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Registros recuperados: 78
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U-Th isotope constraints on gas hydrate and pockmark dynamics at the Niger delta margin ArchiMer
Bayon, Germain; Henderson, Gideon M.; Etoubleau, Joel; Caprais, Jean-claude; Ruffine, Livio; Marsset, Tania; Dennielou, Bernard; Cauquil, Eric; Voisset, Michel; Sultan, Nabil.
The application of uranium-thorium dating methods to authigenic carbonates provides unique constraints on the temporal evolution of methane seeps at ocean margins. In this study, we report U-Th isotope measurements for carbonate breccias collected from within a hydrate-bearing pockmark located at the Niger Delta margin. These concretions were extracted from a carbonate-rich layer in the upper two meters of a sediment core (N2-KS-44; ~ 1200 m water depth), well above the present-day sulphate-methane transition zone (about 3 m depth) and the presence of gas hydrates in the sediment. The stratigraphy of core N2-KS-44 was established by tuning its downcore Al/Ti profile to a well-dated nearby reference core, and carbonate 230Th/U ages were calculated using...
Tipo: Text Palavras-chave: Gas hydrates; Pockmarks; U-series; Authigenic carbonates; Niger delta.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00286/39708/41518.pdf
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Hf and Nd isotopes in marine sediments: Constraints on global silicate weathering ArchiMer
Bayon, Germain; Burton, K. W.; Soulet, Guillaume; Vigier, N.; Dennielou, Bernard; Etoubleau, Joel; Ponzevera, Emmanuel; German, C. R.; Nesbitt, R. W..
The combined use of Lu-Hf and Sm-Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf-Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (epsilon(Nd)similar to - 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the...
Tipo: Text Palavras-chave: Congo fan; Seawater array; Continental erosion; Silicate weathering; Hafnium isotopes; Neodymium isotopes.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6451.pdf
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Determination of Rare Earth Elements, Sc, Y, Zr, Ba, Hf and Th in Geological Samples by ICP-MS after Tm Addition and Alkaline Fusion ArchiMer
Bayon, Germain; Barrat, Jean Alix; Etoubleau, Joel; Benoit, Mathieu; Bollinger, Claire; Revillon, Sidonie.
We present a revised method for the determination of concentrations of rare earth (REE) and other trace elements (Y, Sc, Zr, Ba, Hf, Th) in geological samples. Our analytical procedure involves sample digestion using alkaline fusion (NaOH-Na2O2) after addition of a Tm spike, co-precipitation on iron hydroxides, and measurement by sector field-inductively coupled plasma-mass spectrometry (SF-ICP-MS). The procedure was tested successfully for various rock types (i.e., basalt, ultramafic rock, sediment, soil, granite), including rocks with low trace element abundances (sub ng g(-1)). Results obtained for a series of nine geological reference materials (BIR-1, BCR-2, UB-N, JP-1, AC-E, MA-N, MAG-1, GSMS-2, GSS-4) are in reasonable agreement with published...
Tipo: Text Palavras-chave: Digestion des Echantillons; Spike de Tm; ICP MS; MatEriaux de rEfErence; Echantillons gEologiques; ElEments du groupe des Terres Rares; Sample digestion; Tm spike; ICP MS; Reference materials; Geological samples; Rare earth elements.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6449.pdf
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Sr/Ca and Mg/Ca ratios in Niger Delta sediments: Implications for authigenic carbonate genesis in cold seep environments ArchiMer
Bayon, Germain; Pierre, C; Etoubleau, Joel; Voisset, Michel; Cauquil, E; Marsset, Tania; Sultan, Nabil; Le Drezen, Eliane; Fouquet, Yves.
We report on a reconnaissance analysis of the geochemical composition of authigenic carbonates and sediment samples collected from various seepage sites on the Niger deep-sea fan. Our aim has been to investigate whether evidence for the presence of authigenic carbonates and gas hydrates within sediments is discernible from solid-phase sediment geochemistry. We show that sedimentary Sr/Ca and Mg/Ca ratios can be used to infer the presence of authigenic aragonite (Sr-rich) and Mg-rich carbonate phases (high-Mg calcite, dolomite) in cold seep settings. Using Sr/Ca and Mg/Ca ratios, the proportion (wt.%) of authigenic carbonates in Niger Fan sediments can be calculated from a mixing model between sediment fractions of terrigenous material, biogenic calcite,...
