phytoplankton; Environments; Biosilica; Recovery; Balance; Tracer.
Ano: 2009 URL: https://archimer.ifremer.fr/doc/00205/31607/30033.pdf
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Particulate barium tracing of significant mesopelagic carbon remineralisation in the North Atlantic ArchiMer
Lemaitre, Nolwenn; Planquette, Helene; Planchon, Frederic; Sarthou, Geraldine; Jacquet, Stephanie; Garcia-ibanez, Maria Isabel; Gourain, Arthur; Cheize, Marie; Monin, Laurence; Andre, Luc; Laha, Priya; Terryn, Herman; Dehairs, Frank.
The remineralisation of sinking particles by prokaryotic heterotrophic activities is important for controlling oceanic carbon sequestration. Here, we report mesopelagic particulate organic carbon (POC) remineralisation fluxes in the North Atlantic along the GEOTRACES-GA01 section (GEOVIDE cruise; May–June 2014) using the particulate biogenic barium (excess barium; Baxs) proxy. Important mesopelagic (100–1000 m) Baxs differences were observed along the transect depending on the intensity of past blooms, the phytoplankton community structure and the physical forcing, including downwelling. The subpolar province was characterized by the highest mesopelagic Baxs content (up to 727 pmol L−1), which was attributed to an intense bloom averaging 6 mg Chl-a m−3...
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Ano: 2018 URL: https://archimer.ifremer.fr/doc/00412/52308/53075.pdf
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Environmental Hf–Nd isotopic decoupling in World river clays ArchiMer
Bayon, Germain; Skonieczny, Charlotte; Delvigne, Camille; Toucanne, Samuel; Bermell, Sylvain; Ponzevera, Emmanuel; Andre, Luc.
The hafnium and neodymium radiogenic isotope systems behave differently during Earth surface processes, causing a wide dispersion of Hf and Nd isotopic compositions in sediments and other sedimentary rocks. The decoupling between Hf and Nd isotopes in sediments is generally attributed to a combination of preferential sorting of zircon during sediment transport and incongruent weathering processes on continents. In this study, we analysed size-fractions of sediment samples collected near the mouth of 53 rivers worldwide to better understand the factors controlling the distribution of Hf and Nd isotopes in sediments. Our results for rivers draining old cratonic areas and volcanic provinces demonstrate that both granite and basalt weathering can lead to...
Tipo: Text Palavras-chave: Hafnium isotopes; Neodymium; Rivers; Clays; Weathering; Climate.
Ano: 2016 URL: http://archimer.ifremer.fr/doc/00310/42094/41479.pdf
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The roles of climate and human land-use in the late Holocene rainforest crisis of Central Africa ArchiMer
Bayon, Germain; Schefuss, Enno; Dupont, Lydie; Borges, Alberto V.; Dennielou, Bernard; Lambert, Thibault; Mollenhauer, Gesine; Monin, Laurence; Ponzevera, Emmanuel; Skonieczny, Charlotte; Andre, Luc.
There is increasing evidence that abrupt vegetation shifts and large-scale erosive phases occurred in Central Africa during the third millennium before present. Debate exists as to whether these events were caused by climate change and/or intensifying human activities related to the Bantu expansion. In this study, we report on a multi-proxy investigation of a sediment core (KZR-23) recovered from the Congo submarine canyon. Our aim was to reconstruct climate, erosion and vegetation patterns in the Congo Basin for the last 10,000 yrs, with a particular emphasis on the late Holocene period. Samples of modern riverine suspended particulates were also analyzed to characterize sediment source geochemical signatures from across the Congo watershed. We find that...
Tipo: Text Palavras-chave: Neodymium isotopes; Suspended particulates; Congo Basin; ENSO; Human land-use; Deforestation.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00463/57467/59747.pdf
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A Review of the Stable Isotope Bio-geochemistry of the Global Silicon Cycle and Its Associated Trace Elements ArchiMer
Sutton, Jill N.; Andre, Luc; Cardinal, Damien; Conley, Daniel J.; De Souza, Gregory F.; Dean, Jonathan; Dodd, Justin; Ehlert, Claudia; Ellwood, Michael J.; Frings, Patrick J.; Grasse, Patricia; Hendry, Katharine; Leng, Melanie J.; Michalopoulos, Panagiotis; Panizzo, Virginia N.; Swann, George E. A..
Silicon (Si) is the second most abundant element in the Earth's crust and is an important nutrient in the ocean. The global Si cycle plays a critical role in regulating primary productivity and carbon cycling on the continents and in the oceans. Development of the analytical tools used to study the sources, sinks, and fluxes of the global Si cycle (e.g., elemental and stable isotope ratio data for Ge, Si, Zn, etc.) have recently led to major advances in our understanding of the mechanisms and processes that constrain the cycling of Si in the modern environment and in the past. Here, we provide background on the geochemical tools that are available for studying the Si cycle and highlight our current understanding of the marine, freshwater and terrestrial...
Tipo: Text Palavras-chave: C - N - O - Si isotopes; Biogenic silica; Element/Si ratios; Biogeochemical cycles; Silicon.
Ano: 2018 URL: https://archimer.ifremer.fr/doc/00431/54217/55547.pdf
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Editorial: Biogeochemistry and Genomics of Silicification and Silicifiers ArchiMer
Moriceau, Brivaela; Gehlen, Marion; Treguer, Paul; Baines, Stephen; Livage, Jacques; Andre, Luc.
Tipo: Text Palavras-chave: Silicon cycle; Biogenic silica; Diatom; Isotope; Bolidophycae; Sponge (Porifera); Nanostructured silica; Anthropogenic pressure.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00488/59978/63223.pdf
Registros recuperados: 6
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