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Research on automation of a reductive dissolved organic nitrogen analyser ArchiMer
Lepoupon, C; Lin, Rg; Benaim, Jy; Merks, Aga.
The accurate classical batch method of Duursma (1961), based on the conversion of Dissolved Organic Nitrogen (DON) into NH3, is used as a basis for a new automatic DON analyser. After testing different possibilities through mechanical automation of the original batch technique, in which the conversion is preceded by the degassing of NH3 and drying of the sample, the procedure of autoanalyses has been selected. This procedure was simplified to the extent that a compact unit could be constructed, which would easily be applicable on board ship. The automatic method has a conversion phase in which in principle only DON is dissociated to NH4+, whereas both NO2- add NO3- are not reduced. This requires selective conditions and particularly high silver purity for...
Tipo: Text Palavras-chave: Dissolved organic nitrogen; Analysis; Automation; Reduction; Total nitrogen.
Ano: 1997 URL: http://archimer.ifremer.fr/doc/00093/20456/18128.pdf
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