Tipo: Text Palavras-chave: Niger Delta; Gas hydrates; Cold seeps; Mg/Ca; Sr/Ca; Authigenic carbonates.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/publication-2696.pdf
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Structure of the Demerara passive-transform margin and associated sedimentary processes. Initial results from the IGUANES cruise ArchiMer
Loncke, L.; Maillard, A.; Basile, C.; Roest, Walter; Bayon, Germain; Gaullier, V.; Pattier, France; Mercier De Lépinay, Marion; Grall, Celine; Droz, L.; Marsset, Tania; Giresse, P.; Caprais, Jean-claude; Cathalot, Cecile; Graindorge, D.; Heuret, A.; Lebrun, J. F.; Bermell, Sylvain; Marcaillou, B.; Sotin, C.; Hebert, B.; Patriat, Martin; Bassetti, M. A.; Tallobre, Cedric; Buscail, R.; Durrieu De Madron, X.; Bourrin, F..
he IGUANES cruise took place in May 2013 on the R/V L'Atalante along the Demerara passive transform margin off French Guiana and Surinam. Seismic, multibeam and chirp acquisitions were made. Piston cores were collected for pore geochemistry and sedimentology. A mooring was deployed on the sea-bottom for 10 months (temperature, salinity, turbidity and current measurements). This new dataset highlights the lateral variability of the 350 km-long Guiana–Surinam transform margin due to the presence of a releasing bend between two transform segments. The adjacent Demerara Plateau is affected by a 350 km-long giant slide complex. This complex initiated in Cretaceous times and was regularly reactivated until recent times. Since the Miocene, contourite processes...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00428/53942/55285.pdf
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Menes caldera, a highly active site of brine seepage in the Eastern Mediterranean sea: "In situ" observations from the NAUTINIL expedition (2003) ArchiMer
Huguen, Caroline; Foucher, Jean-paul; Mascle, J.; Ondreas, Helene; Thouement, M.; Gontharet, S.; Stadnitskaia, A.; Pierre, C.; Bayon, Germain; Loncke, L.; Boetius, A.; Bouloubassi, I.; De Lange, G.; Caprais, Jean-claude; Fouquet, Yves; Woodside, J.; Dupre, Stephanie.
This paper reports the first "in situ" seafloor observations of fluid escape structures in a fault-controlled caldera-type depression of about 8 km diameter, named the Menes caldera, in the Eastern Mediterranean sea off Egypt (western province of the Nile Deep Sea Fan). A detailed analysis of seven Nautile dives, performed during the Nautinil cruise in 2003, focused on determining the nature, origin, importance, mechanisms and environmental impacts of the fluid escape processes from the geological observations. Seafloor maps, constructed from direct visual observations and video records made from the submersible, and sampling results, for three mud volcanoes of the caldera, Cheops, Chephren and Mykerinos show differences in activity but many common...
Tipo: Text Palavras-chave: Mediterranean Sea; Nile Deep Sea Fan; Mud volcano; Brine seep.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/00000/11089/10627.pdf
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Trace element systematics in cold seep carbonates and associated lipid compounds ArchiMer
Wang, Xudong; Bayon, Germain; Kim, Jung-hyun; Lee, Dong-hun; Kim, Dahae; Guéguen, Bleuenn; Rouget, Marie-laure; Barrat, Jean-alix; Toffin, Laurent; Feng, Dong.
Seeping of methane-rich fluids at submarine cold seeps drives intense microbial activity and precipitation of authigenic carbonates. Some trace elements play an important role in the biogeochemical processes operating at cold seeps, especially as specific enzymatic co-factors related to methanogenesis and the anaerobic oxidation of methane (AOM). However, it is unclear whether microbial trace metal utilization can be traced by the geochemical composition of seep carbonates. In this study, we analyzed a series of authigenic carbonate samples recovered from various seep settings worldwide and report for the first time trace element concentrations for total lipid fractions, combined with biomarker analyses and determination of elemental abundances in...
Tipo: Text Palavras-chave: Seep carbonate; Lipid compounds; Trace elements; Tungsten; Nickel; Cobalt; Molybdenum.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00511/62311/66562.pdf
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Rare earth elements and neodymium isotopes in world river sediments revisited ArchiMer
Bayon, Germain; Toucanne, Samuel; Skonieczny, Charlotte; Andre, L.; Bermell, Sylvain; Cheron, Sandrine; Dennielou, Bernard; Etoubleau, Joel; Freslon, Nicolas; Gauchery, T.; Germain, Yoan; Jorry, Stephan; Menot, G.; Monin, L.; Ponzevera, Emmanuel; Rouget, M. -l.; Tachikawa, K.; Barrat, Jean-alix.
Over the past decades, rare earth elements (REE) and their radioactive isotopes have received tremendous attention in sedimentary geochemistry, as tracers for the geological history of the continental crust and provenance studies. In this study, we report on elemental concentrations and neodymium (Nd) isotopic compositions for a large number of sediments collected near the mouth of rivers worldwide, including some of the world’s major rivers. Sediments were leached for removal of non-detrital components, and both clay and silt fractions were retained for separate geochemical analyses. Our aim was to re-examine, at the scale of a large systematic survey, whether or not REE and Nd isotopes could be fractionated during Earth surface processes. Our results...
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Ano: 2015 URL: http://archimer.ifremer.fr/doc/00276/38733/37249.pdf
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Dinocyst assemblage constraints on oceanographic and atmospheric processes in the eastern equatorial Atlantic over the last 44 kyr ArchiMer
Hardy, William; Penaud, Aurelie; Marret, Fabienne; Bayon, Germain; Marsset, Tania; Droz, Laurence.
A new 44 kyr long record of dinoflagellate (phytoplanktonic organisms) cysts (dinocysts) is presented from a marine sediment core collected on the Congolese margin with the aim of reconstructing past hydrological changes in the equatorial eastern Atlantic Ocean since Marine Isotopic Stage (MIS) 3. Our high-resolution dinocyst record indicates that significant temperature and moisture variations occurred across the glacial period, the last deglaciation and the Holocene. The use of specific dinocyst taxa, indicative of fluvial, upwelling and Benguela Current past environments for instance, provides insights into the main forcing mechanisms controlling palaeohydrological changes on orbital timescales. In particular, we are able, for the last 44 kyr, to...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00349/46006/45675.pdf
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Multi-disciplinary investigation of fluid seepage on an unstable margin: The case of the Central Nile deep sea fan ArchiMer
Bayon, Germain; Loncke, L.; Dupre, Stephanie; Caprais, Jean-claude; Ducassou, E.; Duperron, Sebastien; Etoubleau, Joel; Foucher, Jean-paul; Fouquet, Yves; Gontharet, S.; Henderson, G. M.; Huguen, Caroline; Klaucke, I.; Mascle, J.; Migeon, S.; Olu-le-roy, Karine; Ondreas, Helene; Pierre, C.; Sibuet, Myriam; Stadnitskaia, A.; Woodside, J..
We report on a multidisciplinary study of cold seeps explored in the Central Nile deep-sea fan of the Egyptian margin. Our approach combines in situ seafloor observation, geophysics, sedimentological data, measurement of bottom-water methane anomalies, pore-water and sediment geochemistry, and Th-230/U dating of authigenic carbonates. Two areas were investigated, which correspond to different sedimentary provinces. The lower slope, at similar to 2100 m water depth, indicates deformation of sediments by gravitational processes, exhibiting slope-parallel elongated ridges and seafloor depressions. In contrast, the middle slope, at similar to 1650 m water depth, exhibits a series of debris-flow deposits not remobilized by post-depositional gravity processes....
Tipo: Text Palavras-chave: Authigenic carbonate; U Th; Cold seep; Continental margin; Nile.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6586.pdf
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A Multi-Elements Isotope Approach to Assess the Geographic Provenance of Manila Clams (Ruditapes philippinarum) via Recombining Appropriate Elements ArchiMer
Won, Eun-ji; Kim, Seung Hee; Go, Young-shin; Kumar, K. Suresh; Kim, Min-seob; Yoon, Suk-hee; Bayon, Germain; Kim, Jung-hyun; Shin, Kyung-hoon.
The increasing global consumption of seafood has led to increased trade among nations, accompanied by mislabeling and fraudulent practices that have rendered authentication crucial. The multi-isotope ratio analysis is considered as applicable tool for evaluating geographical authentications but requires information and experience to select target elements such as isotopes, through a distinction method based on differences in habitat and physiology due to origin. The present study examined recombination conditions of multi-elements that facilitated geographically distinct classifications of the clams to sort out appropriate elements. Briefly, linear discriminant analysis (LDA) analysis was performed according to several combinations of five stable isotopes...
Tipo: Text Palavras-chave: Authentication; Manila clam; Stable isotope; Traceability; Linear discriminant analysis.
Ano: 2021 URL: https://archimer.ifremer.fr/doc/00685/79701/82488.pdf
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Formation of seep carbonates along the makran convergent margin, northern Arabian sea and a molecular and isotopic approach to constrain the carbon isotopic composition of parent methane ArchiMer
Himmler, Tobias; Birgel, Daniel; Bayon, Germain; Pape, Thomas; Ge, Lu; Bohrmann, Gerhard; Peckmann, Joern.
Authigenic carbonate deposits have been sampled with the remotely operated vehicle ‘MARUM-QUEST 4000 m’ from five methane seeps between 731 and 1823 m water depth along the convergent Makran continental margin, offshore Pakistan (northern Arabian Sea). Two seeps on the upper slope are located within the oxygen minimum zone (OMZ; ca. 100 to 1100 m water depth), the other sites are situated in oxygenated water below the OMZ (below 1100 m water depth). The carbonate deposits vary with regard to their spatial extent, sedimentary fabrics, and associated seep fauna: Within the OMZ, carbonates are spatially restricted and associated with microbial mats, whereas in the oxygenated zone below the OMZ extensive carbonate crusts are exposed on the seafloor with...
Tipo: Text Palavras-chave: Anaerobic oxidation of methane Authigenic carbonates Cold-seep carbonates; Makran subduction zone Oxygen minimum zone Methane Lipid biomarkers.
Ano: 2015 URL: http://archimer.ifremer.fr/doc/00280/39120/37673.pdf
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Description of a contourite depositional system on the Demerara Plateau: Results from geophysical data and sediment cores ArchiMer
Tallobre, Cedric; Loncke, Lies; Bassetti, Maria-angela; Giresse, Pierre; Bayon, Germain; Buscail, Roselyne; De Madron, Xavier Durrieu; Bourrin, Francois; Vanhaesebroucke, Marc; Sotin, Christine.
The Demerara Plateau, belonging to the passive transform margin of French Guiana, was investigated during the IGUANES cruise in 2013. The objectives of the cruise were to explore the poorly-known surficial sedimentary column overlying thick mass transport deposits as well as to understand the factors controlling recent sedimentation. The presence of numerous bedforms at the seafloor was observed thanks to newly acquired IGUANES bathymetric, high resolution seismic and chirp data, while sediment cores allowed the characterization of the deposits covering the mass transport deposits. Modern oceanographic conditions were determined in situ, using mooring monitoring over a 10-month period. Our data indicate the presence of a Contourite Depositional System...
Tipo: Text Palavras-chave: Marginal plateau; Contourite; Comet tail; Demerara Plateau.
Ano: 2016 URL: https://archimer.ifremer.fr/doc/00308/41957/41220.pdf
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Formation and evolution of glauconite in the Demerara Contourite depositional system related to NADW circulation changes during late Quaternary (French Guiana) ArchiMer
Tallobre, Cédric; Giresse, Pierre; Bassetti, Maria-angela; Loncke, Lies; Bayon, Germain; Buscail, Roselyne; Tudryn, Alina; Zaragosi, Sébastien.
The Demerara Plateau is a marginal plateau which forms a bathymetric relief on the sea floor. Here, contourite deposits have been studied in detail, following the recent discovery of contourite sequences likely related to the bottom currents and linked both to contour current and peculiar sea-floor morphology. A chronostratigraphic framework, based on δ18O relative variations and palaeomagnetic events in sediment cores allows correlating sediment processes to current intensity changes and major climate phases (glacial or interglacial). The studied sediments are enriched in glauconitic grains. In addition, the glauconite mineralogical maturity can easily correlate to low sedimentation rate and slightly energetic bottom currents on the seafloor. Based on...
Tipo: Text Palavras-chave: Marginal plateau; Contourite; Glauconite; Demerara plateau.
Ano: 2019 URL: https://archimer.ifremer.fr/doc/00485/59665/62724.pdf
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delta(44/42) Ca in gas hydrates, porewaters and authigenic carbonates from Niger Delta sediments ArchiMer
Henderson, Gm; Chu, Nc; Bayon, Germain; Benoit, M.
Tipo: Text
Ano: 2006 URL: http://archimer.ifremer.fr/doc/2006/publication-3588.pdf
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Multi-Element Determination of Trace Elements in Natural Water Reference Materials by ICP-SFMS after Tm Addition and Iron Co-precipitation ArchiMer
Bayon, Germain; Birot, Dominique; Bollinger, Claire; Barrat, Jean Alix.
We report on an improved method for determining trace element abundances in seawater and other natural waters. The analytical procedure involves co-precipitation on iron hydroxides after addition of a Tm spike, and measurement by inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The validity of the method was assessed through a series of co-precipitation experiments, using ultra-diluted solutions of a certified rock reference material (BIR-1). Results obtained for four natural water reference materials (NASS-5, CASS-4, SLEW-3, SLRS-4) are in agreement with published working values for rare earth elements, yttrium, vanadium and, when available, for hafnium, zirconium, thorium and scandium. A set of proposed values with uncertainties...
Tipo: Text Palavras-chave: Seawater; Reference material; ICP-MS; Trace elements; Rare earth elements; Eau de mer; Materiau de reference; ICP-MS; Elements traces; Terres Rares.
Ano: 2011 URL: http://archimer.ifremer.fr/doc/00031/14189/18000.pdf
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North Atlantic Deep Water Production during the Last Glacial Maximum ArchiMer
Howe, Jacob N. W.; Piotrowski, Alexander M.; Noble, Taryn L.; Mulitza, Stefan; Chiessi, Cristiano M.; Bayon, Germain.
Changes in deep ocean ventilation are commonly invoked as the primary cause of lower glacial atmospheric CO2. The water mass structure of the glacial deep Atlantic Ocean and the mechanism by which it may have sequestered carbon remain elusive. Here we present neodymium isotope measurements from cores throughout the Atlantic that reveal glacial-interglacial changes in water mass distributions. These results demonstrate the sustained production of North Atlantic Deep Water under glacial conditions, indicating that southern-sourced waters were not as spatially extensive during the Last Glacial Maximum as previously believed. We demonstrate that the depleted glacial delta C-13 values in the deep Atlantic Ocean cannot be explained solely by water mass source...
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Ano: 2016 URL: http://archimer.ifremer.fr/doc/00343/45386/44888.pdf
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Glacial erosion dynamics in a small mountainous watershed (Southern French Alps): A source-to-sink approach ArchiMer
Bonneau, Lucile; Toucanne, Samuel; Bayon, Germain; Jorry, Stephan; Emmanuel, Laurent; Silva Jacinto, Ricardo.
In this study we used major element composition, neodymium isotopes ratios (εNdεNd) and concentration of REE to track and quantify the sediment routing in the Var sedimentary system from source (Southern French Alps) to sink (Ligurian Sea) over the last 50 ka. Our data reveal that changes in sediment sources over that period, associated with concomitant changes in the hyperpycnal (i.e. flood-generated turbidity currents) activity in the Var submarine canyon, were mainly driven by paleoenvironmental conditions in the upper basin and in particular by the presence of glaciers during the last glacial period. Based on this evidence, we determined when and how glacier-derived sediments were produced, then excavated and transferred to the ocean, allowing us to...
Tipo: Text Palavras-chave: Var; Routing system; Glacial erosion; Source-to-sink.
Ano: 2017 URL: http://archimer.ifremer.fr/doc/00358/46957/47130.pdf
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Determination of ultra-low U-236/U-238 isotope ratios by tandem quadrupole ICP-MS/MS ArchiMer
Tanimizu, Masaharu; Sugiyama, Naoki; Ponzevera, Emmanuel; Bayon, Germain.
Isotope ratios of U-236/U-238 were measured at levels below 10(-7) by single collector ICPMS with a tandem quadrupole mass separation mechanism. Peak tailing of the prominent U-238(+) ion beam on the U-236(+) peak was reduced to the level of similar to 10(-10) by use of two quadrupole mass filters. The (UH+)-U-235 interference on U-236(+) was efficiently reduced to a UH+/U+ ratio of 1 x 10(-8) by an ion-molecule reaction between UH+ and O-2 in a collision/reaction cell placed between the two quadrupoles. The resultant detection limit for U-236/U-238 measurement was better than those reported by any other ICPMS study. The U-236/U-238 ratios, measured as (UO+)-U-236-O-16/(UO+)-U-238-O-16, were determined in the range 10(-9) to 10(-7) without correction for...
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Ano: 2013 URL: http://archimer.ifremer.fr/doc/00152/26358/24440.pdf
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Hf and Nd isotope records of West African monsoon precipitation in sediments from the Niger Delta ArchiMer
Bayon, Germain; Etoubleau, Joel; Ponzevera, Emmanuel; Voisset, Michel.
Tipo: Text
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00023/13413/10490.pdf
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